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30944444017
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3, Z = 2, R1 = 0.018, wR2 = 0.054. Additional crystallographic data are provided as Supporting Information.
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34
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54
-
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30944462654
-
-
note
-
These values represent the average of two separate analyses performed upon the same sample.
-
-
-
-
55
-
-
30944463312
-
-
note
-
2.
-
-
-
-
56
-
-
30944462266
-
-
note
-
3, Z = 4, R1 = 0.074, wR2 = 0.139.
-
-
-
-
57
-
-
30944454352
-
-
note
-
3, Z = 4, R1 = 0.015, wR2 = 0.035. Additional crystallographic data are provided as Supporting Information.
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59
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0002492595
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30944451438
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note
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3, Z = 4, R1 = 0.040, wR2 = 0.091. Additional crystallographic data are provided as Supporting Information.
-
-
-
-
62
-
-
30944461051
-
-
See ref 6
-
2. See ref 6.
-
-
-
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63
-
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30944459741
-
-
note
-
3 units are nearly planar in all three compounds.
-
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64
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Wildschek, M.1
Rieker, C.2
Jaitner, P.3
Schottenberger, H.4
Schwarzhans, K.E.5
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72
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33845282426
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(b) Chisholm, M. H.; Clark, D. L.; Hoffman, J. C.; Van Der Sluys, W. G.; Kober, E. M.; Lichtenberger, D. L.; Bursten, B. E. J. Am. Chem. Soc. 1987, 109, 6796.
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Chisholm, M.H.1
Clark, D.L.2
Hoffman, J.C.3
Van Der Sluys, W.G.4
Kober, E.M.5
Lichtenberger, D.L.6
Bursten, B.E.7
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73
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0033616099
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Lichtenberger, D. L.; Lynn, M. A.; Chisholm, M. H. J. Am. Chem. Soc. 1999, 121, 12167.
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J. Am. Chem. Soc.
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Lichtenberger, D.L.1
Lynn, M.A.2
Chisholm, M.H.3
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74
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30944442713
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Ph.D. Dissertation, The University of Arizona: Tucson, AZ
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Jatcko, M. E., Ph.D. Dissertation, The University of Arizona: Tucson, AZ, 1989.
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(1989)
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Jatcko, M.E.1
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75
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30944458480
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note
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z, and 6s orbitals that contribute 34%, 50%, and 9%, respectively, as obtained from this calculation.
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-
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76
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30944454924
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note
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2+ unit may be viewed as a σ* acceptor.
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-
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78
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30944461252
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note
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2 system with Cl axial ligands and an empty σ* orbital may be expected to experience some degree of elongation of the M-M bond.
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80
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0038785648
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and references therein
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2 compounds with M = Mo, W, Ru, Re, Os, Ir, Pd, and Pt. (see Cotton, F. A.; Murillo, C. A.; Wang, X.; Wilkinson, C. C. Inorg. Chim Acta 2003, 351, 191 and references therein). In those compounds, the M-Cl distances vary from 2.47 to 3.17 Å. The short distance of 2.47 Å (for the Pd compound) seems to indicate that the Cl atoms can approach the metal atoms without problems.
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(2003)
Inorg. Chim Acta
, vol.351
, pp. 191
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Cotton, F.A.1
Murillo, C.A.2
Wang, X.3
Wilkinson, C.C.4
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81
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30944461433
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note
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2.
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