Transformation of coordinated dinitrogen by reaction with dihydrogen and primary silanes

Science

Volumn 275, Issue 5305, 1997, Pages 1445-1447

  Fryzuk, Michael D ^a   Love, Jason B ^a   Rettig, Steven J ^a   Young, Victor G ^b  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

^b University of Minnesota ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

NITROGEN; SILANE DERIVATIVE;

ARTICLE; ENZYME SUBSTRATE COMPLEX; MOLECULAR INTERACTION; NITROGEN FIXATION; NONHUMAN; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 0031039732     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.275.5305.1445     Document Type: Article

References (39)

1. S. Gambarotta, J. Organomet. Chem. 500, 117 (1995).
2. G. Ertl, in Catalytic Ammonia Synthesis, J. R. Jennings, Eds. (Plenum, New York, 1991).
3. M. K. Chan et al., Science 260, 792 (1993).
4. G. J. Leigh, ibid. 268, 827 (1995); C. E. LaPlaza and C. C. Cummins, ibid., p. 861; M. Hidai and Y. Mizobe, Chem. Rev. 95, 1115 (1995); G. J. Leigh, J. Mol. Catal. 47, 363 (1988); R. A. Henderson, Transition Met. Chem. 15, 330 (1990); _, G. J. Leigh, C. J. Pickett, Adv. Inorg. Chem. Radiochem. 27, 197 (1983); J. Chatt, J. R. Dilworth, R. L. Richards, Chem. Rev. 78, 589 (1978).
5. G. J. Leigh, ibid. 268, 827 (1995); C. E. LaPlaza and C. C. Cummins, ibid., p. 861; M. Hidai and Y. Mizobe, Chem. Rev. 95, 1115 (1995); G. J. Leigh, J. Mol. Catal. 47, 363 (1988); R. A. Henderson, Transition Met. Chem. 15, 330 (1990); _, G. J. Leigh, C. J. Pickett, Adv. Inorg. Chem. Radiochem. 27, 197 (1983); J. Chatt, J. R. Dilworth, R. L. Richards, Chem. Rev. 78, 589 (1978).
6. G. J. Leigh, ibid. 268, 827 (1995); C. E. LaPlaza and C. C. Cummins, ibid., p. 861; M. Hidai and Y. Mizobe, Chem. Rev. 95, 1115 (1995); G. J. Leigh, J. Mol. Catal. 47, 363 (1988); R. A. Henderson, Transition Met. Chem. 15, 330 (1990); _, G. J. Leigh, C. J. Pickett, Adv. Inorg. Chem. Radiochem. 27, 197 (1983); J. Chatt, J. R. Dilworth, R. L. Richards, Chem. Rev. 78, 589 (1978).
7. G. J. Leigh, ibid. 268, 827 (1995); C. E. LaPlaza and C. C. Cummins, ibid., p. 861; M. Hidai and Y. Mizobe, Chem. Rev. 95, 1115 (1995); G. J. Leigh, J. Mol. Catal. 47, 363 (1988); R. A. Henderson, Transition Met. Chem. 15, 330 (1990); _, G. J. Leigh, C. J. Pickett, Adv. Inorg. Chem. Radiochem. 27, 197 (1983); J. Chatt, J. R. Dilworth, R. L. Richards, Chem. Rev. 78, 589 (1978).
8. G. J. Leigh, ibid. 268, 827 (1995); C. E. LaPlaza and C. C. Cummins, ibid., p. 861; M. Hidai and Y. Mizobe, Chem. Rev. 95, 1115 (1995); G. J. Leigh, J. Mol. Catal. 47, 363 (1988); R. A. Henderson, Transition Met. Chem. 15, 330 (1990); _, G. J. Leigh, C. J. Pickett, Adv. Inorg. Chem. Radiochem. 27, 197 (1983); J. Chatt, J. R. Dilworth, R. L. Richards, Chem. Rev. 78, 589 (1978).
