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Volumn 15, Issue 30, 2009, Pages 7329-7338

Neutral pentacoordinate silicon(IV) complexes with silicon-chalcogen (S, Se, Te) bonds

Author keywords

Chalcogens; Coordination chemistry; Pentacoordination; Silicon; Tridentate ligands

Indexed keywords

CHALCOGEN; CHALCOGENS; COORDINATION CHEMISTRY; NMR SPECTROSCOPY; PENTACOORDINATE SILICON; PENTACOORDINATION; SINGLE CRYSTAL X-RAY DIFFRACTION; TRIDENTATE LIGANDS;

EID: 67651070969     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200900592     Document Type: Article
Times cited : (29)

References (38)
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    • For selected reviews dealing with higher-coordinate silicon compounds, see: a
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    • Eds, Z. Rappoport, Y. Apeloig, Wiley, New York
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    • (1998) The Chemistry of Organic Silicon Compounds , vol.2 , Issue.PART 2 , pp. 1339-1445
    • Kost, D.1    Kalikhman, I.2
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    • 0037415563 scopus 로고    scopus 로고
    • For selected publications dealing with penlacoordinate silicon compounds thai contain Si-Cl or Si-Br bonds, see: a A. R. Bassindale, D. J. Parker, P. G. Taylor, N. Auner, B. Herrschaft, J. Organomet. Chem. 2003, 667, 66-72;
    • For selected publications dealing with penlacoordinate silicon compounds thai contain Si-Cl or Si-Br bonds, see: a) A. R. Bassindale, D. J. Parker, P. G. Taylor, N. Auner, B. Herrschaft, J. Organomet. Chem. 2003, 667, 66-72;
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    • (2005) Angew. Chem. Int. Ed , vol.44 , pp. 6738-6741
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    • Angew. Chem. Int. Ed. 2007, 46, 7006-7009.
    • (2007) Angew. Chem. Int. Ed , vol.46 , pp. 7006-7009
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    • 0035907716 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2001, 40, 2339-2341;
    • (2001) Angew. Chem. Int. Ed , vol.40 , pp. 2339-2341
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    • and references therein;
    • Angew. Chem. Int. Ed. 2007, 46, 7001-7005, and references therein;
    • (2007) Angew. Chem. Int. Ed , vol.46 , pp. 7001-7005
  • 22
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    • 29Si chemical shift (δ = -6.7 ppm) also indicates only a weak Si⋯Se interaction; see: T. Saeki. A. Toshimitsu, K. Tamao, Organometallics 2003, 22, 3299-3303.
    • 29Si chemical shift (δ = -6.7 ppm) also indicates only a weak Si⋯Se interaction; see: T. Saeki. A. Toshimitsu, K. Tamao, Organometallics 2003, 22, 3299-3303.
  • 26
    • 67651038594 scopus 로고    scopus 로고
    • Data taken from: Holleman-Wiberg, Lehrbuch der Anorganischen Chemie, 102nd ed., Walter de Gruyter, Berlin, 2007, p. 138.
    • Data taken from: Holleman-Wiberg, Lehrbuch der Anorganischen Chemie, 102nd ed., Walter de Gruyter, Berlin, 2007, p. 138.
  • 27
    • 67651023219 scopus 로고    scopus 로고
    • The Berry distortions were analyzed by using the PLATON program system; A. L. Spek, PLATON. Utrecht University, Utrecht, The Netherlands, 2008.
    • The Berry distortions were analyzed by using the PLATON program system; A. L. Spek, PLATON. Utrecht University, Utrecht, The Netherlands, 2008.
  • 29
    • 67651060404 scopus 로고    scopus 로고
    • 29Si NMR measurement to improve the signal-to-noise ratio.
    • 29Si NMR measurement to improve the signal-to-noise ratio.
  • 32
    • 67651051132 scopus 로고    scopus 로고
    • Drying in vacuo over a longer period of time led to a partial loss of acetonitrile
    • Drying in vacuo over a longer period of time led to a partial loss of acetonitrile.
  • 33
    • 67651054233 scopus 로고    scopus 로고
    • 29Si chemical shifts are those of the pentacoordinate species.
    • 29Si chemical shifts are those of the pentacoordinate species.
  • 34
    • 67651076206 scopus 로고    scopus 로고
    • The accuracy of the elemental analysis is affected by the partial loss of acetonitrile even at storage at standard temperature and pressure conditions
    • The accuracy of the elemental analysis is affected by the partial loss of acetonitrile (even at storage at standard temperature and pressure conditions).
  • 35
    • 67651054232 scopus 로고    scopus 로고
    • 29Si resonance signal, not all pairs of satellites expected from the respective structures could be found.
    • 29Si resonance signal, not all pairs of satellites expected from the respective structures could be found.
  • 36
    • 67651045004 scopus 로고    scopus 로고
    • C1 is the atom bound to the XH group with the highest priority
    • C1 is the atom bound to the XH group with the highest priority: OH > SH > SeH.
    • OH > SH > SeH
  • 37
    • 67651013876 scopus 로고    scopus 로고
    • G. M. Sheldrick. SHELXS-97 Program for crystal structure solution, University of Göttingen. Gottingen, Germany, 1997;
    • a) G. M. Sheldrick. SHELXS-97 Program for crystal structure solution, University of Göttingen. Gottingen, Germany, 1997;
  • 38
    • 67651045005 scopus 로고    scopus 로고
    • G. M. Sheldrick, SHELXL-97 Program for crystal structure refinement. University of Götlingen. Gottingen, Germany. 1997.
    • b) G. M. Sheldrick, SHELXL-97 Program for crystal structure refinement. University of Götlingen. Gottingen, Germany. 1997.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.