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-et. (10f, 10g) Return electron transfer can be competitive in the SSRIP, but much less so in the contact species, because the larger reorganization energy and the inverted region effect in the SSRIP outweigh the smaller electronic coupling. (10f)
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For clarity, we note that the term in braces is unitless under standard-state (1 M) conditions
-
For clarity, we note that the term in braces is unitless under standard-state (1 M) conditions.
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79953893090
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A more rigorous analysis yielded similar results. (18c)
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A more rigorous analysis yielded similar results. (18c)
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79953846350
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et at the isoergic point is ∼3
-
et at the isoergic point is ∼3.
-
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69
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68049091006
-
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For a recent example, see
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For a recent example, see: Baciocchi, E.; Bietti, M.; Di Fusco, M.; Lanzalunga, O.; Raponi, D. J. Org. Chem. 2009, 74, 5576
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