Intramolecular catalysis of phosphodiester hydrolysis by two imidazoles

Journal of the American Chemical Society

Volumn 132, Issue 24, 2010, Pages 8513-8523

  Orth, Elisa S ^a   Brandão, Tiago A S ^a   Souza, Bruno S ^a   Pliego, Josefredo R ^b   Vaz, Boniek G ^c   Eberlin, Marcos N ^b   Kirby, Anthony J ^d   Nome, Faruk ^a  

^a FEDERAL UNIVERSITY OF SANTA CATARINA   (Brazil)

^b FEDERAL UNIVERSITY OF SÃO JOÃO DEL REI   (Brazil)

^c UNIVERSITY OF CAMPINAS   (Brazil)

^d UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EQUIVALENT MECHANISMS; IMIDAZOLE GROUP; IMIDAZOLIUM; IMIDAZOLYL; INTRAMOLECULAR CATALYSIS; INTRAMOLECULAR GENERAL ACID CATALYSIS; NUCLEOPHILIC CATALYSIS; PHOSPHODIESTERS; PHOSPHOLIPASE D; SIMPLE MODEL;

CATALYSIS; ELECTROSPRAY IONIZATION; HYDROLYSIS; MASS SPECTROMETRY;

PLANTS (BOTANY);

IMIDAZOLE DERIVATIVE; NUCLEOPHILE; PHOSPHODIESTER BIS [2 (1 METHYL 1H IMIDAZOLYL)PHENYL] PHOSPHATE; PHOSPHOLIPASE D; PHOSPHORIC ACID DERIVATIVE; PHOSPHORUS; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTROSPRAY MASS SPECTROMETRY; HYDROLYSIS; NUCLEOPHILICITY; PROTON TRANSPORT; STRUCTURE ANALYSIS;

BUFFERS; CATALYSIS; HYDROGEN-ION CONCENTRATION; HYDROLYSIS; IMIDAZOLES; KINETICS; MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHATES; QUANTUM THEORY; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION; THERMODYNAMICS;

EID: 77953632695     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1034733     Document Type: Article

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