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+ and a rigorous assignment cannot be made. However, in the range of collision energies studied here, these fragments never comprise more than 5 % of the total fragment ion abundances, and equal sharing between both channels gave a reasonable fit with the experimental data in Figures 1 (M = Co) and 2 (M = Ni).
-
+ and a rigorous assignment cannot be made. However, in the range of collision energies studied here, these fragments never comprise more than 5 % of the total fragment ion abundances, and equal sharing between both channels gave a reasonable fit with the experimental data in Figures 1 (M = Co) and 2 (M = Ni).
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For example, IE(CoO) = (8.9±0.2)eV vs. IE(NiO) = (9.5 ± 0.2) eV, see: P. B. Armentour, L. F. Halle, J. L. Beauch-amp, J. Chem. Phys. 1982, 76, 2449-2457.
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85152991149
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2) = (9.586 ± 0.002) eV. Taken from: P. J. Linstrom, W. G. Mallard (Eds.), NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg MD, 20899, http://webbook.nist.gov.
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2) = (9.586 ± 0.002) eV. Taken from: P. J. Linstrom, W. G. Mallard (Eds.), NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg MD, 20899, http://webbook.nist.gov.
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61
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M. Trachtman, G. D. Markham, J. P. Glusker, P. George, C. W. Bock, Inorg. Chem. 2001, 40, 4230-4241.
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S. Kazazic, S. P. Kazazic, L. Klasinc, S. P. McGlynn, W. A. Pryor, J. Phys. Org. Chem. 2002, 15, 728-731.
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2, see: J. J. Claasen, D. B. Jacobsen, J. Am. Chem. Soc. 1988, 110, 974-976.
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2, see: J. J. Claasen, D. B. Jacobsen, J. Am. Chem. Soc. 1988, 110, 974-976.
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81
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85153025038
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For formally spin-forbidden reactions in the gas phase and the related concept of two-state reactivity, see: a D. Schroder, S. Shaik, H. Schwarz, Ace. Chem. Res. 2000, 33, 139-145;
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For formally spin-forbidden reactions in the gas phase and the related concept of two-state reactivity, see: a) D. Schroder, S. Shaik, H. Schwarz, Ace. Chem. Res. 2000, 33, 139-145;
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83
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85153023157
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For a recent example of the use of labeling for the differentiation of all atoms in the quasidegenerate CO22+/CO2 system, see: a J. Roithova, C. L. Ricketts, D. Schroder, S. D. Price, Angew. Chem. Int. Ed. 2007, 46, 9316-9319;
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For a recent example of the use of labeling for the differentiation of all atoms in the quasidegenerate CO22+/CO2 system, see: a) J. Roithova, C. L. Ricketts, D. Schroder, S. D. Price, Angew. Chem. Int. Ed. 2007, 46, 9316-9319;
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84
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Angew. Chem. 2007, 119, 9476-9479;
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85
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b) C. L. Ricketts, D. Schroder, J. Roithova, H. Schwarz, R. Thissen, O. Dutuit, J. Zabka, Z. Herman, S. D. Price, Phys. Chem. Chem. Phys. 2008, 10, 5135-5143.
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Phys. Chem. Chem. Phys
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Ricketts, C.L.1
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Price, S.D.9
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86
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D. Schroder, M. Engeser, H. Schwarz, E. C. E. Rosenthal, J. Dobler, J. Sauer, Inorg. Chem. 2006, 45, 6235-6245.
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87
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C. Heinemann, H. H. Cornehl, D. Schroder, M. Dolg, H. Schwarz, Inorg. Chem. 1996, 35, 2463.
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Heinemann, C.1
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88
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D. Schroder, M. Semialjac, H. Schwarz, Int. J. Mass Spectrom. 2004, 233, 103-109.
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Int. J. Mass Spectrom
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G. Bouchoux, D. Leblanc, J. Y. Salpin, Int. J. Mass Spectrom. 1996, 153, 37-48.
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Bouchoux, G.1
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90
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P. Milko, J. Roithova, D. Schroder, J. Lemaire, H. Schwarz, M. C. Holthausen, Chem. Eur. J. 2008, 14, 4318-4327.
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Chem. Eur. J
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Milko, P.1
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J. Roithova, D. Schroder, J. Misek, I. G. Stara, I. Stary, J. Mass Spectrom. 2007, 42, 1233-1237.
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J. Mass Spectrom
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a) J. Roithova, P. Milko, C. L. Ricketts, D. Schroder, T. Besson, V. Dekoj, M. Belohradsky, J. Am. Chem. Soc. 2007, 129, 10141-10148;
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J. Am. Chem. Soc
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Roithova, J.1
Milko, P.2
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Besson, T.5
Dekoj, V.6
Belohradsky, M.7
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93
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b) B. Colasson, M. Save, O. Reinaud, P. Milko, J. Roithova, D. Schroder, Org. Lett. 2007, 9, 4987-4990.
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Org. Lett
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Colasson, B.1
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Schroder, D.6
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