Functionalization of Octavinylsilsesquioxane by Ruthenium-Catalyzed Silylative Coupling versus Cross-Metathesis

Chemistry - A European Journal

Volumn 10, Issue 5, 2004, Pages 1239-1248

  Itami, Y ^a   Marciniec, B ^a   Kabicki, M ^a  

^a ADAM MICKIEWICZ UNIVERSITY   (Poland)

Author keywords

Metathesis; Ruthenium; Silsesquioxanes; Silylative coupling; Vinylsilanes

Indexed keywords

CATALYSIS; COMPLEXATION; DERIVATIVES; ISOMERS; RUTHENIUM COMPOUNDS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); X RAY ANALYSIS;

STEREOSELECTIVITY; X RAY STRUCTURES;

ORGANIC COMPOUNDS;

HEXENE; NITROGEN; OCTAVINYLSILSESQUIOXANE; OXYGEN; POLYMER; RUTHENIUM; RUTHENIUM COMPLEX; SILANE DERIVATIVE; SILICON; STYRENE; TRIMETHYLSILYL DERIVATIVE; UNCLASSIFIED DRUG; VINYL DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CROSS METATHESIS; CRYSTAL STRUCTURE; ISOMER; REACTION ANALYSIS; SILYLATION; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; SYNTHESIS; TECHNIQUE; X RAY CRYSTALLOGRAPHY;

CATALYSIS; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; RUTHENIUM; STEREOISOMERISM; VINYL COMPOUNDS;

EID: 1642371660     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200305433     Document Type: Article

References (57)

