Ion-molecule reactions of O,S-dimethyl methylphosphonothioate: Evidence for intramolecular sulfur oxidation during VX perhydrolysis

Journal of Organic Chemistry

Volumn 74, Issue 24, 2009, Pages 9319-9327

  McAnoy, Andrew M ^a   Williams, Jilliarne ^a   Paine, Martin R L ^b   Rogers, Michael L ^a   Blanksby, Stephen J ^b  

^a DEFENCE SCIENCE AND TECHNOLOGY ORGANISATION   (Australia)

^b UNIVERSITY OF WOLLONGONG   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL EQUATIONS; CLEAVAGE PRODUCTS; COLLISION-INDUCED DISSOCIATION; GASPHASE; ION TRAP MASS SPECTROMETER; ION-MOLECULE REACTION; MODEL SYSTEM; NERVE AGENTS; NON-TOXIC PRODUCTS; NUCLEOPHILIC ADDITIONS; NUCLEOPHILIC REACTION; PROTON TRANSFER PROCESS; SOLUTION PHASE; SULFUR OXIDATION; THEORETICAL CALCULATIONS;

ADDITION REACTIONS; COMPETITION; INTERNAL OXIDATION; ISOTOPES; MASS SPECTROMETRY; NEGATIVE IONS; PHOSPHORUS; PROTON TRANSFER; SULFUR;

REACTION INTERMEDIATES;

CARBON; DIMETHYLPHOSPHONATE; ION; NUCLEOPHILE; O DIMETHYL METHYLPHOSPHONOTHIOATE; OXYGEN; PHOSPHONIC ACID DERIVATIVE; PHOSPHOROTHIOIC ACID DERIVATIVE; PHOSPHORUS; SULFUR; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; COLLISIONALLY ACTIVATED DISSOCIATION; CONTROLLED STUDY; CROSS LINKING; CYCLOADDITION; GAS; HYDROLYSIS; ISOTOPE LABELING; KINETICS; MOLECULAR INTERACTION; MOLECULAR STABILITY; MOLECULE; OXIDATION; PHASE TRANSITION; VX PERHYDROLYSIS;

CARBON; CHEMICAL WARFARE AGENTS; HYDROGEN-ION CONCENTRATION; HYDROLYSIS; IONS; KINETICS; ORGANOPHOSPHORUS COMPOUNDS; ORGANOTHIOPHOSPHORUS COMPOUNDS; OXIDATION-REDUCTION; PHOSPHORUS; PROTONS; SULFHYDRYL COMPOUNDS; SULFUR;

EID: 73149103712     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo901944p     Document Type: Article

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