Synthesis, molecular structures, and reactivity of mono- and binuclear neutral copper(I) carbenes

Inorganic Chemistry

Volumn 47, Issue 24, 2008, Pages 11755-11762

  Hofmann, Peter ^a   Shishkov, Igor V ^a   Rominger, Frank ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 60849099661     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic801443y     Document Type: Article

References (43)

1. Some of this work has been previously presented: Hofmann, P.; Shishkov, I. V.; Rominger, F.; Straub, B. Book of abstracts, 14th International Symposium on Homogeneous Catalysis, München, Germany, July 5-9, 2004; poster No. 0410.
2. (a) Nozaki, H.; Moriuti, S.; Takaya, H.; Noyori, R. Tetrahedron Lett. 1966, 5239.
3. (b) Nozaki, H.; Takaya, H.; Moriuti, S.; Noyori, R. Tetrahedron 1968, 24, 3655.
4. (c) For a review see Kirmse, W. Angew. Chem. 2003, 115, 1120;
5. Angew. Chem., Int. Ed. 2003, 42, 1088.
6. (d) Doyle, M. P.; McKervey, M. A.; Ye, T. Modern Catalytic Methods for Organic Synthesis with Diazo Compounds; Wiley: New York, 1998;
7. (e) Pfaltz, A. In Transition Metals for Organic Synthesis; Beller, M., Bolm, C., Eds.; Wiley: Weinheim, 1998; Vol. 1, p 100.
8. Fritschi, H.; Leutenegger, U.; Pfaltz, A. Helv. Chim. Acta 1988, 71, 1553.
9. Straub, B. F.; Hofmann, P. Angew. Chem. 2001, 113, 1328;
10. Angew. Chem. Int. Ed. 2001, 40, 1288.
11. Scherer, O. J.; Schieder, G. Chem. Ber. 1968, 101, 4184.
12. (a) Straub, B. F.; Eisenträger, F.; Hofmann, P. Chem. Commun. 1999, 2507.
13. (b) Straub, B. F.; Gruber, I.; Rominger, F.; Hofmann, P. J. Organomet. Chem. 2003, 684, 124.
14. Barluenga, J.; López, L. A.; Löber, O.; Tomás, M.; García-Granda, S.; Alvarez-Rúa, C.; Borge, J. Angew. Chem. 2001, 113, 3495;
15. Angew. Chem., Int. Ed. 2001, 40, 3392.
16. (a) Dai, X.; Warren, T. H. J. Am. Chem. Soc. 2004, 126 (32), 10085.
17. (b) Badiei, Y. M.; Warren, T. H. J. Organomet. Chem. 2005, 690, 5989.
18. (c) Mankad, N. P.; Peters, J. C. Chem. Commun. 2008, 1061.
19. Straub, B. F.; Rominger, F.; Hofmann, P. Organometallics 2000, 19, 4305.
20. (a) Doyle, M. P.; McKervey, M. A. Chem. Commun. 1997, 983.
21. (b) Bühl, M.; Terstegen, F.; Löffler, F.; Meynhardt, B.; Kierse, S.; Müller, M.; Näther, C.; Lüning, U. Eur. J. Org. Chem. 2001, 2151.
22. (c) Rasmussen, T.; Jensen, J. F.; Østergaard, N.; Tanner, D.; Ziegler, T.; Norrby, P.-O. Chem. - Eur. J. 2002, 8, 177.
23. (d) Fraile, J. M.; García, J. I.; Martínez-Merino, V.; Mayoral, J. A.; Salvatella, L. J. Am. Chem. Soc. 2001, 123, 7616.
24. Bent, H. A. Chem. Rev. 1961, 61, 275.
25. Macomber, R. S. A Complete Introduction to Modern NMR Spectroscopy, Wiley: New York, 1998.
26. (a) Raubenheimer, H. G.; Cronje, S.; Olivier, P. J. J. Chem. Soc., Dalton Trans. 1995, 313.
27. (b) Raubenheimer, H. G.; Cronje, S.; van Rooyen, P. H.; Olivier, P. J.; Toerien, J. G. Angew. Chem. 1994, 106, 687;
28. Angew. Chem. Int, Ed. Engl. 1994, 33, 672.
29. 3 = 1.913(6) Å.
30. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals; Wiley: New York, 1994; p 276.
31. Hofmann, P.; Heiss, H.; Müller, G. Z. Naturforsch., Teil B 1987, 42, 395.
32. Díaz-Requejo, M. M.; Nicasio, M. C.; Pérez, P. J. Organometallics 1998, 17, 3051.
33. Díaz-Requejo, M. M.; Belderrain, T. R.; Nicasio, M. C.; Prieto, F.; Pérez, P. J. Organometallics 1999, 18, 2601.
34. Mussons, M. L.; Raposo, C.; Anaya, J.; Grande, M.; Morán, J. R.; Caballero, M. C. J. Chem. Soc. Perkin Trans. 1 1992, 3125.
35. Just, G.; Wang, Z. Y.; Chan, L. J. Org. Chem. 1988, 53, 1030.
36. (a) Eichkorn, K.; Treutler, O.; Oehm, H.; Haeser, M.; Ahlrichs, R. Chem. Phys. Lett. 1995, 240, 283.
37. (b) Eichkorn, K.; Treutler, O.; Oehm, H.; Haeser, M.; Ahlrichs, R. Chem. Phys. Lett. 1995, 242, 652.
38. (c) Ahlrichs, R.; Baer, M.; Haeser, M.; Horn, H.; Koelmel, C. Chem. Phys. Lett. 1989, 162, 165.
39. Becke, A. D. Phys. Rev. 1988, A38, 3098.
40. (a) Perdew, J. P.; Zunger, A. Phys. Rev. 1981, B23, 5048.
41. (b) Perdew, J. P. Phys. Rev. 1986, B33, 8822.
42. Bhawal, B. M.; Khanapure, S. P.; Biehl, E. R. Synthesis 1991, 112.
43. Sheldrick, G. M. SMART, SHELXTL-PLUS, SADABS; Bruker Analytical X-ray-Division: MadisonWI 2008.