Cyclopentadienyl and olefin substituent effects on insertion and β-hydrogen elimination with group 4 metallocenes. kinetics, mechanism, and thermodynamics for zirconocene and hafnocene alkyl hydride derivatives

Organometallics

Volumn 24, Issue 22, 2005, Pages 5407-5423

  Chirik, Paul J ^a,b   Bercaw, John E ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b Department of Obstetrics Gynecology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYBRID COMPLEXES; HYDRIDE TRANSFER; METAL COMPLEXES; METALLOCENE;

ACTIVATION ENERGY; COMPLEXATION; DEUTERIUM; FREE ENERGY; ISOTOPES; OLEFINS; RATE CONSTANTS; SUBSTITUTION REACTIONS;

ORGANOMETALLICS;

EID: 27544433061     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0580351     Document Type: Article

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