Synthesis and photophysical properties of stilbeneoctasilsesquioxanes. emission behavior coupled with theoretical modeling studies suggest a 3-D excited state involving the silica core

Journal of the American Chemical Society

Volumn 132, Issue 11, 2010, Pages 3708-3722

  Laine, R M ^b   Sulaiman, S ^d   Brick, C ^b   Roll, M ^b   Tamaki, R ^b,d   Asuncion, M Z ^b   Neurock, M ^c   Filhol, J S ^c,e   Lee, C Y ^c   Zhang, J ^b   Goodson III, T ^b   Ronchi, M ^a   Pizzotti, M ^a   Rand, S C ^b   Li, Y ^b  

^a UNIVERSITY OF MILAN   (Italy)

^b UNIVERSITY OF MICHIGAN   (United States)

^c UNIVERSITY OF VIRGINIA   (United States)

^d Quallion Inc   (France)

^e UNIVERSITÉ DE MONTPELLIER   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BAND GAPS; BLUE-SHIFTED; CATHODOLUMINESCENCE SPECTROSCOPY; CHARGE TRANSFER INTERACTION; CONJUGATION LENGTH; DELOCALIZATIONS; DENSITY FUNCTIONALS; EMISSION BEHAVIOR; EMISSION SPECTRUMS; ENERGY COLLECTION; FTIR; FUNCTIONALIZATIONS; MACROCYCLES; MALDI-TOF; MODEL COMPOUND; MOLECULAR ANTENNAE; MOLECULAR SYMMETRY; MOLECULAR TRANSISTORS; NMR TECHNIQUES; NONLINEAR OPTICAL APPLICATIONS; ORBITALS; ORGANIC SUBSTITUENTS; OXYGEN ATOM; PHOTOPHYSICAL PROPERTIES; RED SHIFT; RED-SHIFTED; SILICA CORES; SILICON CENTERS; SILSESQUIOXANES; SOLID POWDERS; SOLVENT POLARITY; SUBSTITUTED COMPOUNDS; THEORETICAL CALCULATIONS; THEORETICAL MODELING; THEORETICAL RESULT; TRANS-STILBENE; TWO-PHOTON ABSORPTION CROSS SECTION; TWO-PHOTON ABSORPTIONS; UV-VIS ABSORPTION SPECTRA; UV-VIS ABSORPTIONS; UV-VIS SPECTRA;

ABSORPTION; CATHODOLUMINESCENCE; EMISSION SPECTROSCOPY; EXCITED STATES; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FUNCTIONAL GROUPS; LIGHT ABSORPTION; LUMINESCENCE OF ORGANIC SOLIDS; MOLECULES; MULTIPHOTON PROCESSES; OPTICAL MATERIALS; OXYGEN; PHOTONS; SILICA; SILICON OXIDES; SOLVENTS; THERMOGRAVIMETRIC ANALYSIS; THREE DIMENSIONAL; ULTRAVIOLET SPECTROSCOPY;

ABSORPTION SPECTROSCOPY;

FUNCTIONAL GROUP; ORGANIC COMPOUND; OXYGEN; SILICON; SILICON DERIVATIVE; SILICON DIOXIDE; SILOXANE; SILSESQUIOXANE; SOLVENT; STILBENE DERIVATIVE; UNCLASSIFIED DRUG;

AIR; ARTICLE; ASYMMETRIC SYNTHESIS; CATHODOLUMINESCENCE SPECTROSCOPY; CONTROLLED STUDY; CROSS COUPLING REACTION; ELECTRON TRANSPORT; EXCITATION; FIELD EMISSION; INFRARED SPECTROSCOPY; LIGHT ABSORPTION; LUMINESCENCE; MATRIX ASSISTED LASER DESORPTION IONIZATION TIME OF FLIGHT MASS SPECTROMETRY; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; MOLECULE; PHOTOCHEMISTRY; POLARIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; THEORETICAL MODEL; THERMOGRAVIMETRY; ULTRAVIOLET SPECTROSCOPY;

EID: 77949836853     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9087709     Document Type: Article

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