Assembly of triangular trimetallic complexes by triamidophosphine ligands: Spin-frustrated Mn2+ plaquettes and diamagnetic Mg2+ analogues with a combined through-space, through-bond pathway for 31P-31P spin-spin coupling

Journal of the American Chemical Society

Volumn 128, Issue 46, 2006, Pages 14992-14999

  Hatnean, Julian A ^a   Raturi, Ritu ^a   Lefebvre, Julie ^b   Leznoff, Daniel B ^b   Lawes, Gavin ^c   Johnson, Samuel A ^a  

^a UNIVERSITY OF WINDSOR   (Canada)

^b SIMON FRASER UNIVERSITY   (Canada)

^c WAYNE STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; MAGNETIC MOMENTS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARAMAGNETIC MATERIALS; PROBABILITY DENSITY FUNCTION;

LIGAND PRECURSORS; SPIN SPIN COUPLING; TRIAMIDOPHOSPHINE LIGANDS; TRIMETALLIC COMPLEXES;

ORGANOMETALLICS;

AMIDE; LIGAND; MAGNESIUM DERIVATIVE; MANGANESE DERIVATIVE; METAL COMPLEX; PHOSPHINE DERIVATIVE; PHOSPHORUS 31;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONDUCTANCE; CRYSTAL STRUCTURE; DIPOLE; GEOMETRY; MOLECULAR INTERACTION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 33845213336     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja065597i     Document Type: Article

References (98)

