Scope and mechanism for Lewis acid-catalyzed cycloadditions of aldehydes and donor-acceptor cyclopropanes: Evidence for a stereospecific intimate ion pair pathway

Journal of the American Chemical Society

Volumn 130, Issue 27, 2008, Pages 8642-8650

  Pohlhaus, Patrick D ^a   Sanders, Shanina D ^a   Parsons, Andrew T ^a   Li, Wei ^a   Johnson, Jeffrey S ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; MECHANISMS; ORGANIC COMPOUNDS;

AMERICAN CHEMICAL SOCIETY (ACS); CYCLOADDITIONS; DIASTEREOSELECTIVE SYNTHESIS; DONOR ACCEPTOR (D A); DONOR SITE; EXPERIMENTAL EVIDENCE; HIGH FIDELITY; ION PAIRS; LEWIS ACIDS; MALONATE; OPTICALLY ACTIVE; REACTION PARTNERS; STEREOCHEMICAL ANALYSIS; STEREOSPECIFIC SYNTHESIS; TETRAHYDROFURAN (PTHF); TETRAHYDROFURANS (THF);

PROPANE;

ALDEHYDE; CYCLOPROPANE DERIVATIVE; LEWIS ACID; MALONIC ACID; TETRAHYDROFURAN; TIN;

ARTICLE; CATALYSIS; CYCLOADDITION; ENANTIOMER; REACTION ANALYSIS; STEREOCHEMISTRY; STEREOSPECIFICITY; SYNTHESIS;

ALDEHYDES; BENZALDEHYDES; CATALYSIS; CYCLOPROPANES; FURANS; MESYLATES; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 46949091089     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8015928     Document Type: Article

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