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Volumn 31, Issue 25, 1998, Pages 9103-9105

Decomposition kinetics, arrhenius parameters, and bond dissociation energies for alkoxyamines of relevance in "living" free radical polymerization

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; ALCOHOLS; AMINES; CHEMICAL BONDS; DISSOCIATION; ENTROPY; FREE RADICAL POLYMERIZATION; GROUND STATE; ORGANIC SOLVENTS; PHOTOLYSIS; POLYESTERS; RATE CONSTANTS;

EID: 0032291931     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9812229     Document Type: Article
Times cited : (127)

References (32)
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    • (1979) Polym. Bull. , vol.1 , pp. 529
    • Rizzardo, E.1    Solomon, D.H.2
  • 2
    • 0000989893 scopus 로고
    • Rizzardo, E.; Solomon, D. H. Polym. Bull. 1979, 1, 529. Moad, G.; Rizzardo, E.; Solomon, D. H. Tetrahedron Lett. 1981, 22, 1165. Moad, G.; Rizzardo, E.; Solomon, D. H. Macromolecules 1982, 15, 909. Moad, G.; Rizzardo, E.; Solomon, D. H. Polym. Bull. 1982, 6, 589. Beckwith, A. L. J.; Bowry, V. W.; O'Leary, M.; Moad, G.; Rizzardo, E.; Solomon, D. H. J. Chem. Soc., Chem. Commun. 1986, 1003.
    • (1981) Tetrahedron Lett. , vol.22 , pp. 1165
    • Moad, G.1    Rizzardo, E.2    Solomon, D.H.3
  • 3
    • 0000610722 scopus 로고
    • Rizzardo, E.; Solomon, D. H. Polym. Bull. 1979, 1, 529. Moad, G.; Rizzardo, E.; Solomon, D. H. Tetrahedron Lett. 1981, 22, 1165. Moad, G.; Rizzardo, E.; Solomon, D. H. Macromolecules 1982, 15, 909. Moad, G.; Rizzardo, E.; Solomon, D. H. Polym. Bull. 1982, 6, 589. Beckwith, A. L. J.; Bowry, V. W.; O'Leary, M.; Moad, G.; Rizzardo, E.; Solomon, D. H. J. Chem. Soc., Chem. Commun. 1986, 1003.
    • (1982) Macromolecules , vol.15 , pp. 909
    • Moad, G.1    Rizzardo, E.2    Solomon, D.H.3
  • 4
    • 0020101572 scopus 로고
    • Rizzardo, E.; Solomon, D. H. Polym. Bull. 1979, 1, 529. Moad, G.; Rizzardo, E.; Solomon, D. H. Tetrahedron Lett. 1981, 22, 1165. Moad, G.; Rizzardo, E.; Solomon, D. H. Macromolecules 1982, 15, 909. Moad, G.; Rizzardo, E.; Solomon, D. H. Polym. Bull. 1982, 6, 589. Beckwith, A. L. J.; Bowry, V. W.; O'Leary, M.; Moad, G.; Rizzardo, E.; Solomon, D. H. J. Chem. Soc., Chem. Commun. 1986, 1003.
    • (1982) Polym. Bull. , vol.6 , pp. 589
    • Moad, G.1    Rizzardo, E.2    Solomon, D.H.3
  • 5
    • 37049076624 scopus 로고
    • Rizzardo, E.; Solomon, D. H. Polym. Bull. 1979, 1, 529. Moad, G.; Rizzardo, E.; Solomon, D. H. Tetrahedron Lett. 1981, 22, 1165. Moad, G.; Rizzardo, E.; Solomon, D. H. Macromolecules 1982, 15, 909. Moad, G.; Rizzardo, E.; Solomon, D. H. Polym. Bull. 1982, 6, 589. Beckwith, A. L. J.; Bowry, V. W.; O'Leary, M.; Moad, G.; Rizzardo, E.; Solomon, D. H. J. Chem. Soc., Chem. Commun. 1986, 1003.
    • (1986) J. Chem. Soc., Chem. Commun. , vol.1003
    • Beckwith, A.L.J.1    Bowry, V.W.2    O'Leary, M.3    Moad, G.4    Rizzardo, E.5    Solomon, D.H.6
  • 24
    • 85034468738 scopus 로고    scopus 로고
    • note
    • Typical initial concentrations are 20 mM for the alkoxyamine and 60 mM for the nitroxide trap.
  • 28
    • 85034472771 scopus 로고    scopus 로고
    • note
    • HPLC analyses were carried out using a Zorbax SB-C18 reverse-phase column with 85:15 methanol/water as eluent. The flow rate was 0.5 mL/min for the first 12 min and 1.5 mL/min after that. Results are based on products formed rather than comsumption of starting material, since at the low conversions used the latter is subject to considerable errors. Product concentrations (coupling and traces of disproportionation) were determined against authentic samples.


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