Octahedral and bicapped-tetrahedral silicon configurations in the solid state and their dynamic coexistence in solution

Organometallics

Volumn 25, Issue 5, 2006, Pages 1252-1258

  Kalikhman, Inna ^a   Gostevskii, Boris ^a,b   Botoshansky, Mark ^c   Kaftory, Menahem ^c   Tessier, Claire A ^d   Panzner, Matthew J ^d   Youngs, Wiley J ^d   Kost, Daniel ^a  

^a BEN GURION UNIVERSITY OF THE NEGEV   (Israel)

^b A E FAVORSKY IRKUTSK INSTITUTE OF CHEMISTRY   (Russian Federation)

^c TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

^d UNIVERSITY OF AKRON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BICAPPED-TETRAHEDRAL GEOMETRY; BICAPPED-TETRAHEDRAL SILICON CONFIGURATIONS; NITROGEN-DONOR LIGANDS; TETRAHEDRAL GROUND-STATE CONFIGURATION;

CRYSTAL STRUCTURE; DIFFRACTION; ELECTRONS; MOLECULAR STRUCTURE; SOLID STATE PHYSICS; THERMAL EFFECTS;

SILICON;

EID: 33644886295     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0509802     Document Type: Article

References (44)

1. Preliminary report: Gostevskii, B.; Kalikhman, I.; Tessier, C. A.; Panzner, M. J.; Youngs, W. J.; Kost, D. Proceedings of the 14th International Symposium on Organosilicon Chemistry ISOSXIV, Würzburg, Germany, August 2005; p 49.
2. For reviews on hypercoordinate silicon complexes see: (a) Tandura, S. N.; Voronkov, M. G.; Alekseev, N. V. Top. Curr. Chem. 1986, 131, 99-189.
3. (b) Kost, D.; Kalikhman, I. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 2, pp 1339-1445.
4. (c) Bassindale, A. R.; Taylor, P. G. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley: Chichester, U.K., 1989; Vol. 1, pp 839-892.
5. (d) Bassindale, A. R.; Glynn, S. J.; Taylor, P. G. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, pp 495-511.
6. (e) Holmes, R. R. Chem. Rev. 1990, 90, 17-31;
7. Holmes, R. R. Chem. Rev. 1996, 96, 927-950.
8. (f) Corriu, R. J. P.; Young, J. C. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley: Chichester, U.K., 1989; Vol. 1, pp 1241-1288.
9. (g) Chuit, C.; Corriu, R. J. P.; Reyé, C.; Young, J. C. Chem. Rev. 1993, 93, 1371.
10. (h) Chuit, C.; Corriu, R. J. P.; Reyé, C. In The Chemistry of Hypervalent Compounds; Akiba, K., Ed.; Wiley-VCH: Weinheim, Germany, 1999; pp 81-146.
11. (i) Kira, M.; Zhang, L. C. In The Chemistry of Hypervalent Compounds; Akiba, K., Ed.; Wiley-VCH: Weinheim, Germany, 1999; pp 147-169.
12. (j) Brook, M. A. Silicon in Organic, Organometallic and Polymer Chemistry; Wiley: New York, 2000; pp 97-115.
13. (k) Tacke, R.; Pülm, M.; Wagner, B. Adv. Organomet. Chem. 1999, 44, 221-273.
14. (l) Tacke, R.; Seiler, O. In Silicon Chemistry: From the Atom to Extended Systems; Jutzi, P., Schubert, U., Eds.; Wiley-VCH: Weinheim, Germany, 2003; pp 324-337.
15. (m) Lukevics, E.; Pudova, O. A. Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381-1418.
16. (n) Voronkov, M. G.; Pestunovich, V. A.; Baukov, Yu. I. Organomet. Chem. USSR 1991, 4, 593.
17. Chem. Abstr. 1992, 116, 41503y.
