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Coordination of the dimethylamino group in ligand B was not observed to date. B should therefore as yet not be regarded as a potentially hemilabile ligand.
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56649092941
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Tridentate diphosphinoazines, featuring a PNP donor set, coordinate in a 5,6′-chelate fashion:;;;;, and references therein Also a PNN ligand based on lutidine has been reported:;;; Organometallics 2005, 24, 5937
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Tridentate diphosphinoazines, featuring a PNP donor set, coordinate in a 5,6′-chelate fashion: Pošta, M.; Čermák, J.; Vojtíšek, P.; Sýkora, J.; Císařová, I. Inorg. Chim. Acta 2009, 362, 208, and references therein Also a PNN ligand based on lutidine has been reported: Poverenov, E.; Leitus, G.; Shimon, L. J.W.; Milstein, D. Organometallics 2005, 24, 5937
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43249098843
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For related 5,6′-PCN ligands see:;;;;; Chem.-Eur. J. 2004, 10, 4673
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79751472733
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In principle, the same general synthetic protocol could also be used to install other functionalities besides dialkylamines or allow for different substitution patterns.
-
In principle, the same general synthetic protocol could also be used to install other functionalities besides dialkylamines or allow for different substitution patterns.
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99
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33748446627
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76349119025
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RhP in the range of ∼200 Hz were observed. Recent work from our laboratories involving other Rh-phosphine complexes
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RhP in the range of ∼200 Hz were observed. Recent work from our laboratories involving other Rh-phosphine complexes: Chikkali, S. H.; Bellini, R.; Berthon-Gelloz, G.; van der Vlugt, J. I.; de Bruin, B.; Reek, J. N. H. Chem. Commun. 2010, 49, 1244
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77955457214
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105
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79751472443
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2 close to the amido group was used to determine the coalescence temperature.
-
2 close to the amido group was used to determine the coalescence temperature.
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68249133579
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For an X-ray structure of the related [Ir(PNP)(COE)] complex, see
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79751494285
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It could also be related to the different substitution pattern on the amino side-group, although this appears less intuitive due to the mutual cis-arrangement rather than the direct trans-influence exerted by the amide donor.
-
It could also be related to the different substitution pattern on the amino side-group, although this appears less intuitive due to the mutual cis-arrangement rather than the direct trans-influence exerted by the amide donor.
-
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63349093184
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79551674010
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2] complex with a monoanionic phosphine-amide PN coordination sphere. For related work on amido-phosphinoalkenyl ligands, see:;;, Rare dinuclear examples:;;;;;; Inorg. Chem. 1985, 24, 2334
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2] complex with a monoanionic phosphine-amide PN coordination sphere. For related work on amido-phosphinoalkenyl ligands, see: Sasamori, T.; Matsumoto, T.; Tokitoh, N. Polyhedron 2010, 29, 425 Rare dinuclear examples: Schenk, T. G.; Downes, J. M.; Milne, C. R. C.; Mackenzie, P. B.; Boucher, H.; Whelan, J.; Bosnich, B. Inorg. Chem. 1985, 24, 2334
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33645419775
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Dubs, C.; Yamamoto, T.; Inagaki, A.; Akita, M. Organometallics 2006, 25, 1359
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119
-
-
79751495662
-
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alkyl bond.
-
alkyl bond.
-
-
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120
-
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79751512674
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We have noted very interesting redox chemistry with these Rh(PNN) species. These results will be disclosed in a separate account.
-
We have noted very interesting redox chemistry with these Rh(PNN) species. These results will be disclosed in a separate account.
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0038626673
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Calculations were performed using Gaussian software at the BP86/6-311G(d,p) level: revision B.04; Gaussian, Inc.: Wallingford, CT
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Calculations were performed using Gaussian software at the BP86/6-311G(d,p) level: Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A., Jr.; Vreven, T.; Kudin, K. N.; Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.; Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross, J. B.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Ayala, P. Y.; Morokuma, K.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz, J. V.; Cui, Q.; Baboul, A. G.; Clifford, S.; Cioslowski, J.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; M. A. Al-Laham; Peng, C. Y.; Nanayakkara, A.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Gonzalez, C.; Pople, J. A. Gaussian 03, revision B.04; Gaussian, Inc.: Wallingford, CT, 2004.
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Trucks, G.W.2
Schlegel, H.B.3
Scuseria, G.E.4
Robb, M.A.5
Cheeseman, J.R.6
Montgomery Jr., J.A.7
Vreven, T.8
Kudin, K.N.9
Burant, J.C.10
Millam, J.M.11
Iyengar, S.S.12
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Barone, V.14
Mennucci, B.15
Cossi, M.16
Scalmani, G.17
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Petersson, G.A.19
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Wong, M.W.79
Gonzalez, C.80
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