Synthesis of a library of iridium-containing dinuclear complexes with bridging PNNN and PNNP ligands (BL), [LM(μ-BL)M′L′]BF 4. 2. Preparation, basic coordination properties, and reactivity of the carbonyl complexes

Organometallics

Volumn 25, Issue 6, 2006, Pages 1359-1367

  Dubs, Christian ^a   Yamamoto, Toshiki ^a   Inagaki, Akiko ^a   Akita, Munetaka ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; ALKYLATION; CATALYSIS; MOLECULAR STRUCTURE; OLEFINS; ORGANOMETALLICS;

ALLYLATION; DINUCLEAR CARBONYL COMPLEXES; LIGANDS; PNNX SYSTEM;

COMPLEXATION;

EID: 33645419775     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050897e     Document Type: Article

References (29)

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5. Complex 6 is obtained as a minor byproduct of the carbonylation and has been characterized only by X-ray crystallography. Crystallographic data are included in the Supporting Information.
6. 5 but intractable mixtures of products were obtained, suggesting considerably different reactivity between the Rh and Ir analogues.
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13. Because of the low quality of the crystal, the result for 10bb is not included in this paper. Crystal data for 10bb: triclinic, space group P1̄, a = 17.553(6) Å, b = 19.473(7) Å, c = 11.441(4) Å, α = 98.91(3)°, β = 90.17(2)°, γ = 65.268(9)°, V = 3500(2) Å3, Z = 4, T = -60 °C.
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17. From the reactions of the PNNN complexes 11 no characterizable product could be obtained.
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29. 13C NMR data and elemental analyses have not been obtained.