Utilization of phosphinoamide ligands in homobimetallic Fe and Mn complexes: The effect of disparate coordination environments on metal-metal interactions and magnetic and redox properties

Inorganic Chemistry

Volumn 51, Issue 15, 2012, Pages 8225-8240

  Kuppuswamy, Subramaniam ^a   Bezpalko, Mark W ^a   Powers, Tamara M ^c   Turnbull, Mark M ^b   Foxman, Bruce M ^a   Thomas, Christine M ^a  

^a BRANDEIS UNIVERSITY   (United States)

^b CLARK UNIVERSITY   (United States)

^c HARVARD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE; COORDINATION COMPOUND; FERROUS ION; LIGAND; MANGANESE; PHOSPHINE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; INFRARED SPECTROPHOTOMETRY; MAGNETISM; MOSSBAUER SPECTROSCOPY; OXIDATION REDUCTION REACTION; TEMPERATURE; X RAY CRYSTALLOGRAPHY;

AMIDES; COORDINATION COMPLEXES; CRYSTALLOGRAPHY, X-RAY; FERROUS COMPOUNDS; LIGANDS; MAGNETIC PHENOMENA; MANGANESE; MODELS, MOLECULAR; OXIDATION-REDUCTION; PHOSPHINES; SPECTROPHOTOMETRY, INFRARED; SPECTROSCOPY, MOSSBAUER; TEMPERATURE;

EID: 84864609640     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic300776y     Document Type: Article

References (88)

