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Owing to the large number of significant studies using SECM, it is impossible to cite them all, yet the following exemplify the wide variety of experimental topics and main groups concerned
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Owing to the large number of significant studies using SECM, it is impossible to cite them all, yet the following exemplify the wide variety of experimental topics and main groups concerned: Salles, M. O.; Battistel, D.; Lima, A. S.; Bertotti, M.; Daniele, S. Electroanalysis 2011, 23, 595-603
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For a similar situation enforced within a confined microfluidic channel compare the following
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For a similar situation enforced within a confined microfluidic channel compare the following: Fosdick, S. E.; Crooks, J. A.; Chang, B. Y.; Crooks, R. M. J. Am. Chem. Soc. 2010, 132, 9226-9227
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We use the term "perfect collector" to enforce the view that it may perform over its whole probed area of importance for the diffusional coupling with the tip as a biased collecting electrode whose potential is poised on the redox plateau of the species to be recycled ("Red" in Figure 4). (4c) This corresponds to the boundary condition imposed in the present theories of SECM developed for reversible charge transfers and infinitely sized conducting substrates. (7)
-
We use the term "perfect collector" to enforce the view that it may perform over its whole probed area of importance for the diffusional coupling with the tip as a biased collecting electrode whose potential is poised on the redox plateau of the species to be recycled ("Red" in Figure 4). (4c) This corresponds to the boundary condition imposed in the present theories of SECM developed for reversible charge transfers and infinitely sized conducting substrates. (7)
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See, e.g
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For previous reports of a similar concentration-focusing strategy used in another context, see:;; Faraday Discuss. 1992, 94, 37-44
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For a description of the experimental difficulty of precisely knowing the tip-substrate distance at short L values and avoiding tilt angles, see, e.g
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