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The experiments summarized in Table 1 were conducted in MeCN degassed by a freeze-pump-thaw cycle; however, we observe no loss of efficiency when a 20 min argon sparge is used to degas the solvent.
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The experiments summarized in Table 1 were conducted in MeCN degassed by a freeze-pump-thaw cycle; however, we observe no loss of efficiency when a 20 min argon sparge is used to degas the solvent.
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This result is also inconsistent with a mechanism involving direct triplet sensitization as in the Ru(bipy)32+-mediated valence isomerization of norbornadienes: Ikezawa, H, Kutal, C, Yasufuku, K, Yamazaki, H. J. Am. Chem. Soc. 1986, 108, 1589-1594
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