Delocalization-to-localization charge transition in diferrocenyl- oligothienylene-vinylene molecular wires as a function of the size by Raman spectroscopy

Journal of the American Chemical Society

Volumn 134, Issue 12, 2012, Pages 5675-5681

  Rodríguez González, Sandra ^a   Ruiz Delgado, M Carmen ^a   Caballero, Rubén ^b   De La Cruz, Pilar ^b   Langa, Fernando ^b   López Navarrete, Juan T ^a   Casado, Juan ^a  

^a UNIVERSITY OF MÁLAGA   (Spain)

^b UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

BOND LENGTH ALTERNATION; BOND-LENGTH EQUALIZATION; CHARGE RESONANCES; CONJUGATED STRUCTURES; HEXAMERS; LARGE SIZES; LOCALIZED STATE; MIXED VALENCE SYSTEMS; MIXED-VALENCE PROPERTIES; MOLECULAR WIRES; OCTAMERS; RAMAN FREQUENCIES; RAMAN MEASUREMENTS; RESONANCE RAMAN SPECTROSCOPY; SPECTROSCOPIC PROPERTY; STRUCTURE-PROPERTY CORRELATION; TETRAMERS; THEORETICAL MODELS; TURNING POINTS; VARIABLE TEMPERATURE;

CABLE STAYED BRIDGES; NANOWIRES; POSITIVE IONS; RAMAN SPECTROSCOPY;

DIMERS;

CATION; DIMER; FERROCENE DERIVATIVE; NANOWIRE; OCTAMER TRANSCRIPTION FACTOR; OLIGOMER; SOLVENT; TETRAMER; THIENYLENE VINYLENE DIFERROCENYL; UNCLASSIFIED DRUG; VINYL DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; ELECTROCHEMISTRY; MOLECULAR SIZE; OXIDATION; RAMAN SPECTROMETRY; TEMPERATURE; THEORETICAL MODEL;

EID: 84859130321     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3005607     Document Type: Article

References (57)

