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Volumn 29, Issue 17, 2010, Pages 3979-3986

Electrospray mass spectrometric studies of two palladium-allyl complexes of the trost standard ligand

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPLEXES; COUNTERIONS; ELECTROSPRAY IONIZATION MASS SPECTROMETRY; ELECTROSPRAYS; ELEVATED CONCENTRATIONS; PALLADIUM COMPLEXES; QUASI-MOLECULAR IONS; SOLUTION CHEMISTRY; TRIFLATES;

EID: 77956404994     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100591c     Document Type: Article
Times cited : (18)

References (55)
  • 19
    • 0035915118 scopus 로고    scopus 로고
    • For cyclohexenyl acetate, a selectivity factor s ? 45 has been found. The selectivity factor s expresses the relative rates of reaction of the two enantiomers and can be estimated by nonlinear regression of s = ln[(1 - c)(1 - ee)]/ln[(1 - c)(1 + ee)]; see:;;, However, determination by measurement of the absolute rates of reactions of the enantiomers shows this value to be a substantial underestimate (; Unpublished results).
    • For cyclohexenyl acetate, a selectivity factor s ? 45 has been found. The selectivity factor s expresses the relative rates of reaction of the two enantiomers and can be estimated by nonlinear regression of s = ln[(1 - c)(1 - ee)]/ln[(1 - c)(1 + ee)]; see: Dominguez, B.; Hodnett, N. S.; Lloyd-Jones, G. C. Angew. Chem., Int. Ed. 2001, 40, 4289 However, determination by measurement of the absolute rates of reactions of the enantiomers shows this value to be a substantial underestimate (Sale, D. A.; Lloyd-Jones, G. C. Unpublished results).
    • (2001) Angew. Chem., Int. Ed. , vol.40 , pp. 4289
    • Dominguez, B.1    Hodnett, N.S.2    Lloyd-Jones, G.C.3    Sale, D.A.4    Lloyd-Jones, G.C.5
  • 33
    • 0342316159 scopus 로고    scopus 로고
    • For previous studies of ionic Pd-allyl species in the gas phase, see
    • For previous studies of ionic Pd-allyl species in the gas phase, see: Schwarz, J.; Schröder, D.; Hrušák, J.; Schwarz, H. Helv. Chim. Acta 1996, 79, 1110
    • (1996) Helv. Chim. Acta , vol.79 , pp. 1110
    • Schwarz, J.1    Schröder, D.2    Hrušák, J.3    Schwarz, H.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.