The anion of a phenyltris(alkylamino)phosphonium (PhTAP) salt as a chelating ligand: Synthesis and X-ray crystal structure of a 16-electron ruthenium(II) organometallic complex

Organometallics

Volumn 17, Issue 4, 1998, Pages 551-555

  Bailey, Philip J ^a   Grant, Keith J ^a   Parsons, Simon ^a  

^a UNIVERSITY OF EDINBURGH   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000193779     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970819u     Document Type: Article

References (58)

1. (a) Schrock, R. R. Acc. Chem. Res. 1997, 30, 9 and references therein.
2. (b) Menge, W. M. P. B.; Verkade, J. G. Inorg. Chem. 1991, 30, 4628.
3. (c) Cummins, C. C.; Schrock, R. R.; Davis, W. M. Inorg. Chem. 1994, 33, 1448.
4. (d) Ge, P.; Haggerty, B. S.; Rheingold, A. L.; Riordan, C. G. J. Am. Chem. Soc. 1994, 116, 8406.
5. (e) Canary, J. W.; Allen, C. S.; Castagnetto, J. M.; Wang, Y. J. Am. Chem. Soc. 1995, 117, 8484.
6. (f) Nomura, K.; Schrock, R. R.; Davis, W. M. Inorg. Chem. 1996, 35, 3695.
7. (g) Kernbach, U.; Ramm, M.; Luger, P.; Fehlhammer, W. P. Angew. Chem, Int. Ed. Engl. 1996, 35, 310.
8. (h) Friedrich, S.; Gade, L. H.; Li, W. S.; McPartlin, M. Chem. Ber. 1996, 129, 1287.
9. (i) Memler, H.; Kauper, U.; Gade, L. H.; Stalke, D.; Lauher, J. W. Organometallics 1996, 15, 3637.
10. (j) Freidrichs, S.; Memler, H.; Gade, L. H.; Li, W. S.; Scowen, I. J.; McPartlin, M.; Housecroft, C. E. Inorg. Chem. 1996, 35, 2433.
11. (k) Lah, M. S.; Chun, H. Inorg. Chem. 1997, 36, 1782.
12. (l) Findeis, B.; Contel, M.; Gade, L. H.; Laguna, M.; Concepcion, M.; Scowen, I. J.; McPartlin, M. Inorg. Chem. 1997, 36, 2386.
13. (a) Burk, M. J.; Harlow, R. L. Angew. Chem, Int. Ed. Engl. 1990, 29, 1462.
14. (b) Ward, T. R.; Venanzi, L. M.; Albinati, A.; Lianza, F.; Gerfin, T.; Gramlich, V.; Tombo, G. M. R. Helv. Chim. Acta 1991, 74, 983.
15. (c) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Tetrahedron: Asymmetry 1991, 2, 569.
16. (d) Nugent, W. A. J. Am. Chem. Soc. 1992, 114, 2786.
17. (e) Tokar, C. J.; Kettler, P. B.; Tolman, W. B. Organometallics 1992, 11, 2737.
18. (f) Adolfsson, H.; Warnmark, K.; Moberg, C. J. Chem. Soc., Chem. Commun. 1992, 1054.
19. (g) LeCloux, D. D.; Tolman, W. B. J. Am. Chem. Soc. 1993, 115, 1153.
20. (h) LeCloux, D. D.; Tokar, C. J.; Osawa, M.; Houser, R. P.; Keys, M. C.; Tolman, W. B. Organometallics 1994, 13, 2855.
21. (i) Nugent, W. A.; Harlow, R. L. J. Am. Chem. Soc. 1994, 116, 6142.
22. (j) Hammes, B. S.; Ramos-Maldonado, D.; Yap, G. P. A.; Liable-Sands, L.; Rheingold, A. L.; Young, V. G., Jr.; Borovik, A. S. Inorg. Chem. 1997, 36, 3210.
23. (k) Bolm, C.; Kadereit, D.; Valacchi, M. Synlett 1997, 687.
24. Bailey, P. J.; Blake, A. J.; Kryszczuk, M.; Parsons, S.; Reed, D. J. Chem. Soc., Chem. Commun. 1995, 1647.
25. (a) Bird, P. H.; Churchill, M. R. J. Chem. Soc., Chem. Commun. 1967, 403.
26. (b) Broach, R. W.; Chuang, I. S.; Marks, T. J.; Williams, J. M. Inorg. Chem. 1983, 22, 1081.
27. Jones, M. D.; Kemmitt, R. D. W. Adv. Organomet. Chem. 1987, 27, 279.
28. (a) Bailey, P. J.; Mitchell, L. A.; Raithby, P. R.; Rennie, M.-A.; Verhorevoort, K.; Wright, D. S. J. Chem. Soc., Chem. Commun. 1996, 1351.
29. (b) Bailey, P. J.; Gould, R. O.; Harmer, C. N.; Pace, S.; Steiner, A.; Wright, D. S. Chem. Commun. 1997, 1161.
30. Bailey, P. J.; Grant, K. J.; Mitchell, L. A.; Pace, S.; Parsons, S.; Stewart, L. J. J. Chem. Soc., Dalton Trans. 1997, 4263.
