Highly enantioselective synthesis of γ-hydroxy-α,β- acetylenic esters catalyzed by a β-sulfonamide alcohol

Organic Letters

Volumn 9, Issue 12, 2007, Pages 2329-2332

  Lin, Li ^a   Jiang, Xianxing ^a   Liu, Weixia ^a   Qiu, Li ^a   Xu, Zhaoqing ^a   Xu, Jiangke ^a   Chan, Albert S C ^b   Wang, Rui ^a,b  

^a LANZHOU UNIVERSITY   (China)

^b HONG KONG POLYTECHNIC UNIVERSITY   (Hong Kong)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; ALKYNE; ESTER; ORGANOMETALLIC COMPOUND; SULFONAMIDE; TITANIUM;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALCOHOLS; ALKYNES; CATALYSIS; ESTERS; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM; SULFONAMIDES; TITANIUM;

EID: 34250792753     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol070692x     Document Type: Article

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40. In Step 1, which needed 16 h for the BINOL-Ti catalytic system, and 7 h for our catalytic system.
41. We are grateful for the reviewers who gave us some good advice. The side reaction is under investigation.