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and references therein
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Cotton, F. A.; Donahue, J. P.; Gruhn, N. E.; Lichtenberger, L.; Murillo, C. A.; Timmons, D. J.; Van Dorn, L. O.; Villagrán, D.; Wang, X. Inorg. Chem. 2006, 45, 201.
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37
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33750288439
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2 system also suggest an important effect of the axial ligands on the Pd-Pd distance. See: Cotton, F. A.; Koshevoy, I. O.; Lahuerta, P.; Murillo, C. A.; Sanaú, M.; Ubeda, M. A.; Zhao, Q. J. Am. Chem. Soc. 2006, 128, 13674.
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2 system also suggest an important effect of the axial ligands on the Pd-Pd distance. See: Cotton, F. A.; Koshevoy, I. O.; Lahuerta, P.; Murillo, C. A.; Sanaú, M.; Ubeda, M. A.; Zhao, Q. J. Am. Chem. Soc. 2006, 128, 13674.
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33947401601
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The use of 2 equiv of [Ag(CH3CN)2]PF6 was with the intention of generating an Re28+ species that had been observed in the cyclovoltammogram of Re2(hpp) 4Cl2 done using NBu4PF6 as electrolyte. See ref 9. However, only the singly oxidized species 4 was isolated from this reaction
-
6 as electrolyte. See ref 9. However, only the singly oxidized species 4 was isolated from this reaction.
-
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47
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0034695842
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See, for example
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See, for example: Clérac, R.; Cotton, F. A.; Daniels, L. M.; Dunbar, K. R.; Murillo, C. A.; Pascual, I. Inorg. Chem. 2000, 39, 752.
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48
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33947393755
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Disorder of hpp ligands in paddlewheel compounds is common, but the disorder is generally well understood. See, for example
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Disorder of hpp ligands in paddlewheel compounds is common, but the disorder is generally well understood. See, for example, ref 17.
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33947411533
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Cotton, F. A, Murillo, C. A, Walton, R. A, Eds, Springer Science and Business Media, Inc, New York, Chapter 8
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33947388947
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As mentioned in ref 25, disorder of hpp ligands is common
-
As mentioned in ref 25, disorder of hpp ligands is common.
-
-
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56
-
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33947357468
-
-
Because the Re-X axial was about 2.03 Å, an oxide group could be ruled out because Re-O distances would be expected to be significantly shorter.
-
Because the Re-X axial was about 2.03 Å, an oxide group could be ruled out because Re-O distances would be expected to be significantly shorter.
-
-
-
-
57
-
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33947374084
-
-
The only significant difference was that for the X-ray structure the occupancy values for each Fa and Fb refined to 0.481, The difference is attributed to the temperatures used for each data collection, 40 K for the neutron data, and 213 K for the X-ray data
-
The only significant difference was that for the X-ray structure the occupancy values for each Fa and Fb refined to 0.48(1). The difference is attributed to the temperatures used for each data collection, 40 K for the neutron data, and 213 K for the X-ray data.
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3-CN/ether were twinned.
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3-CN/ether were twinned.
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SMART, Software for the CCD Detector System, version 5.625; Bruker Advanced X-ray Solutions: Madison, WI, 2001.
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