Role of the P-F bond in fluoride-promoted aqueous VX hydrolysis: An experimental and theoretical study

Journal of Organic Chemistry

Volumn 77, Issue 22, 2012, Pages 10042-10049

  Marciano, Daniele ^a   Columbus, Ishay ^a   Elias, Shlomi ^a   Goldvaser, Michael ^a   Shoshanim, Ofir ^a   Ashkenazi, Nissan ^a   Zafrani, Yossi ^a  

^a ISRAEL INSTITUTE FOR BIOLOGICAL RESEARCH   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

BOND FORMATION; COMPUTATIONAL STUDIES; DEGRADATION PROCESS; DILUTE AQUEOUS SOLUTION; FLUORIDE ION; FLUORIDE SOLUTION; LOW ACTIVATION; MECHANISTIC STUDIES; METHYLPHOSPHONIC ACID; NON-TOXIC PRODUCTS; NUCLEOPHILICITIES; ORGANOPHOSPHORUS COMPOUNDS; PERSISTENT CHEMICALS; PRACTICAL IMPORTANCE; REACTION MECHANISM; RELATIVE BASICITY; SIDE PRODUCTS; SLOW DEGRADATION; THEORETICAL STUDY;

CHEMICAL WARFARE; REACTION RATES;

PHOSPHORUS COMPOUNDS;

ETHYL METHYLPHOSPHONIC ACID; FLUORIDE; FLUORIDE ION; HYDROXIDE; INORGANIC SALT; METHYLPHOSPHONIC ACID; O ETHYL METHYLPHOSPHONOFLUORIDATE; O ETHYL S 2 (DIISOPROPYLAMINO)ETHYL METHYLPHOSPHONOTHIOATE; PHOSPHATE; PHOSPHORUS; POTASSIUM ION; SODIUM ION; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL BOND; CONTROLLED STUDY; DEGRADATION; GAS; HYDROLYSIS; NUCLEOPHILICITY; PH; QUANTUM MECHANICS; ROOM TEMPERATURE; SOLVATION; THERMODYNAMICS;

FLUORIDES; HYDROLYSIS; KINETICS; MODELS, THEORETICAL; ORGANOTHIOPHOSPHORUS COMPOUNDS; WATER;

EID: 84869151125     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo301549z     Document Type: Article

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