1. James, D. K.; Tour, J. M. Chem. Mater. 2004, 16, 4423
2. Klauk, H. Chem. Soc. Rev. 2010, 39, 2643
3. Perepichka, D. F.; Meng, H.; Wuld, F. Adv. Mater. 2005, 17, 2281
4. Allard, S.; Foster, M.; Souharce, B.; Thiem, H.; Scherf, U. Angew. Chem. Int. Ed. 2008, 47, 4070
5. Melzer, C.; Von Seggern, H. Nat. Mater. 2010, 9, 470
6. Hush, N. S. Prog. Inorg. Chem. 1967, 8, 391
7. Marcus, R. A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 26
8. Hoekstra, R. M.; Telo, J. P.; Wu, Q.; Stephenson, R. M.; Nelsen, S. F.; Zink, J. I. J. Am. Chem. Soc. 1997, 119, 10213
9. Bixon, M.; Joner, J. Adv. Chem. Phys. 1999, 106, 35
10. D'Alessandro, D. M.; Keene, F. R. Chem. Soc. Rev. 2006, 35, 424
11. Hankache, J.; Wenger, O. S. Chem. Rev. 2011, 111, 5138
12. Heckmann, A.; Lambert, C. Angew. Chem. Int. Ed. 2012, 51, 326
13. de Boer, E.; MacLean, C. J. Chem. Phys. 1966, 44, 1334
14. Elliot, C. M.; Derr, D. L.; Matyushov, D. V.; Newton, M. D. J. Am. Chem. Soc. 1998, 120, 11714
15. Heinen, U.; Berthold, T.; Kothe, G.; Stavitski, E.; Galili, T; Levanon, H.; Wiederrecht, G.; Wasielewski, M. R. J. Phys. Chem. A 2002, 106, 1933
16. Nelsen, S. F.; Ismagilov, R. F.; Gentile, K. E.; Powell, D. R. J. Am. Chem. Soc. 1997, 119, 10213
17. Ito, T.; Hamaguchi, T.; Nagino, H.; Yamaguchi, T.; Washington, J.; Kubiak, C. P. Science 1997, 277, 660
18. Demadis, K. D.; Hartshorn, C. M.; Meyer, T. J. Chem. Rev. 2001, 101, 2655
19. Coropceanu, V.; Cornil, J.; da Silva Filho, D. A.; Oliver, Y.; Silbey, R.; Brédas, J.-L. Chem. Rev. 2007, 107, 926
20. Heckmann, A.; Amthor, S.; Lambert, C. Chem. Commun. 2006, 2959
21. Robin, M. B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247
22. Brunschwig, B. S.; Creutz, C.; Sutin, N. Chem. Soc. Rev. 2002, 31, 168
23. Lacroix, J. C.; Chane-Ching, K. I.; Maquére, F.; Maurel, F. J. Am. Chem. Soc. 2006, 128, 7264
24. Lambert, C.; Nöll, G.; Schelter, J. Nat. Mater. 2002, 1, 69
25. Nelsen, S. F.; Konradsson, A. E.; Telo, J. P. J. Am. Chem. Soc. 2005, 127, 920
26. Mishra, A.; Ma, C.-Q.; Bäuerle, P. Chem. Rev. 2009, 109, 1141
27. Perepichka, I. F.; Perepichka, D. F.; Meng, H.; Wuld, F. Adv. Mater. 2005, 17, 2281
28. Roncali, J. Chem. Rev. 1997, 97, 173
29. Handbook of Thiophene-Based Materials. Applications in Organic Electronics and Photonics; Perepichka, I. F.; Perepichka, D. F., Eds.; Wiley: Chichester, 2009.
30. Brédas, J.-L. J. Chem. Phys. 1985, 82, 3808
31. Brédas, J.-L.; Themans, B.; Fripiat, J. P.; André, J. M.; Chance, R. R. Phys. Rev. B 1984, 29, 6761
32. Cammi, R.; Mennucci, B.; Tomasi, B, J. J. Am. Chem. Soc. 1994, 116, 2619
33. Castiglioni, C.; Zoppoi, M.; Zerbi, G. J. Raman Spectrosc. 1993, 24, 485
34. Castiglioni, C.; Tommasini, M.; Zerbi, G. Philos. Trans. R. Soc. London A 2004, 362, 2425
35. The Raman Effect: A Unified Treatment of the Theory of Raman Scattering by Molecules; Long, A. D., Ed.; John Wiley & Sons: West Sussex, England, 2002.
36. Josowics, M.; Tolber, L. M. J. Am. Chem. Soc. 2010, 132, 10374
37. Tolbert, L. M.; Zhao, X.; Ding, Y.; Bottomley, L. A. J. Am. Chem. Soc. 1995, 117, 12891
38. Casado, J.; Rodríguez González, S.; Ruiz Delgado, M. C.; Moreno Oliva, M.; López Navarrete, J. T.; Caballero, R.; de la Cruz, P.; Langa, F. Chem.-Eur. J. 2009, 15, 2548
39. Roncali, J. Acc. Chem. Res. 2000, 33, 147
40. Jestin, I.; Frère, I. P.; Blanchard, P.; Roncali, J. Angew. Chem., Int. Ed. 1998, 37, 942
41. Oswald, F.; Shafiqul Islam, D.-M.; Araki, Y.; Troiani, V.; de la Cruz, P.; Moreno, A.; Ito, O.; Langa, F. Chem.-Eur. J. 2007, 13, 3924
42. Becke, A. D. J. Chem. Phys. 1993, 98, 5648
43. Lee, C. T.; Yang, W. T.; Parr, R. G. Phys. Rev. B 1988, 37, 785
44. Frisch, M. J.,; Gaussian 09, Revision A.02; Gaussian, Inc.: Wallingford CT, 2009.
45. Harihara, P. C.; Pople, J. A. Theor. Chim. Acta 1973, 28, 213
46. Hehre, W. J.; Ditchfield, R.; Pople, J. A. J. Chem. Phys. 1972, 56, 2257
47. Francl, M. M.; Pietro, W. J.; Hehre, W. J.; Binkley, J. S.; Gordon, M. S.; Defrees, D. J.; Pople, J. A. J. Chem. Phys. 1982, 77, 3654
48. Scott, A. P.; Radom, L. J. Phys. Chem. 1996, 100, 16502
49. Brédas, J. L.; Beljonne, D.; Coropceanu, V.; Cornil J. Chem. Rev. 2004, 104, 4971
50. Hernández, V.; Casado, J.; Ramírez, F. J.; Zotti, G.; Hotta, S.; López Navarrete, J. T. J. Chem. Phys. 1996, 104, 9271
51. Casado, J.; Hernández, V.; Hotta, S.; López Navarrete, J. T. J. Chem. Phys. 1998, 109, 10419
52. Casado, J.; Hernández, V.; Hotta, S.; López Navarrete, J. T. Adv. Mater. 1998, 10, 1458
53. Casado, J.; Takimiya, K.; Otsubo, T.; Ramírez, F. J.; Quirante, J. J.; Ponce Ortiz, R.; Rodríguez González, S.; Moreno Oliva, M.; López Navarrete, J. T. J. Am. Chem. Soc. 2008, 130, 14028
54. Casado, J.; Hernández, V.; López Navarrete, J. T.; Viruela, P. M.; Ortí, E.; Takimiya, K.; Otsubo, T. Angew. Chem., Int. Ed. 2007, 46, 9057
55. Leng, W.; Würthner, F.; Meyers Kelly, A. J. Phys. Chem. A 2005, 109, 1570
56. Koopmans, T. Physica 1934, 1, 101
57. Casado, J.; Hernández, V.; Ruiz Delgado, M. C.; Ponce Ortiz, R; López Navarrete, J. T.; Facchetti, J. A.; Marks, T. J. Am. Chem. Soc. 2005, 127, 13364