Rigid, vapor-permeable poly(4-methyl-2-pentyne) templates for high resolution patterning of nanoparticles and polymers

ACS Nano

Volumn 6, Issue 8, 2012, Pages 6890-6896

  Demko, Michael T ^a,b   Cheng, Jim C ^a   Pisano, Albert P ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

microfluidic molding; nanoparticles; patterning; poly(4 methyl 2 pentyne); polymeric materials; soft lithography

Indexed keywords

HIGH RESOLUTION; HIGH-RESOLUTION PATTERNING; LOW YOUNG'S MODULUS; PATTERNING; POLY(4-METHYL-2-PENTYNE); POLYDIMETHYLSILOXANE PDMS; RIGID POLYMERS; SOFT LITHOGRAPHY; TEMPLATE MATERIAL; VAPOR PERMEABILITY;

MICROCHANNELS; NANOPARTICLES; VAPORS;

POLYMERS;

DIMETICONE; NANOMATERIAL; POLY(4 METHYL 1 PENTENE); POLY(4-METHYL-1-PENTENE); POLYDIMETHYLDIPHENYLSILOXANE; POLYENE;

ARTICLE; CHEMISTRY; CONFORMATION; CRYSTALLIZATION; GAS; HARDNESS; MACROMOLECULE; MATERIALS TESTING; METHODOLOGY; MOLECULAR IMPRINTING; PARTICLE SIZE; POROSITY; SURFACE PROPERTY; ULTRASTRUCTURE; YOUNG MODULUS;

CRYSTALLIZATION; DIMETHYLPOLYSILOXANES; ELASTIC MODULUS; GASES; HARDNESS; MACROMOLECULAR SUBSTANCES; MATERIALS TESTING; MOLECULAR CONFORMATION; MOLECULAR IMPRINTING; NANOSTRUCTURES; PARTICLE SIZE; POLYENES; POROSITY; SURFACE PROPERTIES;

EID: 84865593377     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn3017266     Document Type: Article

References (33)

