The unusual electronic structure of dinitrosyl iron complexes

Journal of the American Chemical Society

Volumn 132, Issue 11, 2010, Pages 3646-3647

  Ye, Shengfa ^a   Neese, Frank ^a  

^a UNIVERSITY OF BONN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIFERRO-MAGNETICALLY COUPLED; ANTIFERROMAGNETICS; CHEMICAL EQUATIONS; COVALENT BONDING; D ORBITALS; DENSITY FUNCTIONALS; ELECTRON ACCEPTOR; FERROUS ION; IRON CENTERS; IRON COMPLEX; IRON-SULFUR CLUSTERS; LIGAND FIELD SPLITTING; ONE-ELECTRON REDUCTIONS; REASSEMBLY; RESONANCE HYBRID; SALIENT FEATURES; SPECTROSCOPIC PARAMETERS;

ANTIFERROMAGNETISM; COMPLEXATION; DEGRADATION; ELECTRONIC PROPERTIES; ELECTRONIC STRUCTURE; HYDRAULIC STRUCTURES; IRON; IRON COMPOUNDS; PARAMAGNETIC RESONANCE; SPECTROSCOPIC ANALYSIS; SULFUR;

LIGANDS;

DINITROSYL IRON COMPLEX; FERROUS ION; IRON COMPLEX; LIGAND; NITRIC OXIDE; SULFUR; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; COVALENT BOND; DENSITY; ELECTRICITY; ELECTRON; HYBRID; MAGNETISM; SPECTROSCOPY; VALIDITY;

ELECTRONS; IRON; MODELS, MOLECULAR; MOLECULAR CONFORMATION; NITROGEN OXIDES; THERMODYNAMICS;

EID: 77949871593     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9091616     Document Type: Article

References (28)

1. (a) Murad, F. Angew. Chem. Int. Ed. 1999, 38, 1856-1868.
2. (b) Furchgott, R. F. Angew. Chem., Int. Ed. 1999, 38, 1870-1880.
3. (c) Ignarro, L. J. Angew. Chem., Int. Ed. 1999, 38, 1882-1892.
4. (a) Sellers, V. M.; Johnson, M. K.; Dailey, H. A. Biochemistry 1996, 35, 2699-2704.
5. (b) Foster, M. W.; Cowan, J. A. J. Am. Chem. Soc. 1999, 121, 4093-4100.
6. (a) Ding, H.; Demple, B. Proc. Natl. Acad. Sci. U.S.A. 2000, 97, 5146-5150.
7. (b) Rogers, P. A.; Ding, H. J. Biol. Chem. 2001, 276, 30980-30986.
8. (c) Yang, W.; Rogers, P. A.; Ding, H. J. Biol. Chem. 2002, 277, 12868-12873.
9. (a) Tsai, M.-L.; Chen, C.-C.; Hsu, I.-J.; Ke, S.-C.; Hsieh, C.-H.; Chiang, K.-A.; Lee, G.-H.; Wang, Y.; Chen, J.-M.; Lee, J.-F.; Liaw, W.-F. Inore. Chem. 2004, 43, 5159-5167.
10. (b) Harrop, T. C.; Tonzetich, Z. J.; Reisner, E.; Lippard, S. J. J. Am. Chem. Soc. 2008, 130, 15602-15610.
11. (c) Lu, T.-T.; Huang, H.-W.; Liaw, W,-F. Inorg. Chem. 2009, 48, 9027-9035.
12. (d) Tonzetich Z. J.; Do, L. H.; Lippard, M. J. J. A m. Chem. Soc. 2009, 131, 7964-7965.
13. Dai, R. J.; Ke, S. C. J. Phys. Chem. B 2007, 111, 2335-2346.
14. (a) Bryar, T. R.; Eaton, D. R. Can. J. Chem. 1992, 70, 1917-1926.
15. (b) Butler, A. R.; Megson, I. L. Chem. Rev. 2002, 102, 1155-1165.
16. (a) Hopmann, K. H.; Ghosh, A.; Noodleman, L. Inorg. Chem. 2009, 48, 9155-9165.
17. (b) Tsai, M.-C.; Tsai, F.-T.; Lu, T.-T.; Tsai, M.-L.; Wei, Y.-C.; Hsu, I.-J.; Lee, J.-F.; Liaw, W.-F. Inorg. Chem. 2009, 48, 9579-9591.
18. Enemark, J. H.; Feltham, R. D. Coord, Chem. Rev. 1974, 13, 339-406.
19. Gütlich, P.; Link, R.; Trautwem, A. X. Mössbauer Spectroscopy and Transtion Metal Chemistry; Springer-Verlag: Berlin, 1978.
20. (a) Becke, A. D. Phys. Rev. A 1988, 38, 3098-3100.
21. (b) Perdew, J. P. Phys. Rev. B 1986, 34, 7406.
22. (a) Tao, J.; Perdew, J. P.; Staroverov, V. N.; Scuseria, G. E. Phys. Rev. Lett. 2003, 91, 146401.
23. (b) Perdew, J. P.; Tao, J.; Staroverov, V. N.; Scuseria, G. E. J. Chem. Phys. 2004, 120, 6898-6911.
24. (a) Becke, A. D. J. Chem. Phys. 1993, 98, 5648-5652.
25. (b) Lee, C. T.; Yang, W. T.; Parr, R. G. Phys. Rev. B 1988, 37, 785-789.
26. Staroverov, V. N.; Scuseria, G. E.; Tao., J.; Perdew, J. P. J. Chem. Phys. 2003, 119, 12129-12137.
27. Atkinson, F. L.; Blackwell, H. E.; Brown, N. C.; Connelly, N. G.; Crossley, J. G.; Orpen, A. G.; Rieger, A. L.; Rieger, P. H. J. Chem. Soc., Dalton Trans. 1996, 3491-3502.
28. Li, M.; Bonnet, D.; Bill, E.; Neese, F.; Weyhermtiller, T.; Blum, N.; Sellmann, D.; Wiegliardt, K. Inorg. Chem. 2002, 41, 3444-3456.