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1
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49449087972
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The term PCET is used here to denote all regimes of coupling from stepwise to concerted
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The term PCET is used here to denote all regimes of coupling from stepwise to concerted.
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2
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0038208381
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In the present work, no temperature dependent change in the & tensor of the phenoxyl radical was observed. For TyrD• in Mn-depleted PSII, a change in gx upon warming from 1.8 to 77 K is mainly attributed to either deprotonation of a histidinyl cation or movement of the uncharged histidine away from the tyrosyl radical.2b In 1 the lack of a secondary proton acceptor and the covalent attachment of the benzimidazole base likely preclude such changes to the local electrostatic environment of the phenoxyl radical
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2b In 1 the lack of a secondary proton acceptor and the covalent attachment of the benzimidazole base likely preclude such changes to the local electrostatic environment of the phenoxyl radical.
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33
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49449111599
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Heterogeneity encompasses various frozen conformations and tautomeric structures of 1.
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Heterogeneity encompasses various frozen conformations and tautomeric structures of 1.
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