1. Toulouse, G. Commun. Phys. 1977, 2, 115-119.
2. (a) Greedan, J. E. J. Mater. Chem. 2001, 11, 37-53.
3. Ramirez, A. P. MRS Bull. 2005, 30, 447-451.
4. (b) Hopkinson, J.; Coleman, P. Phys. Rev. Lett. 2002, 89, 267201-267211.
5. Anderson, P. W. Science 1987, 235, 1196-1198.
6. Cannon, R. D.; White, R. P. Prog. Inorg. Chem. 1988, 36, 195-298.
7. (a) Cage, B.; Cotton, F. A.; Dalal, N. S.; Hillard, E. A.; Rakvin, B.; Ramsey, C. M. J. Am. Chem. Soc. 2003, 125, 5270-5271.
8. (b) Berry, J. F.; Cotton, F. A.; Liu, C. Y.; Lu, T.; Murillo, C. A.; Tsukerblat, B. S.; Villagran, D.; Wang, X. J. Am. Chem. Soc. 2005, 127, 4895-4902.
9. (c) Yoon, J.; Mirica, L. M.; Stack, T. D. P.; Solomon, E. I. J. Am. Chem. Soc. 2004, 126, 12586-12595.
10. (d) Telfer, S. G.; Kuroda, R.; Lefebvre, J.; Leznoff, D. B. Inorg. Chem. 2006, 45, 4592-4601.
11. (a) Harrison, A. J. Phys.; Condens. Matter 2004, 16, S553-S572.
12. (b) Moulton, B.; Lu, J.; Hajndl, R.; Hariharan, S.; Zaworotko, M. J. Angew. Chem., Int. Ed. 2002, 41, 2821-2824.
13. (c) Manson, J. L.; Ressouche, E.; Miller, J. S. Inorg. Chem. 2000, 39, 1135-1141.
14. Kahn, O. Molecular Magnetism; VCH: New York, 1993.
15. (a) Gatteschi, D. Adv. Mater. (Weinheim, Fed. Repub. Ger.) 1994, 6, 635-645.
16. (b) Itoh, K., Kinoshita, M., Eds. Molecular Magnetism: New Magnetic Materials; Gordon and Breach: Amsterdam, 2000.
17. (c) Miller, J. S., Drillon, M., Eds. Magnetism: Molecules to Materials; Wiley-VCH: New York, 2005.
18. (a) Putzer, M. A.; Pilz, A.; Mueller, U.; Neumueller, B.; Dehnicke, K. Z. Anorg. Allg. Chem. 1998, 624, 1336-1340.
19. (b) Putzer, M. A.; Neumueller, B.; Behnicke, K.; Magull, J. Chem. Ber. 1996, 129, 715-719.
20. (c) Belforte, A.; Calderazzo, F.; Englert, U.; Straehle, J.; Wurst, K. J. Chem. Soc., Dalton Trans. 1991, 2419-2427.
21. (d) Chen, H.; Olmstead, M. M.; Pestana, D. C.; Power, P. P, Inorg. Chem. 1991, 30, 1783-1787.
22. (e) Rouxel, J.; Chevalier, P. Bull. Soc. Chim. Fr. 1972, 111-114.
23. (f) Kennepohl, D. K.; Brooker, S.; Sheldrick, G. M.; Roesky, H. W. Z. Naturforsch., B: Chem. Sci. 1992, 47, 9-16.
24. (a) Alvarez, C. S.; Bond, A. D.; Cave, D.; Mosquera, M. E. G.; Harron, E. A.; Layfield, R. A.; McPartlin, M.; Rawson, J. M.; Wood, P. T.; Wright, D. S. Chem. Commun. 2002, 2980-2981.
25. (b) Alvarez, C. S.; Bashall, A.; Bond, A. D.; Cave, D.; Harron, E. A.; Layfield, R. A.; Mosquera, M. E. G.; McPartlin, M.; Rawson, J. M.; Wood, P. T.; Wright, D. S. J. Chem. Soc., Dalton Trans. 2003, 3002-3008.
26. (c) Crewdson, P.; Gambarotta, S.; Yap, G. P. A.; Thompson, L. K. Inorg. Chem. 2003, 42, 8579-8584.
27. Hua, H.; Elsmaili, M.; Johnson, S. Inorg. Chem. 2006, 45, 7435-7445.
28. Keen, A. L.; Doster, M.; Han, H.; Johnson, S. A. Chem. Commun. 2006, 1221-1223.
29. (a) Turculet, L.; Tilley, T. D. Organometallics 2002, 21, 3961-3972.
30. (b) Jia, L.; Ding, E.; Rheingold, A. L.; Rhatigan, B. Organometallics 2000, 19, 963-965.
31. (c) Gade, L. H. Acc. Chem. Res. 2002, 35, 575-582.
32. (d) Gade, L. H. J. Organomet. Chem. 2002, 661, 85-94.
33. (a) Fryzuk, M. D. Can. J. Chem. 1992, 70, 2839-2845.
34. (b) Fryzuk, M. D.; Johnson, S. A.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 11024-11025.
35. (c) Fryzuk, M. D.; Love, J. B.; Rettig, S. J. Chem. Commun. 1996, 2783-2784.
