Multiple-site concerted proton-electron transfer reactions of hydrogen-bonded phenols are nonadiabatic and well described by semiclassical marcus theory

Journal of the American Chemical Society

Volumn 134, Issue 40, 2012, Pages 16635-16645

  Schrauben, Joel N ^a,b   Cattaneo, Mauricio ^a,c   Day, Thomas C ^a   Tenderholt, Adam L ^a,d   Mayer, James M ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

^b NATIONAL RENEWABLE ENERGY LABORATORY   (United States)

^c UNIVERSIDAD NACIONAL DE TUCUMÁN   (Argentina)

^d Target Discovery Inc   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADIABATIC LIMIT; BIMOLECULAR REACTION; DATA SETS; DIFFUSION LIMITS; DIRECT MEASUREMENT; DRIVING FORCES; ELECTRON TRANSFER; HYDROGEN-BONDED PHENOLS; INTRAMOLECULAR PROTON TRANSFER; MARCUS THEORY; NON-ADIABATIC; PHENOL HYDROXYL GROUP; POLYARENES; PYRIDYL; RADICAL CATIONS; STOPPED-FLOW KINETICS; TERT-BUTYL GROUP; TRANSFER REACTION;

ELECTRON TRANSITIONS; EXCITED STATES; EXPERIMENTS; FREE RADICAL REACTIONS; OXIDATION; POLYCYCLIC AROMATIC HYDROCARBONS; RATE CONSTANTS;

PHENOLS;

CARBON; HYDROGEN; HYDROXYL GROUP; PHENOL; POLYCYCLIC AROMATIC HYDROCARBON; PROTON; TERT BUTYL ALCOHOL;

ARTICLE; CONJUGATION; DIFFUSION; ELECTRON TRANSPORT; EXPERIMENT; FLOW KINETICS; HYDROGEN BOND; OXIDATION; PHOTOCHEMISTRY; THEORY;

ELECTRON TRANSPORT; ELECTRONS; HYDROGEN BONDING; OXIDATION-REDUCTION; PHENOLS; PROTONS; THERMODYNAMICS;

EID: 84867389272     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja305668h     Document Type: Article

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