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Volumn 16, Issue 45, 2010, Pages 13429-13434

Ylenes in the MII→SiIV (M=Si, Ge, Sn) coordination mode

Author keywords

coordination compounds; intermetallic bonding; main group elements; M ssbauer spectroscopy; oligosilanes; silylenes

Indexed keywords

COORDINATION COMPOUNDS; INTERMETALLIC BONDING; MAIN-GROUP ELEMENTS; OLIGOSILANES; SILYLENES; SSBAUER SPECTROSCOPIES;

EID: 78649819165     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201002191     Document Type: Article
Times cited : (27)

References (72)
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    • For reviews on higher-coordinate silicon compounds, see, for example
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    • note
    • 2=0.1214. For tables containing more crystal data and bond lengths and angles please see the Supporting Information.
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    • 3Si(mt) was already mentioned in:,. For its preparation and characterization please see the Supporting Information
    • 3Si(mt) was already mentioned in:, E. Brendler, T. Heine, A. F. Hill, J. Wagler, Z. Anorg. Allg. Chem. 2009, 635, 1300-1305. For its preparation and characterization please see the Supporting Information.
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    • note
    • The triflate-substituted tetrasilanes reported by Tacke eta al. exhibit two adjacent Si atoms with bicapped tetrahedral coordination spheres (long Si-O separations of ca. 2.7-2.9a Å). A similar kind of "capped" coordination is found in a disilane reported as heptacoordinate by Kawashima eta al. with long Si-S separations (ranging between 3.0 and 3.5a Å). According to their definition, atom Si1 of compound 3a would have to be referred to as "decacoordinate" and atom Si3 "octacoordinate", as indicated by the additional S donors with longer Si-S interatomic separations [Å] in 3a: Si1-S1 3.436(1), Si1-S2 3.436(1), Si1-S3 3.430(1), Si1-S4 3.407(1), Si3-S1 3.216(1), Si3-S2 3.374(1), Si3-S3 3.471(1), Si3-S4 3.342(1)
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    • 3 solution. Thus, NMR spectra of the solids were recorded.
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    • 119Sn Mössbauer spectroscopic investigation at 77a K. Fitting of the spectra was performed with the Normos-90 program system [27]
    • 119Sn Mössbauer spectroscopic investigation at 77a K. Fitting of the spectra was performed with the Normos-90 program system [27].
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.