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Volumn 88, Issue 11, 2011, Pages 1695-1708

High-resolution NMR spectroscopy: An alternative fast tool for qualitative and quantitative analysis of diacylglycerol (DAG) oil

Author keywords

Composition; Diacylglycerol oil; NMR spectroscopy

Indexed keywords

ACYL CHAIN; ACYLGLYCEROLS; DIACYLGLYCEROL; DOUBLE BONDS; FAST TOOL; HIGH RESOLUTION; HSQC-TOCSY; LINOLENIC ACIDS; MULTIDIMENSIONAL NMR; NMR SPECTRUM; NMR TECHNIQUES; OIL COMPOSITION; QUALITATIVE AND QUANTITATIVE ANALYSIS; RELATIVE POSITIONS; TRIACYLGLYCEROLS;

EID: 84855652760     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-011-1848-2     Document Type: Article
Times cited : (69)

References (41)
  • 4
    • 2442570631 scopus 로고    scopus 로고
    • Lipase-catalysed production and chemical composition of diacylglycerols from soybean oil deodoriser distillate
    • DOI 10.1002/ejlt.200300888
    • Lo SK, Baharin BS, Tan CP, Laia OM (2004) Lipase-catalysed production and chemical composition of diacylglycerols from soybean oil deodoriser distillate. Eur J Lipid Sci Technol 106:218-224 (Pubitemid 38648588)
    • (2004) European Journal of Lipid Science and Technology , vol.106 , Issue.4 , pp. 218-224
    • Lo, S.K.1    Baharin, B.S.2    Tan, C.P.3    Lai, O.M.4
  • 5
    • 84855681592 scopus 로고    scopus 로고
    • Determination of mono- and diglycerides by capillary gas chromatography, Method Cd 11b-91
    • AOCS, 5th edn, AOCS press, Champaign
    • AOCS (2003) Determination of mono- and diglycerides by capillary gas chromatography, Method Cd 11b-91. In: Official Methods and Recommended Practices of the American Oil Chemists, 5th edn, AOCS press, Champaign
    • (2003) Official Methods and Recommended Practices of the American Oil Chemists
  • 7
    • 0000359722 scopus 로고    scopus 로고
    • 1H and 13C NMR of virgin oil. An overview
    • Sacchi R, Addeo F, Paolillo L (1997) 1H and 13C NMR of virgin oil. An overview. Magn Reson Chem 35:5133-5145
    • (1997) Magn Reson Chem , vol.35 , pp. 5133-5145
    • Sacchi, R.1    Addeo, F.2    Paolillo, L.3
  • 8
  • 9
    • 0032741144 scopus 로고    scopus 로고
    • 13C NMR study
    • DOI 10.1016/S0009-3084(99)00092-4, PII S0009308499000924
    • Mannina L, Luchinat C, Emanuele MC, Segre A (1999) Acyl positional distribution of glycerol tri-esters in vegetable oils: a 13C NMR study. Chem Phys Lipids 103:47-55 (Pubitemid 29492860)
    • (1999) Chemistry and Physics of Lipids , vol.103 , Issue.1-2 , pp. 47-55
    • Mannina, L.1    Luchinat, C.2    Emanuele, M.C.3    Segre, A.4
  • 10
    • 0033625095 scopus 로고    scopus 로고
    • 31P NMR spectroscopy in food analysis. 1. Quantitative determination of the mono- and diglyceride composition of olive oils
    • DOI 10.1021/jf9910990
    • Spyros A, Dais P (2000) Application of 31P NMR spectroscopy in food analysis. I. Quantitative determination of the mono- and diglyceride composition of olive oils. J Agric Food Chem 48:802-805 (Pubitemid 30194008)
    • (2000) Journal of Agricultural and Food Chemistry , vol.48 , Issue.3 , pp. 802-805
    • Spyros, A.1    Dais, P.2
  • 11
    • 34247545259 scopus 로고    scopus 로고
    • 31P NMR spectroscopy in the quality control and authentication of virgin olive oil. An account of recent results
    • Dais P, Spyros A (2007) 31P NMR spectroscopy in the quality control and authentication of virgin olive oil. An account of recent results. Magn Reson Chem 45:367-377
    • (2007) Magn Reson Chem , vol.45 , pp. 367-377
    • Dais, P.1    Spyros, A.2
  • 12
    • 77950595354 scopus 로고    scopus 로고
    • A facile NMR method for the quantification of total, free and esterified sterols in virgin olive oil
    • Hatzakis E, Dagounakis G, Agiomyrgianaki A, Dais P (2010) A facile NMR method for the quantification of total, free and esterified sterols in virgin olive oil. Food Chem 122:346-352
