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34250728603
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Complex 1
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Complex 1: Vicente, J.; Gonzalez-Herrero, P.; Perez-Cadenas, M.; Jones, P. G.; Bautista, D. Inorg. Chem. 2007, 46, 4718.
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4143151730
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Complex 2
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Complex 2: Neumann, R.; Bar-Nahum, I.; Khenkin, A. M. J. Am. Chem. Soc. 2004, 126, 10236.
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Neumann, R.1
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37
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0000938390
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Complex 3: See Supporting Information. Complex 4
-
Complex 3: See Supporting Information. Complex 4: Annibale, G.; Cattalini, L.; Chessa, G.; Marangoni, G.; Pitteri, B.; Tobe, M. L. Gazz. Chim. Ital. 1985, 115, 279.
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38
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3142738624
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Complex 5
-
Complex 5: Rauterkus, M. J.; Krebs, B. Angew. Chem., Int. Ed. 2004, 43, 1300.
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-
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0346786375
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Complex6
-
Complex6: Tu, C.; Wu, X.; Liu, Q.; Wang, X.; Xu, Q.; Guo, Z. Inorg. Chim. Acta 2004, 357,95.
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-
40
-
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0035944048
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Complex 7: ref 12. Complex 8
-
Complex 7: ref 12. Complex 8: Peters, J. C.; Harkins, S. B.; Brown, S. D.; Day, M. W. Inorg. Chem. 2001, 40, 5083.
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41
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84869604290
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4 as well as some residual DMF from recrystallization.
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4 as well as some residual DMF from recrystallization.
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-
-
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42
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70349365505
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-
A number of additional Ag salts were screened in this reaction (see Supporting Information for details). Notably, AgTFA afforded essentially identical results to AgOAc; therefore we utilized the less expensive Ag salt for these transformations.
-
A number of additional Ag salts were screened in this reaction (see Supporting Information for details). Notably, AgTFA afforded essentially identical results to AgOAc; therefore we utilized the less expensive Ag salt for these transformations.
-
-
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43
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0037121128
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Wong-Foy, A. G.; Henling, L. M.; Day, M.; Labinger, J. A.; Bercaw, J. E. J. Mol. Catal. A 2002, 189, 3.
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Wong-Foy, A.G.1
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33645458949
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Corberan, R.; Sanau, M.; Peris, E. J. Am. Chem. Soc. 2006, 128, 3974.
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Corberan, R.1
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45
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84869615449
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1 were corrected by subtraction of the % deuterium incorporation observed in the background reaction between TFA-rfi and C6H6 in the presence of AgCl.
-
1 were corrected by subtraction of the % deuterium incorporation observed in the background reaction between TFA-rfi and C6H6 in the presence of AgCl.
-
-
-
-
46
-
-
70349362205
-
-
The apparently lower TONs observed at extended times are an artifact of subtraction of the AgCl background reaction at the respective time points.
-
The apparently lower TONs observed at extended times are an artifact of subtraction of the AgCl background reaction at the respective time points.
-
-
-
-
47
-
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84869615450
-
-
2 also catalyze this reaction, but the addition of a mineral acid is required. See ref 10 for details.
-
2 also catalyze this reaction, but the addition of a mineral acid is required. See ref 10 for details.
-
-
-
-
48
-
-
84869615447
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3 under our standard conditions.
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3 under our standard conditions.
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-
-
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49
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84869614223
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3 because this solvent is prohibitively expensive.
-
3 because this solvent is prohibitively expensive.
-
-
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50
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0037481958
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Xu, X.; Kua, J.; Periana, R. A.; Goddard, W. A. Organometallics 2003, 22, 2057.
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Xu, X.1
Kua, J.2
Periana, R.A.3
Goddard, W.A.4
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