18. (o) Verkade, J. G. Coord. Chem. Rev. 1994, 137, 233-295.
19. (p) Kost, D.; Kalikhman, I. Adv. Organomet. Chem. 2004, 50, 1-106.
20. Kost, D.; Kingston, V.; Gostevskii, B.; Ellern, A.; Stalke, D.; Walfort, B.; Kalikhman, I. Organometallics 2002, 21, 2293.
21. Gostevskii, B.; Silbert, G.; Adear, K.; Sivaramakrishna, A.; Stalke, D.; Deuerlein, S.; Kocher, N.; Voronkov, M. G.; Kalikhman, I.; Kost, D. Organometallics 2005, 24, 2913.
22. When 1:1 molar ratios of the reactants in eqs 2 and 3 are used, pentacoordinate monochelate compounds can be isolated: (a) Kalikhman, I. D.; Gostevskii, B. A.; Bannikova, O. B.; Voronkov, M. G.; Pestunovich, V. A. Metalloorg. Khim. 1989, 2, 205.
23. Chem. Abstr. 1990, 112, 77291j.
24. (b) Kalikhman, I.; Krivonos, S.; Ellern, A.; Kost, D. Organometallics 1996, 15, 5073.
25. (a) Breliere, C.; Carré, F.; Corriu, R. J. P.; Poirier, M.; Royo, G.; Zwecker, J., Organometallics 1989, 8, 1831.
26. (b) Carré, F.; Cerveau, G.; Chuit, C.; Corriu, R. J. P.; Reyé, C. New J. Chem, 1992, 16, 63.
27. (c) BoyerElma, K.; Carré, F.; Corriu, R. J. P.; Douglas, W. E. J. Chem. Soc., Chem. Commun. 1995, 725.
28. (d) Carré, F.; Chuit, C.; Corriu, R. J. P.; Mehdi, A.; Reyé, C. Organometallics 1995, 14, 2754.
29. (e) Belzner, J.; Schär, D.; HerbstIrmer, R.; Kneisel, B. O,; Noltemeyer, M. Tetrahedron 1998, 54, 8481.
30. (f) Ahdab, A. A.-E.; Rima, G.; Gornitzka, H.; Barrau, J. J. Organomet. Chem. 2001, 636, 96.
31. (g) Karsch, H. H.; Deubelly, B.; Keller, U.; Bienlein, F.; Richter, R.; Bissinger, P.; Heckel, M.; Mueller, G. Chem. Ber. 1996, 129, 759.
32. (h) Wagler, J.; Schley, M.; Gerlach, D.; Böhme, U.; Brendler, E.; Roewer, G. Z. Naturforsch. 2005, 60b, 1054.
33. (a) Kalikhman, I.; Gostevskii, B.; Girshberg, O.; Krivonos, S.; Kost, D. Organometallics 2002, 21, 2551.
34. (b) Kalikhman, I.; Gostevskii, B.; Girshberg, O.; Sivaramakrishna, A.; Kocher, N.; Stalke, D.; Kost, D. J. Organomet. Chem. 2003, 686, 202.
35. Kalikhman, I.; Krivonos, S.; Stalke, D.; Kottke, T.; Kost, D. Organometallics, 1997, 16, 3255.
36. Klebe, G.; Tran Qui, D. Acta Crystallogr. 1984, C40, 476.
37. Gostevskii, B.; Kalikhman, I.; Tessier, C. A.; Panzner, M. J.; Youngs, W. J.; Kost, D. Organometallics 2005, 24, 5786.
38. Engelhardt, G.; Mägi, M.; Lippmaa, E. J. Organomet. Chem. 1973, 54, 115.
39. Kintzinger, J.-P.; Marsmann, H. Nucl. Magn. Reson. 1981, 17, 65.
40. For the only previously reported similar situation see ref 6h and: Wagler, J.; Böhme, U.; Brendler, E.; Roewer, G. Organometallics 2005, 24, 1348.
41. Kost, D.; Kalikhman, I.; Raban, M. J. Am. Chem. Soc. 1995, 117, 11512.
42. Jensen, K. A. Acta Chem. Scand., Ser. B 1977, B31, 145.
43. Gostevskii, B.; Pestunovich, V.; Kalikhman, I.; Sivaramakrishna, A.; Kocher, N.; Deuerlein, S.; Leusser, D.; Stalke, D.; Kost, D. Organometallics 2004, 23, 4346.
44. Majchrzak, M. W.; Bekhazi, M.; Tse-Sheepy, I.; Warkentin, J. J. Org. Chem. 1989, 54, 1842.