Expanding Mg-Zn hybrid chemistry: Inorganic salt effects in addition reactions of organozinc reagents to trifluoroacetophenone and the implications for a synergistic lithium-magnesium-zinc activation

Chemistry - A European Journal

Volumn 17, Issue 30, 2011, Pages 8333-8341

  Armstrong, David R ^a   Clegg, William ^b   García Úlvarez, Pablo ^c   Kennedy, Alan R ^a   McCall, Matthew D ^a   Russo, Luca ^b   Hevia, Eva ^a  

^a UNIVERSITY OF STRATHCLYDE   (United Kingdom)

^b NEWCASTLE UNIVERSITY   (United Kingdom)

^c UNIVERSITY OF OVIEDO   (Spain)

Author keywords

addition reactions; cooperative effects; Grignard reaction; magnesium; salt effect; zincates

Indexed keywords

CHEMO-SELECTIVITY; COOPERATIVE EFFECTS; DFT CALCULATION; EQUIMOLAR AMOUNT; GRIGNARD REACTION; GRIGNARD REAGENT; HYBRID CHEMISTRY; INORGANIC SALTS; METATHESIS REACTIONS; ORGANIC TRANSFORMATIONS; ORGANOLITHIUMS; ORGANOZINC COMPOUNDS; ORGANOZINC REAGENTS; SALT EFFECT; STRUCTURAL MOTIFS; SYNERGISTIC EFFECT; THEORETICAL MODELLING; TRIFLUOROACETOPHENONE; ZINC PRECURSOR; ZINCATES;

ADDITION REACTIONS; CHEMICAL REACTIVITY; CHLORINE; KETONES; LITHIUM; LITHIUM COMPOUNDS; MAGNESIUM; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

ZINC;

EID: 79960326704     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201100866     Document Type: Article

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