The first structurally confirmed paddlewheel compound with an M27+ core: [Os2(hpp)4Cl2](PF6)

Inorganic Chemistry

Volumn 42, Issue 3, 2003, Pages 670-672

  Cotton, F Albert ^a   Dalal, Naresh S ^b   Huang, Penglin ^a   Murillo, Carlos A ^a   Stowe, Ashley C ^b   Wang, Xiaoping ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b FLORIDA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

MANGANESE;

ANALYTIC METHOD; ARTICLE; CRYSTALLIZATION; CYCLIC POTENTIOMETRY; DATA ANALYSIS; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; OXIDATION REDUCTION REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS;

EID: 0037429143     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic026250t     Document Type: Article

References (28)

1. Cotton, F. A.; Timmons, D. J. Polyhedron 1998, 17, 179.
2. (a) Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Timmons, D. J.; Wilkinson, C. C. J. Am. Chem. Soc. 2002, 124, 9249.
3. (b) Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Timmons, D. J. Chem. Commun. 1997, 1449.
4. Cotton, F. A.; Matonic, J. H.; Murillo, C. A. J. Am. Chem. Soc. 1998, 120, 6047.
5. Clérac, R.; Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Timmons, D. J. Inorg. Chem. 2000, 39, 2581.
6. Cotton, F. A.; Huang, P.; Murillo, C. A.; Timmons, D. J. Inorg. Chem. Commun. 2002, 5, 501.
7. Cotton, F. A.; Gu, J.; Murillo, C. A.; Timmons, D. J. J. Chem. Soc., Dalton Trans. 1999, 3741.
8. Bear, J. L.; Li, Y.; Han, B.; Kadish, K. M. Inorg. Chem. 1996, 35, 1395.
9. Cotton, F. A.; Murillo, C. A.; Timmons, D. J. Chem. Commun. 1999, 1427.
10. Cotton, F. A.; Gu, J.; Murillo, C. A.; Timmons, D. J. J. Am. Chem. Soc. 1998, 120, 13280.
11. Cotton, F. A.; Gruhn, N. E.; Gu, J.; Huang, P.; Lichtenberger, D. L.; Murillo, C. A.; Van Dorn, L. O.; Wilkinson, C. C. Science 2002, 298, 1971.
12. + couple appears at 0.533 V.
13. + couple appeared at 0.560 V and the other two oxidation waves at 0.085 and 1.050 V.
14. + see: Kadish, K. M.; Burdet, F.; Jérôme, F.; Barbe, J.-M.; Ou, Z.; Shao, J.; Guilard, R. J. Organomet. Chem. 2002, 652, 69.
15. -1.
16. -3, T = 213 K. R1 = 0.0331, wR2 = 0.0746, GOF = 1.030 for all data.
17. -3. T = 213 K. R1 = 0.0442, wR2 = 0.0739, GOF = 1.169 for all data.
18. Cotton, F. A.; Jennings, J. G.; Price, A. C.; Vidyasagar, K. Inorg. Chem. 1990, 29, 4138.
19. 6+ units. See, for example: Cotton, F. A.; Dunbar, K. R.; Falvello, L. R.; Tomas, M.; Walton, R. A. J. Am. Chem. Soc. 1983, 105, 4950.
20. (a) Schwesinger, R. Chimia 1985, 39, 269.
21. (b) Novak, I.; Wei, X.; Chin, W. S. J. Phys. Chem. A 2001, 105, 1783.
22. -1 for the bands at 355, 465, and 495 nm, respectively. For 1 there is also a weak shoulder at 585 nm (see ref 4).
23. 2 (see Supporting Information).
24. (a) Schubert, E. M. J. Chem. Educ. 1992, 69, 62.
25. Evans, D. F. J. Chem. Soc. 1959, 2003.
26. Gerloch, M. Orbitals, Terms and States; Wiley: Chichester, U.K., 1986; p 73.
27. See, for example: (a) DeSimone, R. E. J. Am. Chem. Soc. 1973, 95, 6238.
28. (b) McGarvey, B. R.; Batista, N. C.; Bezerra, C. W. B.; Schultz, M. S.; Franco, D. W. Inorg. Chem. 1998, 37, 2865.