31. Bailey, P. J.; Mitchell, L. A.; Parsons, S. J. Chem. Soc., Dalton Trans. 1996, 2839.
32. Bailey, P. J.; Bone, S.; Mitchell, L. A.; Parsons, S.; Taylor, K.; Yellowlees, L. J. Inorg. Chem. 1997, 36, 867.
33. 4-coordination are known, see: (a) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 499. (b) Herberich, G. E.; Kreuder, C.; Englert, U. Angew. Chem., Int. Ed. Engl. 1994, 33, 2465. (c) Bazan, G. C.; Rodriguez, G.; Cleary, B. P. J. Am. Chem. Soc. 1994, 116, 2177. (d) Watanabe, S.; Kurosawa, H. Organometallics 1997, 16, 3601.
34. 4-coordination are known, see: (a) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 499. (b) Herberich, G. E.; Kreuder, C.; Englert, U. Angew. Chem., Int. Ed. Engl. 1994, 33, 2465. (c) Bazan, G. C.; Rodriguez, G.; Cleary, B. P. J. Am. Chem. Soc. 1994, 116, 2177. (d) Watanabe, S.; Kurosawa, H. Organometallics 1997, 16, 3601.
35. 4-coordination are known, see: (a) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 499. (b) Herberich, G. E.; Kreuder, C.; Englert, U. Angew. Chem., Int. Ed. Engl. 1994, 33, 2465. (c) Bazan, G. C.; Rodriguez, G.; Cleary, B. P. J. Am. Chem. Soc. 1994, 116, 2177. (d) Watanabe, S.; Kurosawa, H. Organometallics 1997, 16, 3601.
36. 4-coordination are known, see: (a) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 499. (b) Herberich, G. E.; Kreuder, C.; Englert, U. Angew. Chem., Int. Ed. Engl. 1994, 33, 2465. (c) Bazan, G. C.; Rodriguez, G.; Cleary, B. P. J. Am. Chem. Soc. 1994, 116, 2177. (d) Watanabe, S.; Kurosawa, H. Organometallics 1997, 16, 3601.
37. Bailey, P. J.; Rankin, D. W. H.; Smart, B. Unpublished results.
38. (a) Almenningen, A.; Haaland, A.; Wahl, K. Acta Chem. Scand. 1969, 13, 1145.
39. (b) Churchill, M. R.; Gold, K. Inorg. Chem. 1969, 8, 401.
40. (c) Churchill, M. R.; DeBoer, B. G. Inorg. Chem. 1973, 12, 525.
41. de la Fuente, G. F.; Huheey, J. E. Phosphorus, Sulfur Silicon Relat. Elem. 1993, 78, 23.
42. 3]Br has been crystallographically characterized (monoclmic, space group C2/c, a = 14.485-(3) Å, b = 9.213(3) Å, c = 29.213(5) Å; β = 99.24(2)°, R1 = 0.0531) and full details are provided in the Supporting Information.
43. +].
44. Bailey, P. J.; Elliot, M.; Parsons, S. Unpublished results.
45. Johnson, T. J.; Folting, K.; Streib, W. E.; Martin, J. D.; Huffman, J. C.; Jackson, S. A.; Eisenstein, O.; Caulton, K. G. Inorg. Chem. 1995, 34, 488.
46. Haack, K.-J.; Hashiguchi, S.; Fujii, A.; Ikariya, T.; Noyori, R. Angew. Chem., Int. Ed. Engl. 1997, 36, 285.
47. Keim, W.; Appel, R.; Storeck, A.; Krüger, C.; Goddard, R. Angew. Chem., Int. Ed. Engl. 1981, 20, 116.
48. Möhring, V. M.; Fink, G. Angew. Chem., Int. Ed. Engl. 1985, 24, 1001.
49. Scherer, O. J.; Kerth, J.; Sheldrick, W. S. Angew. Chem., Int. Ed. Engl. 1984, 23, 156.
50. (a) Schmidbaur, H. Acc. Chem. Res. 1975, 8, 62.
51. (b) Schmidbaur, H. Pure Appl. Chem. 1978, 50, 19.
52. (c) Kaska, W. C. Coord. Chem. Rev. 1983, 48, 1.
53. (d) Grohmann, A.; Schmidbaur, H. Comprehensive Organometallic Chemistry II; Pergamon: Oxford, 1995; Vol. 3, pp 19-31.
54. Bennett, M. A.; Smith, A. K. J. Chem. Soc., Dalton Trans. 1974, 233.
55. Clegg, W. Acta Crystallogr. 1981, A37, 22.
56. Cosier, J.; Glaser, A. M. J. Appl. Crystallogr. 1986, 19, 105.
57. Altomare, A.; Burla, M. C.; Camalli, M.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A.; Polidori, G. J. Appl. Crystallogr. 1994, 27, 435.
58. Sheldrick, G. M. SHELXTL; Siemens Analytical X-ray Instruments: Madison, WI, 1995.