1. Adams, R. D. and Cotton, F. A. Catalysis by Di- and Polynuclear Metal Cluster Complexes; Wiley-VCH: New York, NY, 1998.
2. Tsui, E. Y.; Kanady, J. S.; Day, M. W.; Agapie, T. Chem. Commun. 2011, 47, 4189-4191
3. Zhao, Q.; Harris, T. D.; Betley, T. A. J. Am. Chem. Soc. 2011, 133, 8293-8306
4. Zhao, Q.; Betley, T. A. Angew. Chem., Int. Ed. 2011, 50, 709-712
5. Powers, T. M.; Fout, A. R.; Zheng, S.-L.; Betley, T. A. J. Am. Chem. Soc. 2011, 133, 3336-3338
6. Eames, E. V.; Harris, T. D.; Betley, T. A. Chem. Sci. 2012, 3, 407-415
7. Harris, T. D.; Zhao, Q.; Sanchez, R. H.; Betley, T. A. Chem. Commun. 2011, 47, 6344-6346
8. Kanady, J. S.; Tsui, E. Y.; Day, M. W.; Agapie, T. Science 2011, 333, 733-736
9. Ragsdale, S. W. J. Inorg. Biochem. 2007, 101, 1657-1666
10. Lindahl, P. A.; Graham, D. E. Acetyl-coenzyme A Synthases and Nickel-Containing Carbon Monoxide Dehydrogenases. In Nickel and Its Surprising Impact in Nature; John Wiley & Sons, Ltd: Hoboken, NJ, 2007; pp 357-415.
11. Kim, E.; Chufan, E. E.; Kamaraj, K.; Karlin, K. D. Chem. Rev. 2004, 104, 1077-1134
12. Dismukes, G. C. Chem. Rev. 1996, 96, 2909-2926
13. Friedle, S.; Reisner, E.; Lippard, S. J. Chem. Soc. Rev. 2010, 39, 2768-2779
14. Merkx, M.; Kopp, D. A.; Sazinsky, M. H.; Blazyk, J. L.; Müller, J.; Lippard, S. J. Angew. Chem., Int. Ed. 2001, 40, 2782-2807
15. Tard, C.; Pickett, C. J. Chem. Rev. 2009, 109, 2245-2274
16. Fontecilla-Camps, J. C.; Volbeda, A.; Cavazza, C.; Nicolet, Y. Chem. Rev. 2007, 107, 4273-4303
17. Cotton, F. A.; Murillo, C. A.; Walton, R. A. Multiple Bonds Between Metal Atoms; Springer Science and Business Media, Inc.: New York, 2005.
18. Collman, J. P.; Boulatov, R. Angew. Chem., Int. Ed. 2002, 41, 3948-3961
19. Chisholm, M. H. Acc. Chem. Res. 1990, 23, 419-425
20. Gade, L. H. Angew. Chem., Int. Ed. 2000, 39, 2658-2678
21. Wheatley, N.; Kalck, P. Chem. Rev. 1999, 99, 3379-3420
22. Stephan, D. W. Coord. Chem. Rev. 1989, 95, 41-107
23. Bullock, R. M.; Casey, C. P. Acc. Chem. Res. 1987, 20, 167-173
24. Cooper, B. G.; Napoline, J. W.; Thomas, C. M. Catal. Rev.-Sci. Eng. 2012, 54, 1-40
25. Thomas, C. M. Comments Inorg. Chem. 2011, 32, 14-38
26. Greenwood, B. P.; Forman, S. I.; Rowe, G. T.; Chen, C.-H.; Foxman, B. M.; Thomas, C. M. Inorg. Chem. 2009, 48, 6251-6260
27. Greenwood, B. P.; Rowe, G. T.; Chen, C.-H.; Foxman, B. M.; Thomas, C. M. J. Am. Chem. Soc. 2010, 132, 44-45
28. Krogman, J. P.; Foxman, B. M.; Thomas, C. M. J. Am. Chem. Soc. 2011, 133, 14582-14585
29. Thomas, C. M.; Napoline, J. W.; Rowe, G. T.; Foxman, B. M. Chem. Commun. 2010, 46, 5790-5792
30. Zhou, W.; Napoline, J. W.; Thomas, C. M. Eur. J. Inorg. Chem. 2011, 2011, 2029-2033
31. Simona, M. Coord. Chem. Rev. 2009, 253, 1793-1832
32. Rosenthal, J.; Bachman, J.; Dempsey, J. L.; Esswein, A. J.; Gray, T. G.; Hodgkiss, J. M.; Manke, D. R.; Luckett, T. D.; Pistorio, B. J.; Veige, A. S.; Nocera, D. G. Coord. Chem. Rev. 2005, 249, 1316-1326
33. Gade, L. H. Angew. Chem., Int. Ed. Engl. 1996, 35, 2089-2090
34. Whittlesey, B. R. Coord. Chem. Rev. 2000, 206-207, 395-418
35. Xu, Z.; Lin, Z. Chem.-Eur. J. 1998, 4, 28-32
36. Lindahl, P. A. J. Inorg. Biochem. 2012, 106, 172-178
37. Nguyen, T.; Merrill, W. A.; Ni, C.; Lei, H.; Fettinger, J. C.; Ellis, B. D.; Long, G. J.; Brynda, M.; Power, P. P. Angew. Chem., Int. Ed. 2008, 47, 9115-9117
38. Hess, C. R.; Weyhermüller, T.; Bill, E.; Wieghardt, K. Angew. Chem., Int. Ed. 2009, 48, 3703-3706
39. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123-9135
40. Cotton, F. A.; Daniels, L. M.; Falvello, L. R.; Matonic, J. H.; Murillo, C. A. Inorg. Chim. Acta 1997, 256, 269-275
41. Cotton, F. A.; Daniels, L. M.; Matonic, J. H.; Murillo, C. A. Inorg. Chim. Acta 1997, 256, 277-282
42. Cotton, F. A.; Feng, X.; Murillo, C. A. Inorg. Chim. Acta 1997, 256, 303-308
43. Zall, C. M.; Zherebetskyy, D.; Dzubak, A. L.; Bill, E.; Gagliardi, L.; Lu, C. C. Inorg. Chem. 2012, 51, 728-736
44. Cotton, F. A.; Daniels, L. M.; Murillo, C. A. Inorg. Chim. Acta 1994, 224, 5-9
45. Timmer, G. H.; Berry, J. F. C.R. Chim. 2012, 15, 192-201
46. Fout, A. R.; Zhao, Q.; Xiao, D. J.; Betley, T. A. J. Am. Chem. Soc. 2011, 133, 16750-16753