9. G. J. Leigh, ibid. 268, 827 (1995); C. E. LaPlaza and C. C. Cummins, ibid., p. 861; M. Hidai and Y. Mizobe, Chem. Rev. 95, 1115 (1995); G. J. Leigh, J. Mol. Catal. 47, 363 (1988); R. A. Henderson, Transition Met. Chem. 15, 330 (1990); _, G. J. Leigh, C. J. Pickett, Adv. Inorg. Chem. Radiochem. 27, 197 (1983); J. Chatt, J. R. Dilworth, R. L. Richards, Chem. Rev. 78, 589 (1978).
10. G. J. Leigh, ibid. 268, 827 (1995); C. E. LaPlaza and C. C. Cummins, ibid., p. 861; M. Hidai and Y. Mizobe, Chem. Rev. 95, 1115 (1995); G. J. Leigh, J. Mol. Catal. 47, 363 (1988); R. A. Henderson, Transition Met. Chem. 15, 330 (1990); _, G. J. Leigh, C. J. Pickett, Adv. Inorg. Chem. Radiochem. 27, 197 (1983); J. Chatt, J. R. Dilworth, R. L. Richards, Chem. Rev. 78, 589 (1978).
11. G. J. Leigh, Acc. Chem. Res. 25, 177 (1992); B. B. Kaul, R. K. Hayes, T. A. George, J. Am. Chem. Soc. 112, 2002 (1990), and references therein.
12. G. J. Leigh, Acc. Chem. Res. 25, 177 (1992); B. B. Kaul, R. K. Hayes, T. A. George, J. Am. Chem. Soc. 112, 2002 (1990), and references therein.
13. J. Chatt, G. A. Heath, G. J. Leigh, Chem. Commun. 1972, 444 (1972); H. M. Colquhoun, Acc. Chem. Res. 17, 23 (1984); Y. Ishii, M. Kawaguchi, Y. Ishino, T. Aoki, M. Hidai, Organometallics 13, 5062 (1994); K. Komori, H. Oshita, Y. Mizobe, M. Hidai, J. Am. Chem. Soc. 111, 1939 (1989); H. Seino, Y. Ishii, T. Sasagawa, M. Hidai, ibid. 117, 12181 (1995).
14. J. Chatt, G. A. Heath, G. J. Leigh, Chem. Commun. 1972, 444 (1972); H. M. Colquhoun, Acc. Chem. Res. 17, 23 (1984); Y. Ishii, M. Kawaguchi, Y. Ishino, T. Aoki, M. Hidai, Organometallics 13, 5062 (1994); K. Komori, H. Oshita, Y. Mizobe, M. Hidai, J. Am. Chem. Soc. 111, 1939 (1989); H. Seino, Y. Ishii, T. Sasagawa, M. Hidai, ibid. 117, 12181 (1995).
15. J. Chatt, G. A. Heath, G. J. Leigh, Chem. Commun. 1972, 444 (1972); H. M. Colquhoun, Acc. Chem. Res. 17, 23 (1984); Y. Ishii, M. Kawaguchi, Y. Ishino, T. Aoki, M. Hidai, Organometallics 13, 5062 (1994); K. Komori, H. Oshita, Y. Mizobe, M. Hidai, J. Am. Chem. Soc. 111, 1939 (1989); H. Seino, Y. Ishii, T. Sasagawa, M. Hidai, ibid. 117, 12181 (1995).
16. J. Chatt, G. A. Heath, G. J. Leigh, Chem. Commun. 1972, 444 (1972); H. M. Colquhoun, Acc. Chem. Res. 17, 23 (1984); Y. Ishii, M. Kawaguchi, Y. Ishino, T. Aoki, M. Hidai, Organometallics 13, 5062 (1994); K. Komori, H. Oshita, Y. Mizobe, M. Hidai, J. Am. Chem. Soc. 111, 1939 (1989); H. Seino, Y. Ishii, T. Sasagawa, M. Hidai, ibid. 117, 12181 (1995).
17. J. Chatt, G. A. Heath, G. J. Leigh, Chem. Commun. 1972, 444 (1972); H. M. Colquhoun, Acc. Chem. Res. 17, 23 (1984); Y. Ishii, M. Kawaguchi, Y. Ishino, T. Aoki, M. Hidai, Organometallics 13, 5062 (1994); K. Komori, H. Oshita, Y. Mizobe, M. Hidai, J. Am. Chem. Soc. 111, 1939 (1989); H. Seino, Y. Ishii, T. Sasagawa, M. Hidai, ibid. 117, 12181 (1995).
18. J. M. Manriquez, D. R. McAlister, R. D. Sanner, J. E. Bercaw, J. Am. Chem. Soc. 100, 2716 (1978).
