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Volumn 14, Issue 5, 2012, Pages 1293-1297

Visible light photoredox organocatalysis: A fully transition metal-free direct asymmetric α-alkylation of aldehydes

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EID: 84860449806     PISSN: 14639262     EISSN: 14639270     Source Type: Journal    
DOI: 10.1039/c2gc35118h     Document Type: Article
Times cited : (143)

References (61)
  • 2
    • 34250729127 scopus 로고    scopus 로고
    • P. I. Dalko Chimia 2007 61 213-218.
    • (2007) Chimia , vol.61 , pp. 213-218
    • Dalko, P.I.1
  • 5
    • 77954046286 scopus 로고    scopus 로고
    • P. T. Anastas and R. H. CrabtreeWiley-VCH Verlag GmbH & Co. KGaA, Weinheim
    • I. McCort-Tranchepain, M. Petit and P. I. Dalko, in Handbook of Green Chemistry, ed. P. T. Anastas and R. H. Crabtree) Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2009, vol. 1, pp. 255–318.
    • (2009) Handbook of Green Chemistry , vol.1 , pp. 255-318
    • McCort-Tranchepain, I.1    Petit, M.2    Dalko, P.I.3
  • 58
    • 85034351302 scopus 로고    scopus 로고
    • For this reaction, the control of the temperature is essential. Using an energetic 1600 W xenon lamp (used in the lab for tertiary amine oxidation (see ref. 9)), a notable enhancement of the temperature (ΔT 30 °C) after 30 min of reaction, preferentially led to a dehalogenation pathway
    • For this reaction, the control of the temperature is essential. Using an energetic 1600 W xenon lamp (used in the lab for tertiary amine oxidation (see ref. 9)), a notable enhancement of the temperature (ΔT 30 °C) after 30 min of reaction, preferentially led to a dehalogenation pathway.
  • 59
    • 85034346368 scopus 로고    scopus 로고
    • See the ESI for further information on the triplet quantum yield
    • See the ESI for further information on the triplet quantum yield.
  • 61
    • 85034389503 scopus 로고    scopus 로고
    • “diffuse sunlight” means the ambient light typically obtained through a translucent glass window. The reaction was performed three times under various sunlight expositions, and same results (yield and ee) were observed
    • “diffuse sunlight” means the ambient light typically obtained through a translucent glass window. The reaction was performed three times under various sunlight expositions, and same results (yield and ee) were observed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.