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Volumn 29, Issue 1, 2010, Pages 425-433

Synthesis of rhodium-carbonyl complexes bearing a novel P,N-chelating ligand of Schiff-base type

Author keywords

Phosphaalkene; Phosphorus; Rhodium; Schiff base; Steric protection; trans Influence

Indexed keywords


EID: 79551674010     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2009.06.043     Document Type: Article
Times cited : (11)

References (44)
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    • (There have been a few reports on the theoretical calculations for a phosphorus analogue of a Schiff-base type ligand (phosphaalkenylphenoxide) from the viewpoint of catalytic activities, see:)
    • (There have been a few reports on the theoretical calculations for a phosphorus analogue of a Schiff-base type ligand (phosphaalkenylphenoxide) from the viewpoint of catalytic activities, see:). Chan M.S.W., Deng L.Q., and Ziegler T. Organometallics 19 (2000) 2741
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    • (Recently, anilido-phosphiniimine complexes have been synthesized, see:). Conroy K.D., Piers W.E., and Parvez M. J. Organomet. Chem. 693 (2008) 834
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    • All calculations were conducted using the gaussian 03 series of electronic structure programs. The geometries were optimized with density functional theory at the B3PW91 level using 6-31G(d) basis sets (for C, H, N, and O), 6-311G(3d) (for P), and Lanl2DZ (for Rh). It was confirmed by frequency calculations that the optimized structures have minimum energies. Computation time was provided by the Super Computer Laboratory, Institute for Chemical Research, Kyoto University.
    • All calculations were conducted using the gaussian 03 series of electronic structure programs. The geometries were optimized with density functional theory at the B3PW91 level using 6-31G(d) basis sets (for C, H, N, and O), 6-311G(3d) (for P), and Lanl2DZ (for Rh). It was confirmed by frequency calculations that the optimized structures have minimum energies. Computation time was provided by the Super Computer Laboratory, Institute for Chemical Research, Kyoto University.
  • 38
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    • 2 (1.0 mg, 2.5 μmol) under the reflux conditions for 4 h. All of these control reactions were unsuccessful with the quantitative recover of 2-cyclohexen-1-one.
    • 2 (1.0 mg, 2.5 μmol) under the reflux conditions for 4 h. All of these control reactions were unsuccessful with the quantitative recover of 2-cyclohexen-1-one.
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    • (For the recent development on phospha-Peterson reactions, see:) (and references cited therein)
    • (For the recent development on phospha-Peterson reactions, see:). Yam M., Chong J.H., Tsang C.W., Patrick B.O., Lam A.E., and Gates D.P. Inorg. Chem. 45 (2006) 5225 (and references cited therein)
    • (2006) Inorg. Chem. , vol.45 , pp. 5225
    • Yam, M.1    Chong, J.H.2    Tsang, C.W.3    Patrick, B.O.4    Lam, A.E.5    Gates, D.P.6


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.