19. M. Hidai, K. Tominari, Y. Uchida, ibid. 94, 110 (1972); T. A. George and R. C. Tisdale, Inorg. Chem. 27, 2909 (1988).
20. M. Hidai, K. Tominari, Y. Uchida, ibid. 94, 110 (1972); T. A. George and R. C. Tisdale, Inorg. Chem. 27, 2909 (1988).
21. M. D. Fryzuk, M. Mylvaganam, J. D. Cohen, T. M. Loehr, J. Am. Chem. Soc. 116, 9529 (1994); M. D. Fryzuk, T. S. Haddad, M. Mylvaganam, D. H. McConville, S. J. Rettig, ibid. 115, 2782 (1993).
22. M. D. Fryzuk, M. Mylvaganam, J. D. Cohen, T. M. Loehr, J. Am. Chem. Soc. 116, 9529 (1994); M. D. Fryzuk, T. S. Haddad, M. Mylvaganam, D. H. McConville, S. J. Rettig, ibid. 115, 2782 (1993).
23. M. D. Fryzuk, J. B. Love, S. J. Rettig, Chem. Commun. 1996, 2783 (1996).
24. w = 0.1223.
25. L. E. Sutton, Tables of Interatomic Distances and Configuration in Molecules and Ions (Chemical Society Spec. Publ. 11, Chemical Society, London, 1958).
26. M. R. Smith III, T.-Y. Cheng, G. L. Hillhouse, J. Am. Chem. Soc. 115, 8638 (1993).
27. G. J. Kubas, Acc. Chem. Res. 21, 120 (1988).
28. P. G. Jessop and R. H. Morris, Coord. Chem. Rev. 121, 155 (1992).
29. J. E. Gozum and G. S. Girolami, J. Am. Chem. Soc. 113, 3829 (1991); J. E. Gozum, S. R. Wilson, G. S. Girolami, ibid. 114, 9483 (1992).
30. J. E. Gozum and G. S. Girolami, J. Am. Chem. Soc. 113, 3829 (1991); J. E. Gozum, S. R. Wilson, G. S. Girolami, ibid. 114, 9483 (1992).
31. H. H. Brintzinger, J. Organomet. Chem. 171, 337 (1979).
32. J. P. Collman et al., J. Am. Chem. Soc. 112, 8206 (1990).
33. Z. He, S. Nefedov, N. Lugan, D. Neibecker, R. Mathieu, Organometallics 12, 3837 (1993); C. Hampton, W. R. Cullen, B. R. James, J. Am. Chem. Soc. 110, 6918 (1988); T. Arliguie, B. Chaudret, R. H. Morris, A. Sella, Inorg. Chem. 27, 598 (1988).
34. Z. He, S. Nefedov, N. Lugan, D. Neibecker, R. Mathieu, Organometallics 12, 3837 (1993); C. Hampton, W. R. Cullen, B. R. James, J. Am. Chem. Soc. 110, 6918 (1988); T. Arliguie, B. Chaudret, R. H. Morris, A. Sella, Inorg. Chem. 27, 598 (1988).
35. Z. He, S. Nefedov, N. Lugan, D. Neibecker, R. Mathieu, Organometallics 12, 3837 (1993); C. Hampton, W. R. Cullen, B. R. James, J. Am. Chem. Soc. 110, 6918 (1988); T. Arliguie, B. Chaudret, R. H. Morris, A. Sella, Inorg. Chem. 27, 598 (1988).
36. X.-L. Luo et al., J. Am. Chem. Soc. 116, 10312 (1994); Ibid. 117, 1159 (1995); J. J. Schneider, Angew. Chem. Int. Ed. Engl. 35, 1068 (1996).
37. X.-L. Luo et al., J. Am. Chem. Soc. 116, 10312 (1994); Ibid. 117, 1159 (1995); J. J. Schneider, Angew. Chem. Int. Ed. Engl. 35, 1068 (1996).
38. X.-L. Luo et al., J. Am. Chem. Soc. 116, 10312 (1994); Ibid. 117, 1159 (1995); J. J. Schneider, Angew. Chem. Int. Ed. Engl. 35, 1068 (1996).
39. Funding for this research was generously provided by the Natural Sciences and Engineering Research Council of Canada.