A base-stabilized silylene with a tricoordinate silicon atom as a ligand for a metal complex

Inorganic Chemistry

Volumn 48, Issue 12, 2009, Pages 5058-5060

  Yang, Wei ^a   Fu, Hao ^a   Wang, Haijun ^a   Chen, Mingqing ^a   Ding, Yuqiang ^a   Roesky, Herbert W ^a,b   Jana, Anukul ^b  

^a JIANGNAN UNIVERSITY   (China)

^b UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 67249166195     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic900204c     Document Type: Article

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29. 2. After stirring for 40 h, the initially light orange solution became darker in color to ultimately afford a garnet brown solution. Solvent was then removed in vacuo, and the residue was extracted with toluene (30 mL). The insoluble solid was filtered off. The garnet brown filtrate was concentrated and stored at -30 °C to yield red-brown crystals of 2 (72%).
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