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Volumn 50, Issue 17, 2011, Pages 3938-3942

Mild and selective H/D exchange at the β position of aromatic α-olefins by N-heterocyclic carbene-hydride-rhodium catalysts

Author keywords

H D exchange; hydride ligands; N heterocyclic carbene; rhodium; steric induction

Indexed keywords

H/D EXCHANGE; HYDRIDE COMPLEXES; HYDRIDE LIGANDS; N-HETEROCYCLIC CARBENES; QUINOLINATE; RHODIUM CATALYSTS; SELECTIVE CATALYSTS; STERIC INDUCTION;

EID: 79954582418     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201007238     Document Type: Article
Times cited : (73)

References (54)
  • 45
    • 79954597424 scopus 로고    scopus 로고
    • A similar high-field signal and unusually high H-Rh coupling has been observed in related rhodium-hydride complexes with a vacant site in the trans position. For examples, see
    • A similar high-field signal and unusually high H-Rh coupling has been observed in related rhodium-hydride complexes with a vacant site in the trans position. For examples, see
  • 49
    • 79954573963 scopus 로고    scopus 로고
    • note
    • 2)=0.0987, GoF=1.042 (9202 unique); CCDC-784690 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via.
  • 50
    • 79954586956 scopus 로고    scopus 로고
    • 1/2 is the turn-over frequency at 50% of H/D exchange
    • 1/2 is the turn-over frequency at 50% of H/D exchange.
  • 51
    • 79954596160 scopus 로고    scopus 로고
    • 13C NMR data
    • 13C NMR data.
  • 54
    • 79954624057 scopus 로고    scopus 로고
    • 6]acetone
    • 6]acetone.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.