Theoretical and experimental studies on stability of the C-ON bond in new ketone functionalized N-alkoxyamines

Journal of Physical Organic Chemistry

Volumn 23, Issue 12, 2010, Pages 1146-1154

  Megiel, Elzbieta ^a   Kaim, Andrzej ^a   Cyrański, Michał Ksawery ^a  

^a UNIVERSITY OF WARSAW   (Poland)

Author keywords

bond dissociation energy (BDE); bond homolysis; N alkoxyamine; persistent radical effect (PRE)

Indexed keywords

ALKOXYAMINES; ALKYL RADICALS; ARRHENIUS PARAMETERS; BOND DISSOCIATION ENERGIES; BOND HOMOLYSIS; EXPERIMENTAL STUDIES; FUNCTIONALIZATIONS; FUNCTIONALIZED; HOMO-LUMO GAPS; HOMOLYSIS; HOMOLYTIC BONDS; N-ALKOXYAMINE; NITROXIDES; ORBITALS; PERSISTENT RADICAL EFFECTS; PROPANONE; QUANTUM-MECHANICAL CALCULATION; RADICAL PRECURSOR; SPIN DENSITIES; SPIN DISTRIBUTION; UNIMOLECULAR INITIATORS;

ACETONE; ALKYLATION; DISSOCIATION; ORGANIC COMPOUNDS; SPIN DYNAMICS;

RATE CONSTANTS;

EID: 78649869694     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.1685     Document Type: Article

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