Structural snapshots of a flexible Cu2P2 core that accommodates the oxidation states CuICuI, Cu 1.5Cu1.5, and CuIICuII

Journal of the American Chemical Society

Volumn 127, Issue 46, 2005, Pages 16032-16033

  Mankad, Neal P ^a   Rivard, Eric ^a   Harkins, Seth B ^a   Peters, Jonas C ^a  

^a California Institute of Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIC POTENTIOMETRY; MOLECULAR STABILITY; OXIDATION; REDUCTION; STRUCTURE ANALYSIS; X RAY DIFFRACTION;

EID: 28144437745     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja056071l     Document Type: Article

References (30)

1. (a) Gray, H. B.; Malmstrom, B. G.; Williams, R. J. P. J. Biol. Inorg. Chem. 2000, 5, 551.
2. (b) Rorabacher, D. B. Chem. Rev. 2004, 104, 651.
3. Marcus, R. A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 265.
4. Azacryptand ligands can overcome the need for large structural reorganization and ligand addition/loss/exchange. See: Nelson J.; McKee, V.; Morgan, G. G. Prog. Inorg. Chem. 1998, 47, 167.
5. Harkins, S. B.; Peters, J. C. J. Am. Chem. Soc. 2004, 126, 2885.
6. (a) Williams, P. A.; Blackburn, N. J.; Sanders, D.; Bellamy, H.; Stura, E. A.; Fee, J. A.; McRee, D. E. Nat. Struct. Biol. 1999, 6, 509.
7. (b) DeBeer George, S.; Metz, M.; Szilagyi, R. K.; Wang, H.; Cramer, S. P.; Lu, Y.; Tolman, W. B.; Hedman, B.; Hodgson, K. O.; Solomon, E. I. J. Am. Chem. Soc. 2001, 123, 5757.
8. (c) Gamelin, D. R.; Randall, D. W.; Hay, M. T.; Houser, R. P.; Mulder, T. C.; Canters, G. W.; de Vries, S.; Tolman, W. B.; Lu, Y.; Solomon, E. I. J. Am. Chem. Soc. 1998, 120, 5246.
9. For other examples of dicopper class III mixed-valence species, see: (a) Houser, R. P.; Young, V. G., Jr.; Tolman, W. B. J. Am. Chem. Soc. 1996, 118, 2101.
10. (b) He, C.; Lippard, S. J. Inorg. Chem. 2000, 39, 5225.
11. 2 system will be reported in due course.
12. 1.5 state: Jiang, X.; Bollinger, J. C.; Baik, M.-H.; Lee, D. Chem. Commun. 2005, 1043.
13. Snyder, B. S.; Patterson, G. S.; Abrahamson, A. J.; Holm, R. H. J. Am. Chem. Soc. 1989, 111, 5214.
14. For example: (a) Sellmann, D.; Binder, H.; Häussinger, D.; Heinemann, F. W.; Sutter, J. Inorg. Chim. Acta 2000, 300-302, 829.
15. (b) Huynh, M. H. V.; El-Samanody, E.-S.; White, P. S.; Meyer, T. J. Inorg. Chem. 1999, 38, 3760.
16. Robin, M.; Day, P. Adv. Inorg. Radiochem. 1967, 10, 247.
17. 31P NMR resonances relating to metal-metal bonding, see: (a) Targos, T. S.; Geoffroy, G. L.; Rheingold, A. L. Organometallics 1986, 5, 12 and references therein.
18. (b) Cartwright, S. J.; Dixon, K. R.; Rattray, A. D. Inorg. Chem. 1980, 19, 1120.
19. 31P chemical shifts on bond angle, see: Garrou, P. E. Chem. Rev. 1981, 81, 229.
20. 9 centers in dicopper systems, see: (a) Charlot, M. F.; Jeannin, S.; Jeannin, Y.; Kahn, O.; Lucrece-Abaul, J.; Martin-Frere, J. Inorg. Chem. 1979, 18, 1675.
21. (b) Crawford, V. H.; Richardson, H. W.; Wasson, J. R.; Hodgson, D. J.; Hatfield, W. E. Inorg. Chem. 1976, 15, 2107.
22. (c) Hay, P. J.; Thibeault, J. C.; Hoffmann, R. J. Am. Chem. Soc. 1975, 97, 4884.
23. For examples, see: (a) Baumann, F.; Livoreil, A.; Kaim, W.; Sauvage, J.-P. Chem. Commun. 1997, 35.
24. (b) Tolman, W. B. Inorg. Chem. 1991, 30, 4877.
25. (c) Knapp, S.; Keenan, T. P.; Zhang, X.; Fikar, R.; Potenza, J. A.; Schugar, H. J. J. Am. Chem. Soc. 1990, 112, 3452.
26. (c) Kitajima, N.; Fujisawa, K.; Moro-oka, Y. J. Am. Chem. Soc. 1990, 112, 3210 and references therein.
27. (a) Pilloni, G.; Bandoli, G.; Tisato, F.; Corain, B. Chem. Commun. 1996, 433.
28. (b) Lobana, T. S.; Bhalia, P. K. J. Chem. Soc., Dalton Trans. 1992, 1407.
29. (c) Zelonka, R. A.; Baird, M. C. Chem. Commun. 1971, 780.
30. See Supporting Information for details.