Remarkably fast oxidation of alkanes by hydrogen peroxide catalyzed by a tetracopper(II) triethanolaminate complex: Promoting effects of acid co-catalysts and water, kinetic and mechanistic features

Journal of Catalysis

Volumn 268, Issue 1, 2009, Pages 26-38

  Kirillova, Marina V ^a   Kozlov, Yuriy N ^b   Shul'pina, Lidia S ^c   Lyakin, Oleg Y ^d   Kirillov, Alexander M ^a   Talsi, Evgenii P ^d   Pombeiro, Armando J L ^a   Shul'pin, Georgiy B ^b  

^a INSTITUTO SUPERIOR TÉCNICO   (Portugal)

^b SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

^c A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^d BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

Author keywords

Acid promoters; Alkanes oxidation; Copper complexes; Cyclohexane; Homogeneous catalysis; Hydrogen peroxide; Water

Indexed keywords

ALKANE MOLECULES; ALKANE OXIDATION; CO CATALYSTS; COCATALYST; COPPER COMPLEXES; EXPERIMENTAL KINETICS; FAST OXIDATION; HOMOGENEOUS CATALYSIS; HYDROPEROXIDES; HYDROXYL RADICALS; KEY FACTORS; OXIDATION OF CYCLOHEXANE; PROMOTING EFFECT; ROLE OF WATER; SECOND-ORDER REACTION; SECONDARY PRODUCT; TRIFLUOROACETIC ACIDS; TURNOVER FREQUENCY;

ACETONITRILE; ACIDS; CATALYSIS; CATALYST SELECTIVITY; COMPLEXATION; COPPER COMPOUNDS; CYCLOHEXANE; FREE RADICAL REACTIONS; HYDROGEN; HYDROGEN PEROXIDE; KETONES; ORGANIC SOLVENTS; OXIDATION; OXYGENATION; PARAFFINS; SULFURIC ACID;

REACTION KINETICS;

EID: 71549139793     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2009.08.016     Document Type: Article

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