메뉴 건너뛰기




Volumn 28, Issue 18, 2009, Pages 5316-5322

Quantitative assay for the direct comparison of platinum catalysts in benzene H/D exchange

Author keywords

[No Author keywords available]

Indexed keywords

BIDENTATE LIGANDS; CHLORIDE COMPLEXES; DIIMINES; H/D EXCHANGE; NITROGEN-DONOR LIGANDS; PLATINUM CATALYSTS; PRECATALYSTS; PT CATALYSTS; PT COMPLEXES; QUANTITATIVE ASSAY; RELATIVE REACTIVITIES; TRIDENTATE LIGANDS; TURNOVER NUMBER;

EID: 70349319979     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900495n     Document Type: Article
Times cited : (45)

References (50)
  • 25
    • 21844451374 scopus 로고    scopus 로고
    • For a review of C-H activation at Pt(II), see: and references therein.
    • For a review of C-H activation at Pt(II), see: Lersch, M.; Tilset, M. Chem. Rev. 2005, 105, 2471, and references therein.
    • (2005) Chem. Rev. , vol.105 , pp. 2471
    • Lersch, M.1    Tilset, M.2
  • 41
    • 84869604290 scopus 로고    scopus 로고
    • 4 as well as some residual DMF from recrystallization.
    • 4 as well as some residual DMF from recrystallization.
  • 42
    • 70349365505 scopus 로고    scopus 로고
    • A number of additional Ag salts were screened in this reaction (see Supporting Information for details). Notably, AgTFA afforded essentially identical results to AgOAc; therefore we utilized the less expensive Ag salt for these transformations.
    • A number of additional Ag salts were screened in this reaction (see Supporting Information for details). Notably, AgTFA afforded essentially identical results to AgOAc; therefore we utilized the less expensive Ag salt for these transformations.
  • 45
    • 84869615449 scopus 로고    scopus 로고
    • 1 were corrected by subtraction of the % deuterium incorporation observed in the background reaction between TFA-rfi and C6H6 in the presence of AgCl.
    • 1 were corrected by subtraction of the % deuterium incorporation observed in the background reaction between TFA-rfi and C6H6 in the presence of AgCl.
  • 46
    • 70349362205 scopus 로고    scopus 로고
    • The apparently lower TONs observed at extended times are an artifact of subtraction of the AgCl background reaction at the respective time points.
    • The apparently lower TONs observed at extended times are an artifact of subtraction of the AgCl background reaction at the respective time points.
  • 47
    • 84869615450 scopus 로고    scopus 로고
    • 2 also catalyze this reaction, but the addition of a mineral acid is required. See ref 10 for details.
    • 2 also catalyze this reaction, but the addition of a mineral acid is required. See ref 10 for details.
  • 48
    • 84869615447 scopus 로고    scopus 로고
    • 3 under our standard conditions.
    • 3 under our standard conditions.
  • 49
    • 84869614223 scopus 로고    scopus 로고
    • 3 because this solvent is prohibitively expensive.
    • 3 because this solvent is prohibitively expensive.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.