Thionium ion initiated medium-sized ring formation: The total synthesis of asteriscunolide D

Journal of the American Chemical Society

Volumn 134, Issue 3, 2012, Pages 1474-1477

  Trost, Barry M ^a   Burns, Aaron C ^a   Bartlett, Mark J ^a   Tautz, Thomas ^a   Weiss, Andrew H ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALIPHATIC ALDEHYDES; BUTENOLIDES; DIASTEREOSELECTIVE; E-OLEFIN; ENANTIOSELECTIVE ADDITION; MACROCYCLES; NATURAL PRODUCTS; PROTECTING GROUP; RING FORMATION; STEREOSPECIFIC; THIOETHERS; TOTAL SYNTHESIS;

ACETYLENE; ALDEHYDES; OLEFINS;

CATALYSIS;

ALDEHYDE; ALKENE; ALKYNE; ASTERISCUNOLIDE D; HUMULENE DERIVATIVE; MACROCYCLIC COMPOUND; SULFIDE; UNCLASSIFIED DRUG;

ALDOL REACTION; ARTICLE; CYCLIZATION; ENANTIOSELECTIVITY; STEREOCHEMISTRY; STEREOSPECIFICITY; SYNTHESIS;

ASTERACEAE; BIOLOGICAL AGENTS; CYCLIZATION; IONS; LACTONES; QUATERNARY AMMONIUM COMPOUNDS; SESQUITERPENES; STEREOISOMERISM;

EID: 84856295370     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja210986f     Document Type: Article

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