    • (2010) Food Chem , vol.122 , pp. 346-352
    • Hatzakis, E.1    Dagounakis, G.2    Agiomyrgianaki, A.3    Dais, P.4
  • 13
    • 0000406592 scopus 로고
    • Cyclic organophosphorus compounds. I. Synthesis and infrared spectral studies of cyclic hydrogen phosphites and thiophosphites
    • Zwierzak A (1967) Cyclic organophosphorus compounds. I. Synthesis and infrared spectral studies of cyclic hydrogen phosphites and thiophosphites. Can J Chem 45:2501-2512
    • (1967) Can J Chem , vol.45 , pp. 2501-2512
    • Zwierzak, A.1
  • 14
    • 0002701007 scopus 로고
    • Carbon-13 nuclear spin relaxation
    • Levy GC (ed) Wiley, New York, Chapter 3
    • Lyerla JR, Levy, GC (1974) Carbon-13 nuclear spin relaxation. In: Levy GC (ed) Topics in carbon-13 NMR spectroscopy. Wiley, New York, Chapter 3, pp 100-101
    • (1974) Topics in carbon-13 NMR Spectroscopy , pp. 100-101
    • Lyerla, J.R.1    Levy, G.C.2
  • 15
    • 49649132112 scopus 로고
    • Proton-decoupled NMR Spectra of carbon-13 with the nuclear Overhauser effect suppressed
    • Freeman R, Hill HDW, Kaptein R (1976) Proton-decoupled NMR. Spectra of carbon-13 with the nuclear Overhauser effect suppressed. J Magn Reson 7:327-329
    • (1976) J Magn Reson , vol.7 , pp. 327-329
    • Freeman, R.1    Hill, H.D.W.2    Kaptein, R.3
  • 17
    • 0001074789 scopus 로고    scopus 로고
    • Improved Sensitivity in Gradient-Based 1D and 2D Multiplicity-Edited HSQC Experiments
    • Parella T, Sanchez-Ferrando F, Virgili A (1997) Improved sensitivity in gradient-based 1D and 2D multiplicity edited HSQC experiments. J Magn Reson 126:274-277 (Pubitemid 127451919)
    • (1997) Journal of Magnetic Resonance , vol.126 , Issue.2 , pp. 274-277
    • Parella, T.1    Sanchez-Ferrando, F.2    Virgili, A.3
  • 19
    • 0141795516 scopus 로고    scopus 로고
    • 1H nuclear magnetic resonance as a fast tool for determining the composition of acyl chains in acylglycerol mixtures
    • Guillén MD, Ruiz A (2003) 1H nuclear magnetic resonance as a fast tool for determining the composition of acyl chains in acylglycerol mixtures. Eur J Lipid Sci Technol 105:502-505
    • (2003) Eur J Lipid Sci Technol , vol.105 , pp. 502-505
    • Guillén, M.D.1    Ruiz, A.2
  • 20
    • 0041833738 scopus 로고    scopus 로고
    • Classification of edible oils by employing 31P and 1H NMR Spectroscopy in combination with multivariate statistical analysis. A proposal for detection of seed oils adulteration in virgin olive oils
    • Vigli G, Philippidis A, Spyros A, Dais P (2003) Classification of edible oils by employing 31P and 1H NMR Spectroscopy in combination with multivariate statistical analysis. A proposal for detection of seed oils adulteration in virgin olive oils. J Agric Food Chem 51:5715-5722
    • (2003) J Agric Food Chem , vol.51 , pp. 5715-5722
    • Vigli, G.1    Philippidis, A.2    Spyros, A.3    Dais, P.4
  • 23
    • 0000663897 scopus 로고
    • Rapid 1HNMR determination of 1,2 and 1,3 diglycerides in virgin olive oils
    • Sacchi R, Paolillo L, Giudicianni I, Addeo (1991) Rapid 1HNMR determination of 1,2 and 1,3 diglycerides in virgin olive oils. Ital J Food Sci 4:245-262
    • (1991) Ital J Food Sci , vol.4 , pp. 245-262
    • Sacchi, R.1    Paolillo, L.2    Giudicianni, I.3    Addeo4
  • 24
    • 24244434833 scopus 로고
    • Proton magnetic resonance identification of nonconjugated cis-unsaturated fatty acids and esters
    • Frost DJ, Barzilay J (1971) Proton magnetic resonance identification of nonconjugated cis-unsaturated fatty acids and esters. Anal Chem 43:1316-1318
    • (1971) Anal Chem , vol.43 , pp. 1316-1318
    • Frost, D.J.1    Barzilay, J.2
  • 25
    • 0025796960 scopus 로고
    • 13C NMR studies of mono-, di-, and triacylglycerols leading to qualitative and semiquantitative information about mixtures of these glycerol esters
