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Volumn 46, Issue 5, 2007, Pages 1718-1726

Better understanding of the species with the shortest Re2 6+ bonds and related Re27+ species with tetraguanidinate paddlewheel structures

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EID: 33947364273     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic062319b     Document Type: Article
Times cited : (27)

References (77)
  • 37
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    • 2 system also suggest an important effect of the axial ligands on the Pd-Pd distance. See: Cotton, F. A.; Koshevoy, I. O.; Lahuerta, P.; Murillo, C. A.; Sanaú, M.; Ubeda, M. A.; Zhao, Q. J. Am. Chem. Soc. 2006, 128, 13674.
    • 2 system also suggest an important effect of the axial ligands on the Pd-Pd distance. See: Cotton, F. A.; Koshevoy, I. O.; Lahuerta, P.; Murillo, C. A.; Sanaú, M.; Ubeda, M. A.; Zhao, Q. J. Am. Chem. Soc. 2006, 128, 13674.
  • 46
    • 33947401601 scopus 로고    scopus 로고
    • The use of 2 equiv of [Ag(CH3CN)2]PF6 was with the intention of generating an Re28+ species that had been observed in the cyclovoltammogram of Re2(hpp) 4Cl2 done using NBu4PF6 as electrolyte. See ref 9. However, only the singly oxidized species 4 was isolated from this reaction
    • 6 as electrolyte. See ref 9. However, only the singly oxidized species 4 was isolated from this reaction.
  • 48
    • 33947393755 scopus 로고    scopus 로고
    • Disorder of hpp ligands in paddlewheel compounds is common, but the disorder is generally well understood. See, for example
    • Disorder of hpp ligands in paddlewheel compounds is common, but the disorder is generally well understood. See, for example, ref 17.
  • 49
    • 33947411533 scopus 로고    scopus 로고
    • Cotton, F. A, Murillo, C. A, Walton, R. A, Eds, Springer Science and Business Media, Inc, New York, Chapter 8
    • Walton, R. A. In Multiple Bonds Between Metal Atoms; Cotton, F. A., Murillo, C. A., Walton, R. A., Eds.; Springer Science and Business Media, Inc.: New York, 2005; Chapter 8.
    • (2005) Multiple Bonds Between Metal Atoms
    • Walton, R.A.1
  • 55
    • 33947388947 scopus 로고    scopus 로고
    • As mentioned in ref 25, disorder of hpp ligands is common
    • As mentioned in ref 25, disorder of hpp ligands is common.
  • 56
    • 33947357468 scopus 로고    scopus 로고
    • Because the Re-X axial was about 2.03 Å, an oxide group could be ruled out because Re-O distances would be expected to be significantly shorter.
    • Because the Re-X axial was about 2.03 Å, an oxide group could be ruled out because Re-O distances would be expected to be significantly shorter.
  • 57
    • 33947374084 scopus 로고    scopus 로고
    • The only significant difference was that for the X-ray structure the occupancy values for each Fa and Fb refined to 0.481, The difference is attributed to the temperatures used for each data collection, 40 K for the neutron data, and 213 K for the X-ray data
    • The only significant difference was that for the X-ray structure the occupancy values for each Fa and Fb refined to 0.48(1). The difference is attributed to the temperatures used for each data collection, 40 K for the neutron data, and 213 K for the X-ray data.
  • 65
    • 33947406107 scopus 로고    scopus 로고
    • 3-CN/ether were twinned.
    • 3-CN/ether were twinned.
  • 66
    • 33947413224 scopus 로고    scopus 로고
    • SMART, Software for the CCD Detector System, version 5.625; Bruker Advanced X-ray Solutions: Madison, WI, 2001
    • SMART, Software for the CCD Detector System, version 5.625; Bruker Advanced X-ray Solutions: Madison, WI, 2001.
  • 67
    • 33947406956 scopus 로고    scopus 로고
    • SAINT. Data Reduction Software. Version 6.33B; Bruker Advanced X-ray Solutions: Madison, WI, 2001
    • SAINT. Data Reduction Software. Version 6.33B; Bruker Advanced X-ray Solutions: Madison, WI, 2001.
  • 69
    • 33947403705 scopus 로고    scopus 로고
    • Sheldrick, G. M. SHELXTL. Version 6.10; Bruker Advanced X-ray Solutions: Madison, WI, 2000
    • Sheldrick, G. M. SHELXTL. Version 6.10; Bruker Advanced X-ray Solutions: Madison, WI, 2000.
  • 74
    • 77957059147 scopus 로고    scopus 로고
    • Sears, V. F. In Methods of Experimental Physics, 23, Neutron Scattering, Part A; Academic Press: Orlando, FL, 1986; pp 521-550.
    • Sears, V. F. In Methods of Experimental Physics, Vol. 23, Neutron Scattering, Part A; Academic Press: Orlando, FL, 1986; pp 521-550.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.