Mild, single-pot hydrocarboxylation of linear C5-C9 alkanes into branched monocarboxylic C6-C10 acids in copper-catalyzed aqueous systems

Applied Catalysis A: General

Volumn 401, Issue 1-2, 2011, Pages 106-113

  Kirillova, Marina V ^a   Kirillov, Alexander M ^a   Pombeiro, Armando J L ^a  

^a INSTITUTO SUPERIOR TÉCNICO   (Portugal)

Author keywords

Alkanes; Aqueous medium; C C bond formation; C H activation; Carboxylation; Carboxylic acids; Copper; Homogeneous catalysis

Indexed keywords

AQUEOUS MEDIUM; AQUEOUS SYSTEM; C-C BOND FORMATION; C-H ACTIVATION; CARBON ATOMS; FREE RADICAL MECHANISM; FUNCTIONALIZATIONS; HOMOGENEOUS CATALYSIS; HOMOGENEOUS CATALYST; HYDROCARBOXYLATION; LOW TEMPERATURES; N-HEPTANES; N-HEXANE; N-NONANE; N-OCTANES; N-PENTANE; POTASSIUM PEROXODISULFATE; SELECTIVITY PARAMETERS; TOTAL YIELD;

ACTIVATION ANALYSIS; CARBON MONOXIDE; CARBOXYLATION; CARBOXYLIC ACIDS; CATALYSIS; CHEMICAL BONDS; FREE RADICALS; HEPTANE; HEXANE; ORGANIC SOLVENTS; POTASSIUM; REACTION KINETICS;

PARAFFINS;

EID: 79959758971     PISSN: 0926860X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apcata.2011.05.009     Document Type: Article

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