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Volumn 47, Issue 11, 2008, Pages 4439-4441

P=N bond formation via incomplete N-atom transfer from a ferrous amide precursor

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE; FERROUS ION; NITROGEN; PHOSPHORUS;

EID: 46749114870     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic800182m     Document Type: Article
Times cited : (31)

References (32)
  • 10
    • 0141645556 scopus 로고    scopus 로고
    • Transient Fe imides have been proposed. (j) Jensen, M. P.; Mehn, M. P.; Que, L. Angew. Chem., Int. Ed. 2003, 42, 4357-4360.
    • Transient Fe imides have been proposed. (j) Jensen, M. P.; Mehn, M. P.; Que, L. Angew. Chem., Int. Ed. 2003, 42, 4357-4360.
  • 20
    • 41949118097 scopus 로고    scopus 로고
    • A stable Fe(IV) terminal nitride has been recently reported and structurally characterized: Vogel, C.; Heinemann, F. W.; Sutter, J.; Anthon, C.; Meyer, K. Angew. Chem., Int. Ed. 2008, 47, 2681-2684.
    • A stable Fe(IV) terminal nitride has been recently reported and structurally characterized: Vogel, C.; Heinemann, F. W.; Sutter, J.; Anthon, C.; Meyer, K. Angew. Chem., Int. Ed. 2008, 47, 2681-2684.
  • 22
    • 46749139939 scopus 로고    scopus 로고
    • See the Supporting Information for complete details
    • See the Supporting Information for complete details.
  • 24
    • 46749151854 scopus 로고    scopus 로고
    • Reference deleted at galley stage
    • Reference deleted at galley stage.
  • 27
    • 46749127423 scopus 로고    scopus 로고
    • Reference deleted at galley stage
    • Reference deleted at galley stage.
  • 28
    • 46749084315 scopus 로고    scopus 로고
    • Crystal data for 3·0.5C6H14: Orthorhombic, space group Pccn, a, 39.4630(7) Å b, 15.8829(3) Å, c, 19.1251(4) Å, V, 1987.4(4) Å3, Z, 8, μ(Mo Kα, 0.626 mm-1, Dc, 1.152 mg/mm3, GOF on F2, 1.179, R 1, 10.42, and wR2, 26.94, F2, all data, Data/restraints/parameters: 10 627/267/728. Out of a total of 66 852 reflections collected, 10 627 were unique (Rint, 9.71, and 9244 were observed with 7 > 2σI brown block, 0.22 x 0.17 x 0.15 mm, 25.07° ≥ θ ≥ 1.38°, The structure showed extensive disorder of the ligands and solvent, which was refined with a strong set of restraints and constraints to achieve convergence. The solvent carbon atoms remained isotropic. The structure was of marginal quality and should be unde
    • int = 9.71%) and 9244 were observed with 7 > 2σI (brown block, 0.22 x 0.17 x 0.15 mm, 25.07° ≥ θ ≥ 1.38°). The structure showed extensive disorder of the ligands and solvent, which was refined with a strong set of restraints and constraints to achieve convergence. The solvent carbon atoms remained isotropic. The structure was of marginal quality and should be understood as proof of connectivity only. A number of systematically weak reflections and considerable TDS were observed in the diffraction pattern. A larger cell that includes the weak reflections can be indexed, which might be in super-subcell relation with the chosen cell.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.