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Poly(ferrocenyl(3-ammoniumpropyl)methylsilane) was kindly provided by Dr. Mark Hempenius of the University of Twente and synthesized as described in ref 40
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Poly(ferrocenyl(3-ammoniumpropyl)methylsilane) was kindly provided by Dr. Mark Hempenius of the University of Twente and synthesized as described in ref 40.
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See Supporting Information for a representative set of POM images for the 14 wt % mixture of A-BTA with l -PEI-med
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See Supporting Information for a representative set of POM images for the 14 wt % mixture of A-BTA with l -PEI-med.
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The correlation length (〈) has been calculated by fitting the peak with a Lorentzian distribution function and using the Scherrer equation as reported in ref 51: 〈 = 0.89 λ/(ω cos θ), wherein λ is the wavelength of the X-rays, ω is the full width at half-maximum of the peak in radians, and θ is Bragg angle of the maximum of the peak
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The correlation length (〈) has been calculated by fitting the peak with a Lorentzian distribution function and using the Scherrer equation as reported in ref 51: 〈 = 0.89 λ/(ω cos θ), wherein λ is the wavelength of the X-rays, ω is the full width at half-maximum of the peak in radians, and θ is Bragg angle of the maximum of the peak.
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79951612731
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-1 region of the spectrum. As can be seen from the spectra of the pure polymers in the Supporting Information, this assumption is very reasonable
-
-1 region of the spectrum. As can be seen from the spectra of the pure polymers in the Supporting Information, this assumption is very reasonable.
-
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Two-dimensional X-ray scattering measurements on shear aligned samples showed that all small angle diffraction peaks split up in two opposing maxima that align in the same direction on the two-dimensional detector. Furthermore, the wide angle maximum related to the stacking of A-BTA splits up in two maxima perpendicular to the small angle diffraction peaks. These measurements confirm that all observed small angle diffraction peaks observed in the LC phase arise from order in a single plane perpendicular to the stacking direction of the A-BTA discotics. See Supporting Information for a representative set of two-dimensional SAXS and WAXS data
-
Two-dimensional X-ray scattering measurements on shear aligned samples showed that all small angle diffraction peaks split up in two opposing maxima that align in the same direction on the two-dimensional detector. Furthermore, the wide angle maximum related to the stacking of A-BTA splits up in two maxima perpendicular to the small angle diffraction peaks. These measurements confirm that all observed small angle diffraction peaks observed in the LC phase arise from order in a single plane perpendicular to the stacking direction of the A-BTA discotics. See Supporting Information for a representative set of two-dimensional SAXS and WAXS data.
-
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See Supporting Information for full indexation
-
See Supporting Information for full indexation
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79951650183
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The calculation requires a set of three equations relating the lattice plane spacings and the corresponding peak positions to be solved simultaneously. This system of equations was solved numerically in the programming language Python using an open-source library (see and www.scipy.org)
-
The calculation requires a set of three equations relating the lattice plane spacings and the corresponding peak positions to be solved simultaneously. This system of equations was solved numerically in the programming language Python using an open-source library (see www.python.org and www.scipy.org).
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See Supporting Information for the complete calculation
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See Supporting Information for the complete calculation.
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