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3]+ with the correct isotope pattern and consistent mass (exp. 378.7816, calc. 378.7804) were observed at elevated cone voltages, but neither CID nor IRMPD studies were possible
-
Traces of [(DMF)2Zn2Cl3]+ with the correct isotope pattern and consistent mass (exp. 378.7816, calc. 378.7804) were observed at elevated cone voltages, but neither CID nor IRMPD studies were possible.
-
-
-
-
83
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34547816634
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nNiCl]+ complexes imply C-H bond activation of one of the N-methyl groups rather than of the formyl unit CHO in DMF; see ref 9
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In the case of nickel, previous labeling data for [(DMF)nNiCl]+ complexes imply C-H bond activation of one of the N-methyl groups rather than of the formyl unit CHO in DMF; see ref 9.
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For recent reviews about the gas-phase chemistry of copper, see:
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79951620538
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note
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More detailed analysis of the data in Table 2 indeed reveals several significant correlations (e.g., between rM-O and vsym with r2 = 0.96), but the total shift of 13 cm-1 between the extremes of [(DMF)2CuC1]+ with rM-O = 1.89 Å and [(DMF)3ZnCl]+ with rM-O = 2.00 A is significantly smaller than the spectral resolution of the IRMPD peaks.
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106
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21844491733
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79951609059
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2-/0/+/2+, see:
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For instructive discussions of the particularly notorious case of Fe2S2-/0/+/2+, see:
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113
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79951640974
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a = 4.06 is not much above the noise level, it was fully reproducible in several independent ion-mobility scans and hence not just a spurious signal
-
Although the second feature at ta = 4.06 is not much above the noise level, it was fully reproducible in several independent ion-mobility scans and hence not just a spurious signal.
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-
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115
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79951591342
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Using the computed stability difference of 0.37 eV, treatment of the about 1:30 ratio using equilibrium considerations would suggest an effective temperature of about 1200 K which is within the range for ions formed via collision-induced dissociation (ref 72)
-
Using the computed stability difference of 0.37 eV, treatment of the about 1:30 ratio using equilibrium considerations would suggest an effective temperature of about 1200 K which is within the range for ions formed via collision-induced dissociation (ref 72).
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77249144824
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For a related IRMPD study of DMF complexes of alkyl zinc cations, see: Dreiocker, F.; Oomens, J.; Meijer, A. J. H. M.; Pickup, B. T.; Jackson, R. F. W.; Schäfer, M. J. Org. Chem. 2010, 75, 1203.
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79951610757
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note
-
A referee pointed out that increased widths of the peaks at about 1650 cm-1 could point to contributions of different rotamers, which indeed have very similar IR spectra. Because of the overall close similarities of the infrared patterns and the limited resolution of the IRMPD spectra, we refrain from a more detailed discussion of this aspect.
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0343314923
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The total ion currents were comparable for all three samples, which is consistent with the fact that at feed concentrations in the order of 10-3 mol L-1 the total ion current in the ESI is charge-limited. See also: Gatlin,C.L.; Tureček, F. J. Mass Spectrom. 2000, 35,172.
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