메뉴 건너뛰기




Volumn 1, Issue 1, 1998, Pages 21-27

Permethylated electron-reservoir sandwich complexes as references for the determination of redox potentials. Suggestion of a new redox scale;Les complexes sandwichs perméthylés réservoirs d'electrons en tant que références pour la détermination des potentiels redox. Suggestion d'une nouvelle échelle redox

Author keywords

Electrochemical scale; Electron reservoir sandwiches; Redox references

Indexed keywords


EID: 0031616540     PISSN: 13871609     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1251-8069(97)86255-0     Document Type: Article
Times cited : (145)

References (19)
  • 1
    • 0004074605 scopus 로고
    • Ives D., Janz J.G. (Eds), Academic Press, New York
    • [1] Hills G.J., in Ives D., Janz J.G. (Eds), Reference Electrodes, Academic Press, New York, 1961.
    • (1961) Reference Electrodes
    • Hills, G.J.1
  • 2
    • 0001512707 scopus 로고
    • Properties of bases in acetonitrile as solvent. II. The autoprotolysis constant of acetonitrile
    • [2] For reduction of rhe instability of rhe SCE in non-aqueous solvents, see Coetzee J.F., Padmanablan G.R., Properties of bases in acetonitrile as solvent. II. The autoprotolysis constant of acetonitrile, J. Phys. Chem. 66 (1962) 7708.
    • (1962) J. Phys. Chem. , vol.66 , pp. 7708
    • Coetzee, J.F.1    Padmanablan, G.R.2
  • 4
    • 0000736799 scopus 로고
    • The study of reactive intermediates by electrochemical methods
    • [4] Parker V.D., The study of reactive intermediates by electrochemical methods. Adv. Phys. Org. Chem. 19 (1983) 131.
    • (1983) Adv. Phys. Org. Chem. , vol.19 , pp. 131
    • Parker, V.D.1
  • 5
    • 0021410857 scopus 로고
    • Recommendations on reporting electrode potentials in nonaqueous solvents
    • [5] Gritzner G., Kuta J., Recommendations on reporting electrode potentials in nonaqueous solvents, Pure Appl. Chem. 56 (1984) 461.
    • (1984) Pure Appl. Chem. , vol.56 , pp. 461
    • Gritzner, G.1    Kuta, J.2
  • 6
    • 6844239208 scopus 로고    scopus 로고
    • Chemical redox reagents for organometallic chemistry
    • [6] Connelly N.G., Geiger W.E., Chemical redox reagents for organometallic chemistry, Chem. Rev. 96 (1996) 877.
    • (1996) Chem. Rev. , vol.96 , pp. 877
    • Connelly, N.G.1    Geiger, W.E.2
  • 8
    • 0001419522 scopus 로고
    • The ferrocene assumption in redox thermodynamics: Implications from optical intervalence studies of ion pairing to ferrocenium
    • [8] Hupp J.T., The ferrocene assumption in redox thermodynamics: implications from optical intervalence studies of ion pairing to ferrocenium, Inorg. Chem. 29 (1990) 5010.
    • (1990) Inorg. Chem. , vol.29 , pp. 5010
    • Hupp, J.T.1
  • 9
    • 0003995772 scopus 로고
    • Oxidatively induced electrocatalytic ligand substitution in 17-electron manganese complexes: An investigation of the kinetics by derivative cyclic voltammetry
    • Martinho S. (Ed.), Kluwer, Dordrecht
    • o values is differential cyclic voltammetry, see Tilset M., Skagestad V., Parker V., Oxidatively induced electrocatalytic ligand substitution in 17-electron manganese complexes: an investigation of the kinetics by derivative cyclic voltammetry, in: Martinho S. (Ed.), Energetics of organometallic species, Kluwer, Dordrecht, 1992, 109-129.
    • (1992) Energetics of Organometallic Species , pp. 109-129
    • Tilset, M.1    Skagestad, V.2    Parker, V.3
  • 10
    • 85030055684 scopus 로고    scopus 로고
    • note
    • pc)/2 holds true even if the chemical reversibility is only partial.
  • 11
    • 0000767218 scopus 로고
    • Permethylated electron-excess metallocenes
    • [11] Koelle U., Khouzami F., Permethylated electron-excess metallocenes, Angew. Chem. 92 (1980) 658; Angew. Chem. Int. Ed. Engl. 19 (1980) 640.
    • (1980) Angew. Chem. , vol.92 , pp. 658
    • Koelle, U.1    Khouzami, F.2
  • 12
    • 84985502114 scopus 로고
    • [11] Koelle U., Khouzami F., Permethylated electron-excess metallocenes, Angew. Chem. 92 (1980) 658; Angew. Chem. Int. Ed. Engl. 19 (1980) 640.
    • (1980) Angew. Chem. Int. Ed. Engl. , vol.19 , pp. 640
  • 13
  • 16
    • 0001129486 scopus 로고
    • Formation and molecular structures of pentabenzylcyclopentadienyl and pentaphenylcyclopentadienyl dicarbonyl derivatives of cobalt and rhodium
    • [15] Chambers J.W., Baskar A.J., Bott S.G., Atwood J.L., Rausch M.D., Formation and molecular structures of pentabenzylcyclopentadienyl and pentaphenylcyclopentadienyl dicarbonyl derivatives of cobalt and rhodium, Organometallics 5 (1986) 1635.
    • (1986) Organometallics , vol.5 , pp. 1635
    • Chambers, J.W.1    Baskar, A.J.2    Bott, S.G.3    Atwood, J.L.4    Rausch, M.D.5
  • 17
    • 33845555683 scopus 로고
    • Electronic structures of metallocene compounds. 3. Comparison of the results of multiple scattering. Xα Calculations with various electronic observables of cobaltocene
    • and references cited therein
    • 2), see for instance Weber J., Goursot A., Penigault E., Ammeter J.H., Bachman J., Electronic structures of metallocene compounds. 3. Comparison of the results of multiple scattering. Xα Calculations with various electronic observables of cobaltocene, J. Am. Chem. Soc. 104 (1982) 1491 and references cited therein.
    • (1982) J. Am. Chem. Soc. , vol.104 , pp. 1491
    • Weber, J.1    Goursot, A.2    Penigault, E.3    Ammeter, J.H.4    Bachman, J.5
  • 19
    • 85030057504 scopus 로고    scopus 로고
    • note
    • [18] A. Masters and P. Lay have informed us (October 1997) that their research group has submitted an article to Inorg. Chem. on the possible use of decamethylferrocene as a redox reference based on the study of the variable differences of potentials between ferrocene and decamethylferrocene in various solvents. We thank these authors for helpful discussions.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.