1. Ko, S. H.; Park, I.; Pan, H.; Grigoropoulos, C. P.; Pisano, A. P.; Luscombe, C. K.; Frechet, J. M. J. Direct Nanoimprinting of Metal Nanoparticles for Nanoscale Electronics Fabrication Nano Lett. 2007, 7, 1869-1877
2. Kim, E.; Xia, Y. N.; Whitesides, G. M. Polymer Microstructures Formed by Molding in Capillaries Nature 1995, 376, 581-584
3. Kim, E.; Xia, Y. N.; Zhao, X. M.; Whitesides, G. M. Solvent-Assisted Microcontact Molding: A Convenient Method for Fabricating Three-Dimensional Structures on Surfaces of Polymers Adv. Mater. 1997, 9, 651-654
4. Kim, Y. S.; Suh, K. Y.; Lee, H. H. Fabrication of Three-Dimensional Microstructures by Soft Molding Appl. Phys. Lett. 2001, 79, 2285-2287
5. Demko, M. T.; Cheng, J. C.; Pisano, A. P. High-Resolution Direct Patterning of Gold Nanoparticles by the Microfluidic Molding Process Langmuir 2010, 26, 16710-16714
6. Schmid, H.; Michel, B. Siloxane Polymers for High-Resolution, High-Accuracy Soft Lithography Macromolecules 2000, 33, 3042-3049
7. Choi, S. J.; Yoo, P. J.; Baek, S. J.; Kim, T. W.; Lee, H. H. An Ultraviolet-Curable Mold for Sub-100-nm Lithography J. Am. Chem. Soc. 2004, 126, 7744-7745
8. Csucs, G.; Kunzler, T.; Feldman, K.; Robin, F.; Spencer, N. D. Microcontact Printing of Macromolecules with Submicrometer Resolution by Means of Polyolefin Stamps Langmuir 2003, 19, 6104-6109
9. Pisignano, D.; D'Amone, S.; Gigli, G.; Cingolani, R. Rigid Organic Molds for Nanoimprint Lithography by Replica Molding of High Glass Transition Temperature Polymers J. Vac. Sci. Technol. B 2004, 22, 1759-1763
10. Kim, Y. S.; Lee, H. H.; Hammond, P. T. High Density Nanostructure Transfer in Soft Molding using Polyurethane Acrylate Molds and Polyelectrolyte Multilayers Nanotechnology 2003, 14, 1140-1144
11. Khang, D. Y.; Kang, H.; Kim, T.; Lee, H. H. Low-Pressure Nanoimprint Lithography Nano Lett. 2004, 4, 633-637
12. Williams, S. S.; Retterer, S.; Lopez, R.; Ruiz, R.; Samulski, E. T.; DeSimone, J. M. High-Resolution PFPE-based Molding Techniques for Nanofabrication of High-Pattern Density, Sub-20 nm Features: A Fundamental Materials Approach Nano Lett. 2010, 10, 1421-1428
13. Lee, B. K.; Hong, L.-Y.; Lee, H. Y.; Kim, D.-P.; Kawai, T. Replica Mold for Nanoimprint Lithography from a Novel Hybrid Resin Langmuir 2009, 25, 11768-11776
14. Lee, B. K.; Cho, H.; Chung, B. H. Nonstick, Modulus-Tunable and Gas-Permeable Replicas for Mold-Based, High-Resolution Nanolithography Adv. Funct. Mater. 2011, 21, 3681-3689
15. Chou, S. Y.; Krauss, P. R.; Renstrom, P. J. Imprint of Sub-25 Nm Vias and Trenches in Polymers Appl. Phys. Lett. 1995, 67, 3114-3116
16. Puetz, J.; Aegerter, M. A. Direct Gravure Printing of Indium Tin Oxide Nanoparticle Patterns on Polymer Foils Thin Solid Films 2008, 516, 4495-4501
17. Pandey, P.; Chauhan, R. S. Membranes for Gas Separation Prog. Polym. Sci. 2001, 26, 853-893
18. Robeson, L. M. Polymer Membranes for Gas Separation Curr. Opin. Solid State Mater. Sci. 1999, 4, 549-552
19. Budd, P. M.; McKeown, N. B. Highly Permeable Polymers for Gas Separation Membranes Polym. Chem. 2010, 1, 63-68
20. Morisato, A.; Pinnau, I. Synthesis and Gas Permeation Properties of Poly(4-methyl-2-pentyne) J. Membr. Sci. 1996, 121, 243-250
21. Shao, L.; Samseth, J.; Hagg, M. B. Crosslinking and Stabilization of Nanoparticle Filled PMP Nanocomposite Membranes for Gas Separations J. Membr. Sci. 2009, 326, 285-292
22. Lee, J. N.; Park, C.; Whitesides, G. M. Solvent Compatibility of Poly(dimethylsiloxane)-Based Microfluidic Devices Anal. Chem. 2003, 75
23. Bi, J.; Simon, G. P.; Yamasaki, A.; Wang, C. L.; Kobayashi, Y.; Griesser, H. J. Effects of Solvent in the Casting of Poly(1-trimethylsilyl-1-propyne) Membranes Radiat. Phys. Chem. 2000, 58, 563-566
24. Claes, S.; Vandezande, P.; Mullens, S.; Adriaensens, P.; Peeters, R.; Maurer, F. H.; Bael, M. K. V. Crosslinked Poly[1-(trimethylsilyl)-1-propyne] Membranes: Characterization and Pervaporation of Aqueous Tetrahydrofuran Mixtures J. Membr. Sci. 2012, 389, 459-469
25. Feron, P. H. M.; Volkov, V. V.; Khotimsky, V. S.; Teplyakov, V. V. Membrane Gas Separation. US Patent 7,591,878, September 22, 2009.
26. Volkov, A. V.; Parashchuk, V. V.; Stamatialis, D. F.; Khotimsky, V. S.; Volkov, V. V.; Wessling, M. High Permeable PTMSP/PAN Composite Membranes for Solvent Nanofiltration J. Membr. Sci. 2009, 333, 88-93
27. Masuda, T.; Kawasaki, M.; Okano, Y.; Higashimura, T. Polymerization of Aliphatic Acetylenes -Polymerization of Methylpentynes by Transition-Metal Catalysts-Monomer Structure, Reactivity, and Polymer Properties Polym. J. 1982, 14, 371-377
28. Shao, L.; Samseth, J.; Hagg, M. B. Effect of Plasma Treatment on the Gas Permeability of Poly(4-methyl-2-pentyne) Membranes Plasma Process. Polym. 2007, 4, 823-831
29. Merkel, T. C.; Bondar, V. I.; Nagai, K.; Freeman, B. D.; Pinnau, I. Gas Sorption, Diffusion, and Permeation in Poly(dimethylsiloxane). J. Polym. Sci., Polym. Phys. 2000, 38.
30. 10 Permeability and Diffusivity in Poly(dimethylsiloxane) J. Membr. Sci. 2007, 306, 75-92
31. Toy, L. G.; Nagai, K.; Freeman, B. D.; Pinnau, I.; He, Z.; Masuda, T.; Teraguchi, M.; Yampolskii, Y. P. Pure-Gas and Vapor Permeation and Sorption Properties of Poly[1-phenyl-2-[p-(trimethylsilyl)phenyl]acetylene] (PTMSDPA) Macromolecules 2000, 33, 2516-2524
32. de Gennes, P.-G.; Brochard-Wyart, F.; Quere, D. Capillarity and Wetting Phenomena: Drops, Bubbles, Pearls, Waves; Springer: New York, 2004; p 120.
33. Demko, M. T.; Choi, S.; Zohdi, T. I.; Pisano, A. P. High Resolution Patterning of Nanoparticles by Evaporative Self-Assembly Enabled by in Situ Creation and Mechanical Lift-Off of a Polymer Template Appl. Phys. Lett. 2011, 99, 253102