    • Gunstone FD (1991) 13C NMR studies of mono-, di-, and triacylglycerols leading to qualitative and semiquantitative information about mixtures of these glycerol esters. Chem Phys Lipids 58:219-224
    • (1991) Chem Phys Lipids , vol.58 , pp. 219-224
    • Gunstone, F.D.1
  • 26
    • 0002060240 scopus 로고
    • High resolution 13C NMR spectroscopy of lipids
    • Christie WW (ed), 2nd edn. The Oily Press, Dundee
    • Gunstone FD (1993) High resolution 13C NMR spectroscopy of lipids. In: Christie WW (ed) Advances in lipid methodology, 2nd edn. The Oily Press, Dundee, pp 1-68
    • (1993) Advances in Lipid Methodology , pp. 1-68
    • Gunstone, F.D.1
  • 27
    • 0025478245 scopus 로고
    • Quantitative high resolution 13C nuclear magnetic resonance of the olefinic and carbonyl carbons of edible vegetable oils
    • Wollemberg KF (1990) Quantitative high resolution 13C nuclear magnetic resonance of the olefinic and carbonyl carbons of edible vegetable oils. J Am Oil Chem Soc 67:487-494
    • (1990) J Am Oil Chem Soc , vol.67 , pp. 487-494
    • Wollemberg, K.F.1
  • 28
    • 0030727356 scopus 로고    scopus 로고
    • High-resolution nuclear magnetic resonance spectroscopy - Applications to fatty acids and triacylglycerols
    • DOI 10.1007/s11745-997-0132-y
    • Lie Ken Jie MSF, Mustafa J (1997) High-resolution nuclear magnetic resonance spectroscopy - applications to fatty acids and triacylglycerols. Lipids 32:1019-1034 (Pubitemid 27459409)
    • (1997) Lipids , vol.32 , Issue.10 , pp. 1019-1034
    • Lie Ken Jie, M.S.F.1    Mustafa, J.2
  • 29
    • 0001306612 scopus 로고    scopus 로고
    • Quantitative 13C NMR method using DEPT pulse sequence for the determination of the geographical origin (DOP) of olive oils
    • Vlahov G, Schiavone C, Simone N (2001) Quantitative 13C NMR method using DEPT pulse sequence for the determination of the geographical origin (DOP) of olive oils. Magn Reson Chem 39:689-695
    • (2001) Magn Reson Chem , vol.39 , pp. 689-695
    • Vlahov, G.1    Schiavone, C.2    Simone, N.3
  • 30
    • 0036890087 scopus 로고    scopus 로고
    • Using simple 13C linewidth and relaxation measurements to make detailed chemical shift assignments in triacylglycerols and related compounds
    • Alenamy LB (2002) Using simple 13C linewidth and relaxation measurements to make detailed chemical shift assignments in triacylglycerols and related compounds. Chem Phys Lipids 120:33-44
    • (2002) Chem Phys Lipids , vol.120 , pp. 33-44
    • Alenamy, L.B.1
  • 31
    • 0036500747 scopus 로고    scopus 로고
    • 13C NMR spectroscopy using chromatographically obtained oil fractions
    • J10064
    • Zamora R, Gómez G, Hidalgo FJ (2002) Classification of vegetable oils by high-resolution 13C NMR spectroscopy using chromatographically obtained oil fractions. J Am Oil Chem Soc 79:267-272 (Pubitemid 34265990)
    • (2002) JAOCS, Journal of the American Oil Chemists' Society , vol.79 , Issue.3 , pp. 267-272
    • Zamora, R.1    Gomez, G.2    Hidalgo, F.J.3
  • 32
    • 0242498768 scopus 로고    scopus 로고
    • Alternative NMR method for quantitative determination of acyl positional distribution in triacylglycerols and related compounds
    • DOI 10.1016/j.chemphyslip.2003.08.003
    • Simonova S, Ivanova G, Spassov SL (2003) Alternative NMR method for quantitative determination of acyl positional distribution in triacylglycerols and related compounds. Chem Phys Lipids 126:167-176 (Pubitemid 37410392)
    • (2003) Chemistry and Physics of Lipids , vol.126 , Issue.2 , pp. 167-176
    • Simova, S.1    Ivanova, G.2    Spassov, S.L.3
  • 33
    • 77954892243 scopus 로고    scopus 로고
    • 13C NMR spectroscopy for determining the acylglycerol positional composition of lampante olive oils. Chemical shift assignments and their dependence on sample concentration