47. Lu, D.-Y.; Yu, J.-S. K.; Kuo, T.-S.; Lee, G.-H.; Wang, Y.; Tsai, Y.-C. Angew. Chem., Int. Ed. 2011, 50, 7611-7615
48. Ashley, A. E.; Cooper, R. T.; Wildgoose, G. G.; Green, J. C.; O'Hare, D. J. Am. Chem. Soc. 2008, 130, 15662-15677
49. Chai, J.; Zhu, H.; Stuckl, A. C.; Roesky, H. W.; Magull, J.; Bencini, A.; Caneschi, A.; Gatteschi, D. J. Am. Chem. Soc. 2005, 127, 9201-9206
50. Hatnean, J. A.; Raturi, R.; Lefebvre, J.; Leznoff, D. B.; Lawes, G.; Johnson, S. A. J. Am. Chem. Soc. 2006, 128, 14992-14999
51. Kuppuswamy, S.; Cooper, B. G.; Bezpalko, M. W.; Foxman, B. M.; Powers, T. M.; Thomas, C. M. Inorg. Chem. 2012, 51, 1866-1873
52. Fenske, D.; Maczek, B.; Maczek, K. Z. Anorg. Allg. Chem. 1997, 623, 1113-1120
53. Thapa, I.; Gambarotta, S.; Korobkov, I.; Duchateau, R.; Kulangara, S. V.; Chevalier, R. Organometallics 2010, 29, 4080-4089
54. Poetschke, N.; Nieger, M.; Khan, M. A.; Niecke, E.; Ashby, M. T. Inorg. Chem. 1997, 36, 4087-4093
55. Lu, C. C.; Peters, J. C. Inorg. Chem. 2006, 45, 8597-8607
56. Pauling, L. The Nature of the Chemical Bond, 3 rd ed.; Cornell University Press: Ithaca, NY, 1960.
57. For completeness we include the van der Waals radii of Mn (2.05 A) and Fe (2.04 A): Hu., S.-Z.; Zhou, Z.-H.; Robertson, B. E. Z. Kristallogr. 2009, 224, 375-383
58. Brown, S. D.; Peters, J. C. J. Am. Chem. Soc. 2004, 126, 4538-4539
59. Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2004, 126, 6252-6254
60. Brown, S. D.; Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2002, 125, 322-323
61. Betley, T. A.; Peters, J. C. Inorg. Chem. 2003, 42, 5074-5084
62. Whited, M. T.; Rivard, E.; Peters, J. C. Chem. Commun. 2006, 1613-1615
63. Chomitz, W. A.; Mickenberg, S. F.; Arnold, J. Inorg. Chem. 2007, 47, 373-380
64. Adhikari, D.; Basuli, F.; Fan, H.; Huffman, J. C.; Pink, M.; Mindiola, D. J. Inorg. Chem. 2008, 47, 4439-4441
65. Buschhorn, D.; Pink, M.; Fan, H.; Caulton, K. G. Inorg. Chem. 2008, 47, 5129-5135
66. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Organometallics 1998, 17, 2313-2323
67. Schunemann, V.; Paulsen, H. Mossbauer Spectroscopy. In Applications of Physical Methods to Inorganic and Bioinorganic Chemistry; Scott, R. A.; Lukehart, C. M., Eds.; John Wiley & Sons, Ltd.: Hoboken, NJ, 2007; pp 241-269.
68. Evans, D. J.; Hughes, D. L.; Silver, J. Inorg. Chem. 1997, 36, 747-748
69. Sanakis, Y.; Power, P. P.; Stubna, A.; Munck, E. Inorg. Chem. 2002, 41, 2690-2696
70. MacDonnell, F. M.; Ruhlandt-Senge, K.; Ellison, J. J.; Holm, R. H.; Power, P. P. Inorg. Chem. 1995, 34, 1815-1822
71. Andres, H.; Bominaar, E. L.; Smith, J. M.; Eckert, N. A.; Holland, P. L.; Munck, E. J. Am. Chem. Soc. 2002, 124, 3012-3025
72. Hendrich, M. P.; Gunderson, W.; Behan, R. K.; Green, M. T.; Mehn, M. P.; Betley, T. A.; Lu, C. C.; Peters, J. C. Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 17107-17112
73. Thoreson, K. A.; Follett, A. D.; McNeill, K. Inorg. Chem. 2010, 49, 3942-3949
74. Sisler, H.; Smith, N. J. Org. Chem. 1961, 26, 611-613
75. Apex 2: Version 2 User Manual, M86-E01078; Bruker Analytical X-ray Systems: Madison, WI, 2006.
76. Evans, D. F. J. Chem. Soc. 1959, 2003-2005
77. Sur, S. K. J. Magn. Reson. 1989, 82, 169-173
78. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Braone, V.; Mennucci, B.; Petersson, G. A. et al. Gaussian 09, Revision A. 1; Gaussian, Inc.: Wallingford, CT, 2009.
79. Becke, A. D. Phys. Rev. A 1988, 38, 3098-3100
80. Perdew, J. P. Phys. Rev. B 1986, 33, 8822-8824
81. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 299-310
82. Roy, L. E.; Hay, P. J.; Martin, R. L. J. Chem. Theory Comput. 2008, 4, 1029-1031
83. Ehlers, A. W.; Bohme, M.; Dapprich, S.; Gobbi, A.; Hollwarth, A.; Jonas, V.; Kohler, K. F.; Stegmann, R.; Veldkamp, A.; Frenking, G. Chem. Phys. Lett. 1993, 208, 111-114
84. Dunning, T. H.; Hay, P. J. In Modern Theoretical Chemistry; Schaefer, H. F., Ed.; Plenum: New York, 1976; Vol. 3, pp 1-28.
85. Glendening, E. D.; Reed, A. E.; Carpenter, J. E. NBO Version 3.1.
86. Hall, M. B. F., R. F. Inorg. Chem. 1972, 11, 768-779
87. Bursten, B. E.; Jensen, J. R.; Fenske, R. F. J. Chem. Phys. 1978, 68, 3320
88. Manson, J.; Webster, C. E.; Perez, L. M.; Hall, M. B. http://www.chem.tamu.edu/jimp2/index.html.