36. (d) Harkins, S. B.; Peters, J. C. J. Am. Chem. Soc. 2005, 127, 2030-2031.
37. (e) Liang, L.-C.; Lin, J.-M.; Hung, C.-H. Organometallics 2003, 22, 3007-3009.
38. (a) Boudalis, A. K.; Sanakis, Y.; Dahan, F.; Hendrich, M.; Tuchagues, J.-P. Inorg. Chem. 2006, 45, 443-453.
39. (b) Boudalis, A. K.; Sanakis, Y.; Raptopoulou, C. P.; Terzis, A.; Tuchagues, J.-P.; Perlepes, S. P. Polyhedron 2005, 24, 1540-1548.
40. (c) Kessissoglou, D. P. Coord. Chem. Rev. 1999, 185-186, 837-858.
41. (a) Godfrey, S. M.; McAuliffe, C. A.; Pritchard, R. G. J. Chem. Soc., Dalton Trans. 1993, 371-375.
42. (b) Hitchcock, P. B.; Lappert, M. F.; Leung, W. P.; Buttrus, N. H. J. Organomet. Chem. 1990, 394, 57-67.
43. Bessac, F.; Frenking, G. Inorg. Chem. 2006, 45, 6956-6964.
44. (a) Uryu, N.; Friedberg, S. A. Phys. Rev. A 1965, 140, 1803-1811.
45. (b) Sorai, M.; Tachiki, M.; Suga, H.; Seki, S. J. Phys. Soc. Jpn. 1971, 30, 750-759.
46. (c) Wrobleski, J. T.; Dziobkowski, C. T.; Brown, D. B. Inorg. Chem. 1981, 20, 684-686.
47. (d) Rakitin, Y. V.; Zhemchuzhnikova, T. A.; Zelentsov, V. V. Inorg. Chim. Acta 1977, 23, 145-148.
48. (e) Dubicki, L.; Day, P. Inorg. Chem. 1972, 11, 1868-1875.
49. (f) Jones, D. H.; Sams, J. R.; Thompson, R. C. J. Chem. Phys. 1984, 81, 440-447.
50. (g) Güdel, H. U. J. Chem. Phys. 1985, 82, 2510-2511.
51. For the static model, the anticipated distortion has been calculated to be approximately 0.01 Å: Murao, T. Phys. Lett. A 1974, 49A, 33-35.
52. Kahn, O. Chem. Phys. Lett. 1997, 265, 109-114.
53. Kambe, K. J. Phys. Soc. Jpn. 1950, 5, 48-51.
54. (a) Reynolds, R. A., III; Yu, W. O.; Dunham, W. R.; Coucouvanis, D. Inorg. Chem. 1996, 35, 2721-2722.
55. (b) Christian, P.; Rajaraman, G.; Harrison, A.; Helliwell, M.; McDouall, J. J. W.; Raftery, J.; Winpenny, R. E. P. J. Chem. Soc., Dalton Trans. 2004, 2550-2555.
56. (c) Lin, W.; Evans, O. R.; Yee, G. T. J. Solid State Chem. 2000, 152, 152-158.
57. (a) Tang, Y.; Zakharov, L. N.; Rheingold, A. L.; Kemp, R. A. Organometallics 2005, 24, 836-841.
58. (b) Bartlett, R. A.; Olmstead, M. M.; Power, P. P. Inorg. Chem. 1994, 33, 4800-4803.
59. (c) Bradley, D. C.; Hursthouse, M. B.; Ibrahim, A. A.; Abdul Malik, K. M.; Motevalli, M.; Moseler, R.; Powell, H.; Runnacles, J. D.; Sullivan, A. C. Polyhedron 1990, 9, 2959-2964.
60. (d) Clegg, W.; Frank, M.; Mulvey, R. E.; O'Neil, P. A. J. Chem. Soc., Chem. Commun. 1994, 97-98.
61. (e) Dozzi, G.; Del Piero, G.; Cesari, M.; Cucinella, S. J. Organomet. Chem. 1980, 190, 229-236.
62. (f) Duff, A. W.; Hitchcock, P. B.; Lappert, M. F.; Taylor, R. G.; Segal, J. A. J. Organomet. Chem. 1985, 293, 271-283.
63. (g) Han, R.; Parkin, G. Organometallics 1991, 10, 1010-1020.
64. (h) Henderson, K. W.; Mulvey, R. E.; Glegg, W.; O'Neil, P. A. J. Organomet. Chem. 1992, 439, 237-250.
65. (i) Henderson, K. W.; Mulvey, R. E.; Clegg, W.; O'Neil, P. A. Polyhedron 1993, 12, 2535-2538.
66. (j) Her, T. Y.; Chang, C. C.; Liu, L. K. Inorg. Chem. 1992, 31, 2291-2294.
67. (k) Holloway, C. E.; Melnik, M. J. Organomet. Chem. 1994, 465, 1-63.
68. (l) Kennedy, A. R.; Mulvey, R. E.; Schulte, J. H. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2001, C57, 1288-1289.
69. (m) Magnuson, V. R.; Stucky, G. D. Inorg. Chem. 1969, 8, 1427-1433.