    • Vlahov G, Giuliani AA, Del Re P (2010) 13C NMR spectroscopy for determining the acylglycerol positional composition of lampante olive oils. Chemical shift assignments and their dependence on sample concentration. Anal Methods 2:916-923
    • (2010) Anal Methods , vol.2 , pp. 916-923
    • Vlahov, G.1    Giuliani, A.A.2    Del Re, P.3
  • 34
    • 0012375706 scopus 로고
    • The specific distribution of unsaturated fatty acids in the triglycerides of plants
    • Mattson FH, Volpenhein RA (1963) The specific distribution of unsaturated fatty acids in the triglycerides of plants. J Lipid Res 4:392-396
    • (1963) J Lipid Res , vol.4 , pp. 392-396
    • Mattson, F.H.1    Volpenhein, R.A.2
  • 35
    • 17244379237 scopus 로고    scopus 로고
    • 13C nuclear magnetic resonance spectroscopy to check 1,3-random, 2-random pattern of fatty acid distribution in olive oil triacylglycerols
    • Vlahov G (2005) 13C nuclear magnetic resonance spectroscopy to check 1,3-random, 2-random pattern for fatty acid distribution in olive oil triacylglycerols. Spectroscopy 19:109-117 (Pubitemid 40529104)
    • (2005) Spectroscopy , vol.19 , Issue.2 , pp. 109-117
    • Vlahov, G.1
  • 36
    • 0032364068 scopus 로고    scopus 로고
    • Assignment of mono- and polyunsaturated fatty acids in lipids of tissues and body fluids
    • Willker W, Leibfritz D (1998) Assignment of mono- and polyunsaturated fatty acids in lipids of tissues and body fluids. Magn Reson Chem 36:S79-S84
    • (1998) Magn Reson Chem , vol.36
    • Willker, W.1    Leibfritz, D.2
  • 37
    • 0032143635 scopus 로고    scopus 로고
    • 13C assignments and structural elucidation of n-3 polyunsaturated fatty acids by the use of a new 2D NMR technique: SAPHIR-HSQC
    • DOI 10.1016/S0009-3084(98)00059-0, PII S0009308498000590
    • Vatele JM, Fenet B, Eynard T (1998) Complete 13C assignment and structural elucidation of n-3 polyunsaturated fatty acids by the use of a new 2D NMR technique SAPHIR-HSQC. Chem Phys Lipids 94:239-250 (Pubitemid 28448473)
    • (1998) Chemistry and Physics of Lipids , vol.94 , Issue.2 , pp. 239-250
    • Vatele, J.-M.1    Fenet, B.2    Eynard, T.3
  • 38
    • 12944265405 scopus 로고    scopus 로고
    • 1H NMR: Development and potential of a method for natural products analysis
    • DOI 10.1021/np0497301
    • Pauli GF, Jaki BU, Lankin DC (2005) Quantitative 1H NMR: development and potential of a method for natural products analysis. J Nat Prod 68:133-149 (Pubitemid 40175949)
    • (2005) Journal of Natural Products , vol.68 , Issue.1 , pp. 133-149
    • Pauli, G.F.1    Jaki, B.U.2    Lankin, D.C.3
  • 39
    • 0001784184 scopus 로고
    • Some quantitative applications of 13C NMR spectroscopy
    • Shoolery JN (1976) Some quantitative applications of 13C NMR spectroscopy. Progr NMR Spectrosc 11:79-93
    • (1976) Progr NMR Spectrosc , vol.11 , pp. 79-93
    • Shoolery, J.N.1
  • 40
    • 0032392718 scopus 로고    scopus 로고
    • Regiospecific analysis of natural mixtures of triglycerides using quantitative 13C nuclear magnetic resonance of acyl chain carbons
    • Vlahov G (1998) Regiospecific analysis of natural mixtures of triglycerides using quantitative 13C nuclear magnetic resonance of acyl chain carbons. Magn Reson Chem 36:359-362
    • (1998) Magn Reson Chem , vol.36 , pp. 359-362
    • Vlahov, G.1
  • 41
    • 84855700206 scopus 로고
    • Rotational dynamics of flexible-chain molecules. 13C NMR relaxation study of hydrocarbon chains attached to a heavy anchor
    • Dais P (1989) Rotational dynamics of flexible-chain molecules. 13C NMR relaxation study of hydrocarbon chains attached to a heavy anchor. Magn Reson Chem 27:61-67
    • (1989) Magn Reson Chem , vol.27 , pp. 61-67
    • Dais, P.1


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