1. a) R. H. Baney, M. Itoh, A. Sakakibara, T. Suzuki, Chem. Rev. 1995, 95, 1409;
2. b) S. Yamaguchi, K. Tamao in Silicon-Containing Polymers (Eds.: R. G. Jones, W. Ando, J. Chojnowski), Kluwer, 2000, Chapter 17;
3. c) S. W. Krska, D. Y. Son, D. Seyferth, Silicon-Containing Polymers (Eds.: R. G. Jones, W. Ando, J. Chojnowski), Kluwer, 2000, Chapter 23;
4. d) B. Boutevin, F. Guida-Pietrasanta, A. Ratsimihety in Silicon-Containing Polymers (Eds.: R. G. Jones, W. Ando, J. Chojnowski), Kluwer, 2000, Chapter 3;
5. e) A. Soum in Silicon-Containing Polymers (Eds.: R. G. Jones, W. Ando, J. Chojnowski), Kluwer, 2000, Chapter 11;
6. f) R. H Baney, X. Cao in Silicon-Containing Polymers (Eds.: R. G. Jones, W. Ando, J. Chojnowski), Kluwer, 2000, Chapter 6;
7. g) F. J. Feher, T. A. Budzichowski, Polyhedron 1995, 14, 3239;
8. h) Organic/Inorganic Hybrid Materials, Mater. Res. Soc. Symp. Proc. 2000, 628, whole volume;
9. i) Organic/Inorganic Hybrid Materials. Mater. Res. Soc. Symp. Proc. 2002, 726, whole volume;
10. j) C. J. Brinker, G. W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing, Academic Press, San Diego, 1990;
11. k) I. M. Saez, J. W. Goodby, R. M. Richardson, Chem. Eur. J. 2001, 7, 2758; K. M. Kim, Y. Chujo, Polym. Bull. 2001, 46, 15, and references therein;
12. k) I. M. Saez, J. W. Goodby, R. M. Richardson, Chem. Eur. J. 2001, 7, 2758; K. M. Kim, Y. Chujo, Polym. Bull. 2001, 46, 15, and references therein;
13. l) N. Auner, B. Ziemer, B. Herrsheft, W. Ziche, P. John, J. Weis, Eur. J. Inorg. Chem. 1999, 1087.
14. M. Bartsch, P. Bornhauser, G. Calzeferri, J. Phys. Chem. 1994, 98, 2817.
15. Marcolli, R. Imhof, G. Calzaferri, Microchim. Acta. 1997, 14, 493.
16. a) A. Sellinger, R. M. Laine, Macromolecules, 1996, 29, 2327;
17. b) A. Sellinger, C. Zhang, R. M. Laine, Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 1995, 36, 282 and reference therein.
18. F. J. Feher, D. Soulivong, A.G. Eklund, K. D. Wyndham, Chem. Commun. 1997, 1185.
19. a) B. Marciniec, in Applied Homogeneous Catalysis with Organometallic Compounds (Eds.: B. Cornils, W. A. Herrmann), VCH, Weinheim, Germany, 2002, Chapter 2.6;
20. b) J. Reichl, D. H Berry, Adv. Organomet. Chem. 1998, 43, 203;
21. c) B. Marciniec, Appl. Organomet. Chem. 2000, 14, 527;
22. d) B. Marciniec, C. Pietraszuk, Curr. Org. Chem. 2003, 7, 691.
23. a) Y. Wakatsuki, H. Yamazaki, M. Nakano, Y. Yamamoto, J. Chem. Soc. Chem. Commun. 1991, 703;
24. b) B. Marciniec, C. Pietraszuk, Chem. Commun. 1995, 2003;
25. c) B. Marciniec, C. Pietraszuk, Organometallics 1997, 16, 4320, and references therein;
26. d) C.-S. Yi, D.-W. Lee, Organometallics 2000, 19, 2036.
27. a) B. Marciniec, E. Walczuk-Gušciora, C. Pietraszuk, Organometallics 2001, 20, 3423;
28. b) B. Marciniec, E. Walczuk-Gušciora, P. Błaż ejewska-Chadyniak, J. Mol. Catal. A: Chem. 2000, 160, 165;
29. c) B. Marciniec, E. Walczuk-Gušciora, C. Pietraszuk, Catal. Lett. 1998, 55, 125.
30. B. Marciniec, I. Kownacki, M. Kubicki, M. Organometallics 2002, 19, 3263.
31. B. Marciniec, I. Kownacki, D. Chadyniak, Inorg. Chem. Commun. 1999, 2, 581.
32. a) B. Marciniec, M. Kujawa, C. Pietraszuk, Organometallics 2000, 19, 1677;
33. b) B. Marciniec, M. Kujawa, C. Pietraszuk, New J. Chem. 2000, 24, 671.
34. Y. Itami, B. Marciniec, M. Kubicki, Organometallics 2003, 22, 3717.
35. Y. Itami, B. Marciniec, M. Majchrzak, M. Kubicki, Organometallics 2003, 22, 1835.
36. C. Pietraszuk, B. Marciniec, H. Fischer, Organometallics 2000, 19, 913.
37. C. Pietraszuk, H. Fischer, M. Kujawa, B. Marciniec, Tetrahedron Lett. 2001, 42, 1175.
38. M. Kujawa-Welten, C. Pietraszuk, B. Marciniec, Organometallics 2002, 21, 840.
39. M. Kujawa-Welten, B. Marciniec, J. Mol. Catal. 2002, 190, 79.
40. C. Pietraszuk, H. Fischer, Chem. Commun. 2002, 2463.
41. B. Marciniec, C. Pietraszuk in Handbook of Methathesis (Ed.: R. Grubbs), Wiley-VCH, 2003, Chapter 2.13, p. 455.
42. a) Pyridine-coordinated ruthenium-carbene complexes: M. S. Stanford, J. A. Love, R. H. Grubbs, Organometallics 2001, 20, 5314;
43. b) pyrydine-coordinated ruthenium-carbene complexes as reactive catalysts: J. A. Love, J. P. Morgan, T. M. Trnka, R. H. Grubbs, Angew. Chem. 2002, 114, 4207; Angew. Chem. Int. Ed. 2002, 41, 4035.
44. b) pyrydine-coordinated ruthenium-carbene complexes as reactive catalysts: J. A. Love, J. P. Morgan, T. M. Trnka, R. H. Grubbs, Angew. Chem. 2002, 114, 4207; Angew. Chem. Int. Ed. 2002, 41, 4035.
45. B. Marciniec, C. Pietraszuk, M. Kujawa, J. Mol. Catal. A: Chem. 1998, 133, 41.
46. J. Louie, R. H. Grubbs, Organometallics 2002, 21, 2153.
47. N. Kuźnik, S. Krompiec, T. Bieg, S. Baj, K. Skutil, A. Chrobk, J. Organomet. Chem. 2003, 665, 167.
48. H. Katayama, M. Nagao, F. Ozawa, Organometallics 2003, 22, 586.
49. C. S. Yi, D. W. Lee, Y. Chen, Organometallics 1999, 18, 2043.
50. P. G. Harrison, C. Hall, R. Kannengiesser, Main Group Met. Chem. 1997, 20, 515; M. G. Voronkov, T. N. Martynova, R. G. Mirscov, V. I. Beleyi, Zh. Obshch. Khim. 1979, 49, 1522.
51. P. G. Harrison, C. Hall, R. Kannengiesser, Main Group Met. Chem. 1997, 20, 515; M. G. Voronkov, T. N. Martynova, R. G. Mirscov, V. I. Beleyi, Zh. Obshch. Khim. 1979, 49, 1522.
52. CrysAlis v. 169, KUMA Diffraction, Wroclaw, Poland, 2001.
53. CrysAlisRed v. 169, KUMA Diffraction, Wroclaw, Poland, 2001.
54. R. H. Blessing, J. Appl. Crystallogr. 1989, 22, 396.
55. G. M. Sheldrick, Acta Crystallogr. Sect. A 1990, 46, 467.
56. G. M. Sheldrick, SHELXL97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
57. Siemens, Stereochemical Workstation. Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, 1989.