Photochemical synthesis of TEMPO-capped initiators for 'living' free radical polymerization

Tetrahedron Letters

Volumn 37, Issue 28, 1996, Pages 4919-4922

  Connolly, Terrence J ^a   Baldovi M V ^a   Mohtat, N ^a   Scaiano, J C ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

FREE RADICAL; STYRENE; TEMPOL;

ARTICLE; LASER; PHOTOCHEMISTRY; PHOTODEGRADATION; PHOTOLYSIS; POLYMERIZATION; STOICHIOMETRY; SYNTHESIS;

EID: 0030575371     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)00986-0     Document Type: Article

References (18)

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15. (15) Baldoví, M.V.; Mohtat, N.; Scaiano, J.C., Macromolecules 1996, in press.
16. (16) The laser system uses Lumonics EX-530 for excitation wavelengths of 248 and 308 nm and a Surelite laser for 266 nm. The signals from the system were captured by a Tektronix 2440 digitizer and transferred to a PowerMacintosh computer that controlled the experiment. Other aspects are similar to those described earlier: Scaiano, J.C. J. Am. Chem. Soc. 1980, 102, 7747; Scaiano, J.C.; Tanner, M.; Weir, D. J. Am. Chem. Soc. 1985, 107, 4396.
17. (16) The laser system uses Lumonics EX-530 for excitation wavelengths of 248 and 308 nm and a Surelite laser for 266 nm. The signals from the system were captured by a Tektronix 2440 digitizer and transferred to a PowerMacintosh computer that controlled the experiment. Other aspects are similar to those described earlier: Scaiano, J.C. J. Am. Chem. Soc. 1980, 102, 7747; Scaiano, J.C.; Tanner, M.; Weir, D. J. Am. Chem. Soc. 1985, 107, 4396.
18. (17) This work was supported by operating grants from the Natural Sciences and Engineering Research Council of Canada. JCS also thanks the Canada Council for the award of a Killam Fellowship.