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Volumn 27, Issue 17, 2008, Pages 4395-4400

Syntheses, structures, and reactions of 2,2,3,3- tetrakis(trifluoromethanesulfonato)tetrasilanes: Hexacoordination ([4 + 2] coordination) of the two central silicon atoms

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL ATOMIC STRUCTURE; NONMETALS; SILICON;

EID: 52649175382     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800332j     Document Type: Article
Times cited : (20)

References (41)
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    • Selected reviews dealing with higher-coordinate silicon compounds: (a) Chuit, C.; Corriu, R. J. P.; Reye, C.; Young, J. C. Chem. Rev. 1993, 93, 1371-1448.
  • 2
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    • (b) Holmes, R. R. Chem. Rev. 1996, 96, 927-950.
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  • 3
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    • (c) Kost, D.; Kalikhman, I. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, UK, 1998; Vol. 2, Part 2, pp 1339-1445.
    • (1998) The Chemistry of Organic Silicon Compounds , vol.2 , Issue.PART 2 , pp. 1339-1445
    • Kost, D.1    Kalikhman, I.2
  • 22
    • 0035903690 scopus 로고    scopus 로고
    • Angew. Chem., Int. Ed. 2001, 40, 3450-3452.
    • (2001) Angew. Chem., Int. Ed , vol.40 , pp. 3450-3452
  • 27
    • 21844469220 scopus 로고    scopus 로고
    • The existence of a silicon polymer built up by a chain of hexacoordinate silicon atoms has been claimed. However, this polymer was characterized only by 29Si NMR and IR spectroscopy: Mucha, F, Böhme, U, Roewer, G. Chem. Commun. 1998, 1289-1290
    • 29Si NMR and IR spectroscopy: Mucha, F.; Böhme, U.; Roewer, G. Chem. Commun. 1998, 1289-1290.
  • 28
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    • and references therein
    • Uhlig, W. Chem. Ber. 1996, 129, 733-739, and references therein.
    • (1996) Chem. Ber , vol.129 , pp. 733-739
    • Uhlig, W.1
  • 34
    • 18744397258 scopus 로고    scopus 로고
    • Although compound 2c has already been synthesized using the method reported in ref 11, the physical data of 2c and experimental details of the synthesis have not been described: Suginome, M, Iwanami, T, Ohmori, Y, Matsumoto, A, Ito, Y. Chem. Eur. J. 2005, 11, 2954-2965
    • Although compound 2c has already been synthesized using the method reported in ref 11, the physical data of 2c and experimental details of the synthesis have not been described: Suginome, M.; Iwanami, T.; Ohmori, Y.; Matsumoto, A.; Ito, Y. Chem. Eur. J. 2005, 11, 2954-2965.
  • 36
    • 37049068695 scopus 로고    scopus 로고
    • Although compound 3c has already been used as a starting material, the physical data of 3c have not been reported: Matsumoto, H, Higuchi, K, Hoshino, Y, Koike, H, Naoi, Y, Nagai, Y. J. Chem. Soc, Chem. Commun. 1988, 1083-1084. Compound 3c was synthesized similarly to compound 3a
    • Although compound 3c has already been used as a starting material, the physical data of 3c have not been reported: Matsumoto, H.; Higuchi, K.; Hoshino, Y.; Koike, H.; Naoi, Y.; Nagai, Y. J. Chem. Soc., Chem. Commun. 1988, 1083-1084. Compound 3c was synthesized similarly to compound 3a.
  • 37
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    • Although compound 4c could be obtained as a colorless crystalline solid from dichloromethane/toluene at -20 °C, it was not possible to determine its yield exactly because 4c quickly decomposed during the operation of removing the solvents and trifluoromethanesulfonic acid in vacuo
    • Although compound 4c could be obtained as a colorless crystalline solid from dichloromethane/toluene at -20 °C, it was not possible to determine its yield exactly because 4c quickly decomposed during the operation of removing the solvents and trifluoromethanesulfonic acid in vacuo.
  • 39
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    • University of Göttingen: Göttingen, Germany
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    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.