70. (n) Sebestl, J. L.; Nadasdi, T. T.; Heeg, M. J.; Winter, C. H. Inorg. Chem. 1998, 37, 1289-1294.
71. (o) Vargas, W.; Englich, U.; Ruhlandt-Senge, K. Inorg. Chem. 2002, 41, 5602-5608.
72. (p) Westerhausen, M. Inorg. Chem. 1991, 30, 96-101.
73. (a) Pape, A.; Lutz, M.; Mueller, G. Angew. Chem., Int. Ed. Engl. 1994, 33, 2281-2284.
74. (b) Gindelberger, D. E.; Arnold, J. Inorg. Chem. 1994, 33, 6293-6299.
75. 3 hybridization of the orbitals participating in the N-C bond. Comparison with the methylene N-C bonds, where no delocalization of the lone pair can occur, allows for an approximate contribution to the difference in bond length that can be attributed to the difference in hybridization. The N(1-3)-C(1-3) bonds are on average 1.459(4) Å, whereas the N(4-6)-C(22-24) bond lengths are on average 1.481(4) Å, a difference of only 0.02 Å; this supports the partial double bond character of the terminal amido-ipso carbon bond.
76. Clegg, W.; Horsburgh, L.; Mulvey, R. E.; Ross, M. J.; Rowlings, R. B.; Wilson, V. Polyhedron 1998, 17, 1923-1930.
77. (a) Pastor, S. D.; Shum, S. P.; Rodebaugh, R. K.; Debellis, A. D.; Clarke, F. H. Helv. Chim. Acta 1993, 76, 900-914.
78. (b) Hierso, J.-C.; Fihri, A.; Ivanov, V. V.; Hanquet, B.; Pirio, N.; Donnadieu, B.; Rebiere, B.; Amardeil, R.; Meunier, P. J. Am. Chem. Soc. 2004, 126, 11077-11087.
79. (c) Kaupp, M.; Patrakov, A.; Reviakine, R.; Malkina, O. L. Chem. - Eur. J. 2005, 11, 2773-2782.
80. Mallory, F. B. J. Am. Chem. Soc. 1973, 95, 7747-7752.
81. Mallory, F. B.; Mallory, C. W.; Butler, K. E.; Lewis, M. B.; Xia, A. Q.; Luzik, E. D., Jr.; Fredenburgh, L. E.; Ramanjulu, M. M.; Van, Q. N.; Francl, M. M.; Freed, D. A.; Wray, C. C.; Hann, C.; Nerz-Stormes, M.; Carroll, P. J.; Chirlian, L. E. J. Am. Chem. Soc. 2000, 122, 4108-4116.
82. (a) Alkorta, I.; Elguero, J. Int. J. Mol. Sci. 2003, 4, 64-92.
83. (b) Diz, A. C.; Contreras, R. H.; Natiello, M. A.; Gavarini, H. O. J. Comput. Chem. 1985, 6, 647-651.
84. Schaftenaar, G. CAOS/CAMM Center; The University of Nijmegen: Nijmegen, The Netherlands, 1991.
85. Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518-1520.
86. (a) Andersen, R. A.; Faegri, K., Jr.; Green, J. C.; Haaland, A.; Lappert, M. F.; Leung, W. P.; Rypdal, K. Inorg. Chem. 1988, 27, 1782-1786.
87. (b) Buerger, H.; Wannagat, U. Monatsh. Chem. 1964, 95, 1099-1102.
88. Jaenschke, A.; Paap, J.; Behrens, U. Organometallics 2003, 22, 1167-1169.
89. SMART, Molecular analysis research tool; Bruker AXS Inc.: Madison, WI, 2001.
90. SAINTPlus, Data reduction and correction program; Bruker AXS Inc.: Madison, WI, 2001.
91. SADABS, An empirical absorption correction program; Bruker AXS Inc.: Madison, WI, 2001.
92. Altomare, A.; Burla, M. C.; Camalli, M.; Cascarano, G. L.; Giacovazzo, C.; Guagliardi, A.; Moliterni, A. G. G.; Polidori, G.; Spagna, R. J. Appl. Crystallogr. 1999, 32, 115-119.
93. Sheldrick, G. M. SHELXL-97; Universitat Gottingen: Gottingen, 1997.
94. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32, 837-838.
95. Van der Sluis, P.; Spek, A. L. Acta Crystallogr., Sect. A: Found. Crystallogr. 1990, A46, 194-201.
96. Farrugia, L. J. J. Appl. Crystallogr. 1997, 30, 565.
97. Becke, A. D. J. Chem. Phys. 1993, 98, 5648-5652.
98. Frisch, M. J.; et al. Gaussian 03, revision C.01; Gaussian, Inc.: Wallingford, CT, 2004.